Complexes of n- and iso-propyl mercury selenocyanates with cobalt and nickel thiocyanates

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Abstract

n- and iso-propyl mercury selenocyanates have been reacted with thiocyanates of Co(II) and Ni(II). Cobalt and nickel thiocyanates form complexes of general formula (SCN)2M(NCSeHgR)2 [M = Co(II), Ni(II); R = n-propyl and iso-propyl]. These complexes have also been reacted with pyridine and 2,2′-bipyridine. pyridine forms non-conducting adducts whereas the 2,2′-bipyridine forms cationic-anionic complexes.

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