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Solubilities and partial molar enthalpies of solution for polar gas-liquid systems determined by gas chromatography

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Summary

The gas-liquid chromatographic method has been used to determine the solubilities and partial molar enthalpies of solution of the gases H2S, CO2 and COS in four polar solvents. The results agree well with literature values obtained using conventional techniques, with the one exception of H2S in N-methyl-2-pyrrolidinone. In this case there is some evidence for the occurrence of adsorption at the gas-liquid interface.

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Sweeney, C.W. Solubilities and partial molar enthalpies of solution for polar gas-liquid systems determined by gas chromatography. Chromatographia 18, 663–667 (1984). https://doi.org/10.1007/BF02265810

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  • DOI: https://doi.org/10.1007/BF02265810

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