Abstract
Poly(2-acrylamido-2-methyl-propane-1-sulphonic acid), poly(AMPS), has been ion exchanged with lithium and sodium to form alkali metal ion conducting polyelectrolytes. In the pure form these materials are rigid and would thus show limited conductivity. However addition of water or dimethylsulphoxide, as plasticizers, increases the conductivity by several orders or magnitude. The thermal analysis and NMR relaxation studies of these systems suggest that the increase in conductivity is as a direct result of increased ion mobility although the FTIR evidence still suggests significant ion association consistent with weak electrolytes. Although the Tg's of the sodium form of the polymer were higher, this system displayed higher conductivities than lithium which can be explained by a greater degree of ion dissociation and hence a larger number of charge carriers in the case of sodium poly(AMPS).
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7. References
F.M. Gray “Solid Polymer Electrolytes”, VCH Publishers, New York (1991).
C.W. Walker and M.J. Salomon, J.Electrochem. Soc.140, 3409 (1993).
A.G. Bishop, M. Forsyth and D.R. MacFarlane J. Phys. Chem. (in press 1996).
L.C. Harday and D.F. Shriver, J.Am.Chem. Soc.107, 3823 (1985).
G.-B. Zhou, I.M. Khan and J. Smid, Polym. Preprints30, 416 (1989).
T. Hamaide and C. LeDeore, Polymer34, 1038 (1993.).
D.J. Bannister, G.R. Davies, I.M. Ward an J.E. McIntyre, Polymer25, 1291 (1984).
J.F. LeNest, A. Gandini, H. Cheradame and J.P. Cohen-Addad, Polym. Commun28, 302 (1987).
H. Ohno and K. Ito, Polymer36, 891 (1995).
C.S. Harris and T.G. Rukavina, Electrochim. Acta40, 2315 (1995).
K.-C. Ho, T.G. Rukavina and C.B. Greenberg, J.Electrochem. Soc.141, 2061 (1994).
S.H. Chung, K. Such, W. Wieczorek an J.R. Stevens, J. Polym. Sci. Part B: Polym. Phys.32, 2733 (1994).
D. Shaw, “Fourier Transform NMR Spectroscopy” Elsevier Science Publishing Company, New York (1984).
D.R. MacFarlane, J. Sun, P. Meakin, P. Fasolopoulos, J. Hey and M. Forsyth, Electrochim. Acta40, 2131 (1995).
S.A. Rice an M. Nagasawa, “Polyelectrolyte Solutions”, Academic Press, New York (1961).
M. Forysth, P. Meakin, J. Hey and D.R. MacFarlane, Proceedings of CIMTEC “New Horizons for Materials” (1995).
J.A. Pople, W.G. Schneider and H.J. Bernstein, “High Resolution Nuclear Magnetic Resonance”, McGraw-Hill, New York (1959).
A. Abragam, “The Principles of Nuclear Magnetism”, Oxford University Press (1961).
M. Forsyth, M. Garcia, D.R. MacFarlane, S. Ng, M.E. Smth and J.H. Strange, Solid State Ionics (in press 1996).
F. Ali, M. Forsyth, M.C. Garcia, M.E. Smith and J.H. Strange, Solid State NMR5, 217 (1995).
F. Oosawa, “Polyelectrolytes”, Marcel Decker, New York (1971).
H. Liu, T.F. Yeh, H.S. Lee, T.A. Skotheim and Y. Okamoto, J. Polym. Sci. Part A: Polym. Chem.30 (1992) 879
Y. Okamoto, Z.S. Xu, M.G. MCLin, J.J. Fontanella, Y.S. pak and S.G. Greenbaum, Solid State Ionics60, 131 (1993)
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Every, H., Forsyth, M. & MacFarlane, D.R. Plasticized single conductung polyelectrolytes based on poly (AMPS). Ionics 2, 53–62 (1996). https://doi.org/10.1007/BF02375869
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DOI: https://doi.org/10.1007/BF02375869