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A temperature study on critical micellization concentration (CMC), solubility, and degree of counterion binding of α-sulfonatomyristic acid methyl ester in water by electroconductivity measurements

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Abstract

For a sodium salt of α sulfonatomyristic acid methyl ester (14SFNa), one of the α-SFMe series surfactants, critical micellization concentration (CMC), solubility and degree of counterion binding (β) were determined by means of electroconductivity measurements at different temperatures (at every 5 °C) ranging from 15 to 50 °C. The phase diagram of 14SFNa in pure water was constructed from the CMC- and solubility-temperature data, in which the Krafft temperature (critical solution temperature) was found around 0 °C. The changes in the Gibbs energy, ΔG om , enthalpy,ΔH om , and entropy, ΔS om , upon micelle formation as a function of temperature were evaluated taking β values into calculation.

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References

  1. Yoneyama Y (1995) J Jpn Oil Chem Soc (Yukagaku) 44:2

    CAS  Google Scholar 

  2. Maurer EW, Weil JK, Linfieked WM (1977) J Am Oil Chem Soc 54:582

    Article  CAS  Google Scholar 

  3. Steber J, Wierrich D (1989) Tenside Surf Deter 26:406

    CAS  Google Scholar 

  4. Masuda M, Odake H, Miura K (1994) J Jpn Oil Chem Soc (Yukagaku) 43:617

    CAS  Google Scholar 

  5. Okumura O, Sakatani, Yamane I (1976) 7th Comite International des Derives Tensio-Actis Moscow, Vol 1, p 25

    Google Scholar 

  6. Schambil F, Schuwuger MJ (1990) Tenside Surf Deter 27:380

    CAS  Google Scholar 

  7. Satsuki T, Umehara K, Yoneyama Y (1992) J Am Oil Chem Soc 69:672

    Article  CAS  Google Scholar 

  8. Fujiwara M, Miyake M, Abe Y (1993) Colloid Polym Sci 271:780

    Article  CAS  Google Scholar 

  9. Sugihara G, Yamamoto Y, Wada Y, Murata Y, Ikawa Y (1988) J Solution Chem 17:225

    Article  CAS  Google Scholar 

  10. Sugihara G (1989) In: Mittal KL (ed) Surfactants in Solution, Vol 7. Plenum, New York, p 397

    Google Scholar 

  11. Wada Y, Ikawa Y, Igimi H, Murata Y, Nagadome S, Sugihara G (1990) J Jpn Oil Chem Soc (Yukagaku), 39:548

    CAS  Google Scholar 

  12. Sugihara G, Nagadome S, Yamashita T, Kawachi N, Takagi H, Moroi Y (1991) Colloids Surf 61:111

    Article  CAS  Google Scholar 

  13. Sugihara G, Arakawa Y, Tanaka T, Lee S, Moroi Y (1995) J Colloid Interface Sci 170:399

    Article  CAS  Google Scholar 

  14. (a) Okano T, Tanabe J, Fukuda M, Tanaka M (1992) J Am Oil Chem Soc 69:44; (b) Abe M, Okuma Y, Kwon KO, Okano T, Tanabe J, Fukuda M (1993) J Jpn Oil Chem Soc 42:447; (c) Abe M, Okuma Y, Kwom KO, Ogino K, Okano T, Tanabe J, Fukuda M (1993) J Jpn Oil Chem Soc 42:929; (d) Hiraro Y, Okano T, Murata S, Urabe S, Abe M (1995) J Jpn Soc Colour Material 68:149

    Article  CAS  Google Scholar 

  15. Okano T, Egawa N, Fujiwara M, Fukuda M (1996) J Am Oil Chem Soc 73:31

    Article  CAS  Google Scholar 

  16. Stirton AJ, Bistline RG, Jr, Weil JK, Waldo CA, Maurer EW (1962) J Am Oil Chem Soc 39:128

    Article  CAS  Google Scholar 

  17. Sugihara G, Era Y, Funatsu M, Lee S, Sasaki Y, in press

  18. Moroi Y (1992) In: Micelles-Theoretical and Applied Aspects Ch. 4. Plenum, New York

    Google Scholar 

  19. Moroi Y, Matuura R (1988) Bull Chem Soc Jpn 61:333

    Article  CAS  Google Scholar 

  20. Mukerjee P, Yang AYS (1976) J Phys Chem 80:1388

    Article  CAS  Google Scholar 

  21. Manabe M, Kawamura H, Yamashita A, Tokunaga S (1987) J Colloid Interface Sci 115:147

    Article  CAS  Google Scholar 

  22. Manabe M, Kawamura H, Yamashita Y, Tokunaga S (1990) In: Bloor M, Wyn-Jones E (eds) The Structure, Dynamics and Equilibrium Properties of Colloidal Systems, p 63

  23. Sugihara G, Nakamura AA, Nakashima T-H, Araki T-I, Okano T, Fujiwara M, to be submitted

  24. Goddard ED, Benson GC (1957) Can J Chem 35:986

    Article  CAS  Google Scholar 

  25. Shinoda K, Katsura K (1964) J Phys Chem 68:1568

    Article  CAS  Google Scholar 

  26. Mukerjee P, Korematsu K, Okawauchi M, Sugihara G (1985) J Phys Chem 89:5308

    Article  CAS  Google Scholar 

  27. Sugihara G, Arakawa Y, Tanak K, Lee S, Moroi Y (1995) J Colloid Interface Sci 170:399

    Article  CAS  Google Scholar 

  28. Shinoda K (1963) In: Shinoda K, Nakagawa T, Tamamushi B-I, Isemura T (eds) Colloidal Surfactants, Ch. 1. Academic Press, New York

    Google Scholar 

  29. Mukerjee P (1996) Adv Colloid Interface Sci 21:331

    Google Scholar 

  30. Musbally GM, Perron G, Desnoyers JE (1976) J Colloid Interface Sci 54:80

    Article  CAS  Google Scholar 

  31. de Lisi R, Ostiguy C, Perron G, Desnoyers JE (1979) J Colloid Interface Sci 71:147

    Article  Google Scholar 

  32. de Lisi R, Perron G, Desnoyers JE (1980) Can J Chem 58:359

    Article  Google Scholar 

  33. Ohtaki H (1987) In: Youeki no Kagaku (Solution Chemistry) (Chem Soc Jpn Ed) Dainihom Tosho, Tokyo

    Google Scholar 

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Authors and Affiliations

  1. Lion Co. Surf. Science Research Center, 13-12 Hirai 7-chome, 123, Edgawa-ku Tokyo, Japan

    M. Fujiwara & T. Okano

  2. Department of Chemistry, Fukuoka University, 814-80, Jonan-ku Fukuoka, Japan

    T. -H. Nakashima, A. A. Nakamura & G. Sugihara

Authors
  1. M. Fujiwara
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  2. T. Okano
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  3. T. -H. Nakashima
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  4. A. A. Nakamura
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  5. G. Sugihara
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Fujiwara, M., Okano, T., Nakashima, T.H. et al. A temperature study on critical micellization concentration (CMC), solubility, and degree of counterion binding of α-sulfonatomyristic acid methyl ester in water by electroconductivity measurements. Colloid Polym Sci 275, 474–479 (1997). https://doi.org/10.1007/s003960050106

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  • DOI: https://doi.org/10.1007/s003960050106

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