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Photochemische Studien, 65. Mitt.: Untersuchungen zur Photostabilität von Ethisteron und Norethisteron sowie deren Kristallstrukturen

Photochemical studies, part 65: Investigations on the photostability of ethisterone and norethisterone and their crystal structures

  • Organische Chemie Und Biochemie
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Summary

UV irradiation of ethisterone (1) and norethisterone (2) in the solid state yielded one photoproduct each: 17,20-epoxy-17ξH-pregna-4,20-diene-3-one (3) and the dimerization product 17′-hydroxy-(13βH, 17′βH)-13,17-seco-[20, 21]bipregnayl-4,20,4′-trien-20′-in-3,17,3′-trione (4), respectively. Compounds3 and4 were characterized by their spectral and analytical data and further confirmed by the molecular packing of1 and2 in the crystal, as shown by X-ray crystallography.

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Literatur

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Authors and Affiliations

  1. Institut für Pharmazeutische Chemie, Universität Münster, Hittorfstraße 58–62, D-48149, Münster, Bundesrepublik Deutschland

    Johannes Reisch, Johannes Zappel & Nurten Ekiz-Gücer

  2. Institut für Anorganische Chemie (Festkörperchemie), Universität Duisburg, Lotharstraße 1, D-47057, Duisburg, Bundesrepublik Deutschland

    Gerald Henkel

Authors
  1. Johannes Reisch
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  2. Johannes Zappel
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  3. Gerald Henkel
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  4. Nurten Ekiz-Gücer
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Reisch, J., Zappel, J., Henkel, G. et al. Photochemische Studien, 65. Mitt.: Untersuchungen zur Photostabilität von Ethisteron und Norethisteron sowie deren Kristallstrukturen. Monatsh Chem 124, 1169–1175 (1993). https://doi.org/10.1007/BF00810025

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  • DOI: https://doi.org/10.1007/BF00810025

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