Elsevier

Chemical Physics Letters

Volume 64, Issue 3, 15 July 1979, Pages 435-439
Chemical Physics Letters

Reactions of NH with C2H6 and C3H8 in the liquid phase

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Abstract

HN3 was photolyzed in C2H6 or C3H8 solution at the temperature of dry ice—methanol. The main products were N2 and C2H5NH2 or n-C3H7NH2 and i-C3H7NH2. NH3 and H2 were also formed as minor products. Possible reaction mechanisms are discussed. It is suggested that alkylamine is mainly formed by the insertion of NH(a1Δ) into the CH bonds of C2H6 or C3H8

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