Abstract
Reduction of “9.10-dehydro-indolinocodeinone” (2 b) with sodium borohydride yields two isomeric carbinols5 a and5 b. Their structures were established on the basis of NMR-spectroscopy and by conversion to known compounds.
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Literatur
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Die Vorsilbe-indolino-wurde für diese Derivate vonOkuda und Mitarb. eingeführt und von uns als Trivialbezeichnung der Verbindungen2, 4, 5 und7 übernommen. Das neue Ringsystem wird aber nach den IUPAC-Regeln beziffert (s. Formeln2a, 2b).
Teile aus der DissertationH. Bartsch, Univ. Wien, 1973.
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Bartsch, H., Vieböck, F. „9,10-Dehydro-indolinocodein”. Monatshefte für Chemie 105, 213–219 (1974). https://doi.org/10.1007/BF00911309
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DOI: https://doi.org/10.1007/BF00911309