Elsevier

Analytica Chimica Acta

Volume 113, Issue 1, 1 January 1980, Pages 139-147
Analytica Chimica Acta

Preparation of dithiocarbamatecellulose derivatives and their adsorption properties for trace elements

https://doi.org/10.1016/S0003-2670(01)85123-0Get rights and content

Abstract

Tosylcellulose was treated separately with aniline, benzylamine, n-butylamine and piperazine to give four different aminocelluloses which were further treated with carbon disulfide to furnish four dithiocarbamatecelluloses (AND, BZD, BUD and PID). A comparative study was made of their performance as adsorbents for several kinds of metal ions. PID, which has the highest degree of substitution of the dithiocarbamate group of the four derivatives obtained, was investigated for its adsorption behavior towards Ag+, As5+, Cd2+, Co2+, Cr3+, Cr6+, Cu2+, Fe3+, Hg2+, Mn2+, Pb2+, Sb5+; Se4+, Te4+ and Zn2+. PID showed good adsorption characteristics with relatively large capacities for Ag+, Cr6+, Cu2+, Hg2+, Pb2+ and Se4+ ranging from 9.5 to 370 mg g-1 of resin.

References (6)

  • J.F. Dingman et al.

    Anal. Chem.

    (1974)
  • K. Hayashi et al.

    Jpn. Anal. (Bunseki Kagaku)

    (1978)
  • R.A.A. Muzzarelli
    (1973)
There are more references available in the full text version of this article.

Cited by (45)

  • Uncovering the hydrophobic mechanism of a novel dithiocarbamate-hydroxamate surfactant towards galena

    2021, Chemical Engineering Science
    Citation Excerpt :

    In-situ AFM images clearly showed that HAPTC covered the whole galena surface at pHs 6.2 and 9.0, while they were barely observed on sphalerite surface, inferring a much stronger adsorption affinity of HAPTC towards galena than that to sphalerite. Due to that HAPTC’s adsorption driving force mainly came from its polar groups, both hydroxamate and dithiocarbamate groups exhibited the preferable affinity to galena in comparison with sphalerite, being consistent with their reactive selectivity towards Pb2+ and Zn2+ ions (Imai et al., 1980; Song-Ping et al., 1996). Therefore, HAPTC achieved a selective beneficiation of galena from sphalerite.

  • Removal of antimony (III) by multi-walled carbon nanotubes from model solution and environmental samples

    2013, Chemical Engineering Research and Design
    Citation Excerpt :

    These interactions result from the delocalized electrons in the hexagonal arrays of carbon atoms on the surfaces of the CNTs. Although there are many research studies focused on the adsorption and removal of Sb(III) from aqueous solutions by different adsorbents (Deorkar and Tavlarides, 1997; Kathrinleuz et al., 2006; Hasany and Chaudhary, 1996; Imai et al., 1980; Xi et al., 2011; Wu et al., 2012; Leng et al., 2012; Wang et al., 2012; Xu et al., 2011), up to the best of author's knowledge, there is no such study applied carbon nanotubes as a promising and potential adsorbent. This manuscript represents the first attempt to study the adsorption of Sb(III) from a model solution and from real environmental samples by MWCNTs.

  • Biosorption of antimony from aqueous solution by lichen (Physcia tribacia) biomass

    2010, Chemical Engineering Journal
    Citation Excerpt :

    Application of the ion-exchange process is rather expensive due to the cost of synthetic ion-exchange resins. Adsorption method is more effective in reducing heavy metal concentration [23–25]. However, adsorbents must have a large surface area and high polarity between the attractive forces on the adsorbent surface and adsorbate.

View all citing articles on Scopus
View full text