Abstract
The separation of noble metal ions was investigated by chemically bonded ligands based on the concept of “hard” and “soft” acids and bases according to Pearson; influences of ion pairing and chelating effects are discussed. Complexing groups containing oxygen, nitrogen and sulphur were immobilized on silica gel. Ag, Au, Ir, Os, Pd, Pt and Rh were adsorbed in the acidic range (pH 0 to pH 5) and eluted from the gel in the range from pH 0 to pH 7.5 avoiding formation of hydroxides and coprecipitation of the noble metals. The separation is dependent on the immobilized ligand, the pH-value of sorption and desorption and the eluent.
Similar content being viewed by others
References
H. Xing-Cun,Talanta 1991,38, 319.
M. Grote, A. Kettrup,Anal. Chim. Acta 1987,201, 95.
G. V. Myasoedova, I. I. Antokol'skaya, S. B. Savvin,Talanta 1985,32, 1105.
D. K. Singh, N. K. Mishra,Chromatographia 1991,31, 300.
M. Förster, K. H. Lieser,Fresenius Z. Anal. Chem. 1981,309, 352.
K. H. Faltynski, J. R. Jezorek,Chromatographia 1986,22, 5.
T. I. Tikhomirova, V. I. Fadeeva, G. V. Kudryavtsev, P. N. Nesterenko, V. M. Ivanov, A. T. Savitchev, N. S. Smirnova,Talanta 1991,38, 267.
G. V. Myasoedova,Fresenius J. Anal. Chem. 1991,341, 586.
P. Schramel, L.-Q. Xu, G. Knapp, M. Michaelis,Fresenius J. Anal. Chem. 1993,345, 600.
L.-Q. Xu, P. Schramel,Fresenius J. Anal. Chem. 1992,342, 179.
C. Kantipuly, S. Kutragadda, A. Chow, H. D. Gesser,Talanta 1990,37, 491.
J. Navrocki,Chromatographia 1991,31, 177.
D. E. Leyden, G. H. Luttrell,Anal. Chem. 1975,47, 1612.
C. Fulcher, M. A. Crowell, R. Bayliss, K. B. Holland, J. R. Jezorek,Anal. Chim. Acta 1981,129, 29.
A. Tong, Y. Akama, S. Tanaka,Anal. Chim. Acta 1990,230, 179.
T. Seshadri, A. Kettrup,Fresenius Z. Anal. Chem. 1982,310, 1.
J. R. Jezorek, K. H. Faltynski, L. G. Blackburn, P. J. Henderson, H. D. Medina,Talanta 1985,32, 763.
M. A. Marshall, H. A. Mottola,Anal. Chem. 1983,55, 2089.
M. Grote, A. Kettrup,Anal. Chim. Acta 1985,175, 239.
V. Hodge, M. Stallard, M. Koide, E. D. Goldberg,Anal. Chem. 1986,58, 616.
M. L. Lee, G. Tölg, E. Beinrohr, P. Tschöpel,Anal. Chim. Acta 1993,272, 193.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Schilling, T., Schramel, P., Michalke, B. et al. Separation of noble metal ions on silica with chemically bonded ligands. Mikrochim Acta 116, 83–90 (1994). https://doi.org/10.1007/BF01244066
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01244066