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The reason for non-linear variation of specific retention volumes and retention indices for members of homologous series of organic compounds

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Summary

Universal equations have been obtained for aliphatic homologous series permitting the calcualtion of the specific retention volume, retention index, partial free energy of sorption and the change in the energy contribution of a methylene unit depending on the length of the carbon chain.

Possible reasons for the violation of the linearity principle of additivity of energy contributions of the free energy of sorption are discussed.

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References

  1. S. Van Straten, Fl. deVrijer, J. C. de Beauveser, Volatile Compounds, Institute for Nutrition and Food Research CIVO-TNO, Zeist, The Netherlands, 1977.

    Google Scholar 

  2. G. Charalambous (Editor), Analysis of Foods and Beverages. Academic Press, New-York, 1978.

    Google Scholar 

  3. H. Maarse, R. Belz: Isolation, Separation and Identification of Volatile Compounds in Aroma Research. Institute for Nutrition and Food Research, CIVO-TNO, Zeist, The Netherlands, 1981.

    Google Scholar 

  4. E. Kováts, Helv. Chim. Acta41, 1915 (1958).

    Google Scholar 

  5. R. V. Golovnya, Yu. N. Arsen'ev, Chromatographia4, 251 (1971).

    Google Scholar 

  6. R. V. Golovnya, Chromatographia12, 533 (1979).

    Google Scholar 

  7. E. Kováts, Helv. Chim. Acta42, 2711 (1959).

    Google Scholar 

  8. E. Kováts inJ. Giddings and R. Keller (editors), Advances in Chromatography. Vol. 1; pp. 229–247 (1965).

  9. G. Guiochon, Anal. Chem.36, 661 (1964).

    Google Scholar 

  10. J. C. Giddings inN. Brenner, J. E. Callen andM. D. Weiss (editors), Gas Chromatography, Academic Press, New-York, 1962; pp. 57–77.

    Google Scholar 

  11. R. V. Golovnya, V. P. Uraletz, J. Chromatogr.36, 276 (1968).

    Google Scholar 

  12. R. V. Golovnya, T. A. Misharina, J. Chromatogr.190, 1 (1980).

    Google Scholar 

  13. V. V. Kejko, B. V. Prokop'ev, L. P. Kuzmenko, N. A. Kalinina, A. V. Gusarov, B. A. Trofimov, Izv. Akad. Nauk. S.S.S.R., Ser. Khim., 1969 (4) 755.

    Google Scholar 

  14. J. Takáts, M. Rockenbauer, J. Chromatogr.42, 19 (1969).

    Google Scholar 

  15. A. A. Anderson, Gasovaya Khromatographiya Aminosoedinenij (Gas Chromatography od Amino-Compounds), Zinatne, Riga, 1982.

    Google Scholar 

  16. L. S. Ettre, K. Billeb, J. Chromatogr.30, 1 (1967).

    Google Scholar 

  17. R. V. Golovnya, Usp. Khimii45 (10), 1895 (1976).

    Google Scholar 

  18. D. N. Grigoryeva, R. V. Golovnya, I. L. Zhuravleva, N. I. Svetlova, G. B. Sergeev, Zh. Analit. Khim.34, 2434 (1979).

    Google Scholar 

  19. R. V. Golovnya, T. E. Kuzmenko, A. L. Samusenko, D. N. Grigoryeva, Prikl. Biokhim. i Mikrobiol.,17, 60 (1981).

    Google Scholar 

  20. M. B. Evans, J. E. Smith, J. Chromatogr.5, 300 (1961).

    Google Scholar 

  21. G. Schomburg, G. Dielmann, Anal. Chem.45, 1647 (1973).

    Google Scholar 

  22. J. Janák, L. Soják, Ber. Bunsenges. Phys. Chem.77, 205 (1973).

    Google Scholar 

  23. J. R. Chrétein, J.-E. Dubois, J. Chromatogr.126, 171 (1976).

    Google Scholar 

  24. F. Saura-Calixto, A. Garcia Raso, J. Chromatogr.216, 326 (1981).

    Google Scholar 

  25. D. N. Desty, W. T. Swanton, J. Phys. Chem.65, 766 (1961).

    Google Scholar 

  26. R. V. Golovnya, D. N. Grigoryeva, Izv. Akad. Nauk S.S.S.R., Ser. Khim.1983, 995.

  27. W. O. Reynolds, Gas Chromatographic Retention Data, Preston Technical Abstracts Co., Evanston, Illinois, 1966.

    Google Scholar 

  28. R. V. Golovnya, V. G. Garbuzov, T. A. Misharina, Izv. Akad. Nauk S.S.S.R., Ser. Khim., 1976 (10) 2066.

    Google Scholar 

  29. R. V. Golovnya, I. L. Zhuravleva, Chromatographia6, 508 (1973).

    Google Scholar 

  30. R. V. Golovnya, D. N. Grigoryeva, I. L. Zhuravleva, Izv. Akad. Nauk S.S.S.R., Ser. Khim. 1981 (8), 1825.

    Google Scholar 

  31. Th. Kleinert, W. Ecknig, H. Kriegsmann, Proceedings of the 3rd Danube Symposium on Chromatography, Siófok, Hungary (1981) p. 175.

  32. G. Schomburg, J. Chromatogr.23, 1 (1966).

    Google Scholar 

  33. H. J. K. Köser, J. Chromatogr.192, 107 (1980).

    Google Scholar 

  34. R. V. Golovnya, I. L. Zhuravleva, M. B. Terenina, D. N. Grigoryeva, Zh. Analit. Khim.35, 968 (1981).

    Google Scholar 

  35. R. V. Golovnya, I. L. Zhuravleva, N. I. Svetlova, D. N. Grigoryeva, Zh. Analit. Khim.35, 1976 (1980).

    Google Scholar 

  36. R. V. Golovnya, I. L. Zhuravleva, Yu. P. Kapustin, Zh. Analit. Khim.30, 2241 (1975).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Organoelement Compounds, Academy of Sciences of the U.S.S.R., Vavilova 28, Moscow, USSR

    R. V. Golovnya & D. N. Grigoryeva

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  1. R. V. Golovnya
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  2. D. N. Grigoryeva
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Dedicated to Dr. E. Kováts on the occasion of the 25-year anniversary of his invention of the retention index system.

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Golovnya, R.V., Grigoryeva, D.N. The reason for non-linear variation of specific retention volumes and retention indices for members of homologous series of organic compounds. Chromatographia 17, 613–622 (1983). https://doi.org/10.1007/BF02261945

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  • DOI: https://doi.org/10.1007/BF02261945

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