Abstract
The Kováts retention indices of 10 polycyclic aromatic hydrocarbons were determined on SE-30, OV-101, SE-52, OV-7 and OV-17 stationary phases. A significant correlation has been found between the retention indices and the average molecular polarizabilities of the analyzed substances. Equations were derived for the direct determination of the average molecular polarizabilities from the retention index values. The influence of the temperature on this relationship is also indicated.
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Lamparczyk, H., Wilczyńska, D. & Radecki, A. Relationship between the average molecular polarizabilities of polycyclic aromatic hydrocarbons and their retention indices determined on various stationary phases. Chromatographia 17, 300–302 (1983). https://doi.org/10.1007/BF02270661
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DOI: https://doi.org/10.1007/BF02270661