Elsevier

Inorganica Chimica Acta

Volume 5, March 1971, Pages 554-558
Inorganica Chimica Acta

Metal Complexes of Di- and Mono-thiocarbamates and Related Compounds. I. Preparation and Characterization of Thallium(I) Compounds

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Abstract

Thallium(I) monothiocarbamates and monothioxanthates have been prepared and characterized. The corresponding dithiocarbamato- and xanthato-Thallium(l) analogues have also been prepared and their properties compared.

Mass spectral, infrared spectral, pmr, and molecular weight measurements have been used to characterize the compounds.

The observation of strong bands in the infrared spectra of the monothiocarbamato- and monothioxanthato compounds at 1525-1582 cm-1 and 665-675 cm-1 which do not occur in the dithio analogues are characteristic of the

grouping.

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    (1) On study-leave, 1970; Department of Chemistry, Trinity College, University of Dublin.

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