Summary
The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated.
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Ferrer, E.G., Etcheverry, S.B. & Baran, E.J. Darstellung und Eigenschaften von Vanadyl(IV)-Saccharinat. Monatsh Chem 124, 355–366 (1993). https://doi.org/10.1007/BF00814132
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DOI: https://doi.org/10.1007/BF00814132