Summary
This paper presents the, chromatographic retention of Co(II), Ni(II) and Cu(II) as diethyldithiocarbamate complexes in the presence of hexadecyltrimethylammonium bromide/ethanol/water systems, as mobile phase, by reversed phase high performance liquid chromatography. The presence of an organic modifier reduces the retention times and improves the efficiency. In order to evaluate the interaction between the metal complexes and the mixed micellar system the values of solute binding constants are calculated in, two ways: a) Arunyanart and Cline-Love's treatment and b) multiple regression analysis taking account of the ethanol percentages.
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D. W. Armstrong, S. J. Henry, J. Liq. Chromatogr.3, 657 (1980).
D. W. Armstrong, F. Nome, Anal. Chem.53, 1662 (1981).
D. W. Armstrong Sep. Purif. Methods,14, 213 (1985).
J. G. Dorsey, Adv. Chromatogr.27, 167 (1987).
“Ordered Media in Chemical Separations,” W. L. Hinze, D. W. Armstrong, Eds., (ACS Symposium Series, No. 342), American Chemical Society, Washington DC, 1987.
M. G. Khaledi, Trends Anal. Chem.7, 293 (1988).
A. Berthod, J. G. Dorsey, Analysis16, 75 (1988).
J. G. Dosey, M. T. De Echegaray, J. S. Landy, Anal. Chem.5, 924 (1983).
A. Berthod, I. Girard, C. Gonnet, Anal. Chem.58, 1359 (1986).
A. Berthod, M. F. Borgerding, W. L. Hinze, J. Chromatogr.556, 263 (1991).
M. L. Marina, O. Jiménez M. A. García, S. Vera, Microchem. J.53, 215 (1996).
M. Arunyanart, L. J. Cline Love, Anal. Chem.56, 1557 (1984).
J. P. Foley, Anal. Chim. Acta231, 237 (1990).
P. Yarmchuck, R. Weinberger, R. F. Hirsch, L. L. Cline-Love, Anal. Chem.57, 2183 (1985).
A. Berthod, A. Roussel, J. Chromatogr.449, 349 (1988).
R. Bailey, R. M. Cassidy, Anal. Chem.64, 2277 (1992).
J. H. Fendler, “Membrane Mimetic, Chemistry,” Wiley-Interscience, New York 1982.
P. C. Hiemenz, “Principles of Colloid and Surface Chemistry”, Marcel Dekker, New York 1986.
D. Myers, “Surfactant Science and Technology”, VCH Publishers, New York 1992.
M. L. Marina, S. Vera, A. R. Rodríguez, Chromatographia28, 379 (1989).
M. A. García, S. Vera, M. L. Marina, Chromatographia,32, 148 (1991).
V. González, M. A. Rodríguez Delgado, M. J. Sánchez, F. García Montelongo, Chromatographia32, 627 (1992).
M. A. Rodríguez Delgado, M. J. Sánchez, V. González, F. García Montelongo, Fresenius J. Anal. Chem.345, 748 (1993).
M. A. Rodríguez Delgado, M. J. Sánchez, V. González, F. García Montelongo, Chromatographia38, 342 (1994).
D. López-López, S. Rubio-Barroso, L. M. Polo-Díez, J. Liq. Chrom. & Rel. Technol.18, 2397 (1995).
M. R. Hadjmohammadi, M. H. Fatemi, J. Liq. Chrom. & Rel. Technol.18, 2569 (1995).
M. A. García, M. L. Marina, J. Liq. Chrom. & Rel. Technol.19, 1757 (1996).
P. Jandera, J. Fischer, J. Chromatogr. A.788, 279 (1996).
X. Li, J. S. Fritz, J. Chromatogr. A728, 235 (1996).
M. L. Marina, M. A. García, J. Chromatogr A780, 103 (1997).
E. Ruckenstein, R. Nagarajan, J. Phys. Chem.84, 1349 (1980).
H. N. Singh, S. M. Sateem, R. P. Singh, K. S. Birdi J. Phys. Chem.84, 1349 (1980).
P. L. Luisi, B. E. Straub, “Reverse Micelles. Biological and Technological Relevance of Amphiphilic Structures in Apolar Media”, Plenum Press, New York, 1984.
K. Fontell, A. Khan, B. Lindström, D. Maciejewska, S. Puang-Ngern, Colloid Polym. Sci.269, 727 (1991).
M. P. San Andrés, S. Vera, M. L. Marina, J. Chromatogr685, 271 (1994).
M. P. San Andrés, S. Vera, J. Liq. Chrom. & Rel. Technol.19, 799 (1996).
“Surfactants in Solution” K. L. Mittal, B. Lindman, Eds., Plenum Press, New York, 1984.
D. A. Piasecki, M. J. Wirth, Anal. Chim. Acta271, 183 (1993).
D. J. Jobe, R. E. Verral, B. Skalski, E. Aircart, J. Phys. Chem.96, 6811 (1992).
E. Aicart, D. J. Jobe, B. Skalski, R. E. Verral, J. Phys. Chem.96, 2348 (1992).
A. Berthod, J. Chromatogr. A780, 191 (1997).
R. Zana, S. Yiv C. Strazielle, P. Lianos, J Colloid Interface Sci.80, 208 (1981).
F. M. Menger, C. E. Portnoy, J. Am. Chem. Soc.89, 4698 (1967).
C. A. Bunton, Pure Appl. Chem.49, 969, (1977).
J. Gettins, D. Hall, P. L. Jobling, J. E. Rassing, E. Wyn-Jones, J. Chem. Soc. FaradayTrans 274, 1957 (1978).
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San Andrés, M.P., Barroso, M.J. & Vera, S. Hexadecyltrimethylammonium bromide/ethanol/water systems as mobie phase in reverse phase high performance liquid chromatography. Study of metal-diethyldithiocarbamate complexes retention. Chromatographia 48, 517–522 (1998). https://doi.org/10.1007/BF02466643
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DOI: https://doi.org/10.1007/BF02466643