Gel chromatography: Interactions between gel matrix, solvent and solute

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Abstract

The partitioning behaviour of homologous series of low-molecular-weight polar and non-polar compounds has been studied on gels of cellulose and various derivative forms in dimethylformamide. The nature of the functional groups present in the gel matrix, solute and solvent markedly affects the solute partitioning. The observed partitioning is discussed in terms of the structures of the components.

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