Hemes and hemoproteins: 1: Preparation and analysis of the heme-containing octapeptide (microperoxidase-8) and identification of the monomeric form in aqueous solution
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2023, Journal of Inorganic BiochemistryThe preparation of N-acetyl-Co(III)-microperoxidase-8 (NAcCoMP8) and its ligand substitution reactions: A comparison with aquacobalamin (vitamin B <inf>12a</inf>)
2013, Journal of Inorganic BiochemistryCitation Excerpt :An outline of the synthesis of NAcCoMP8 is provided below; more complete details are given in the Supporting Information (Section S1). FeMP11 was prepared from horse heart cytochrome c by peptic digestion as previously described [5,9,10,12] with some modifications (see Supplementary Information). Treatment with a 500 molar excess acetic anhydride in a sodium acetate solution at 5 °C yielded NAcFeMP11.
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2012, Journal of Molecular Catalysis B: EnzymaticCitation Excerpt :A number of reports have described the capability of microperoxidases (MP-8, MP-9 and MP-11) to transform a wide variety of organic compounds at the expense of hydrogen peroxide [11–15]. Microperoxidases are obtained by proteolytic digestion of mammalian cytochrome c [16]. Microperoxidase-11 (MP-11) is a heme-containing undecapeptide containing the heme group (ferric-protoporphyrin IX) and amino acids 11–21 of the parent cytochrome c [17,18].
Physical and catalytic properties of a peroxidase derived from cytochrome c
2011, Biochimica et Biophysica Acta - Molecular Basis of DiseaseUse of microperoxidase-11 to functionalize tin dioxide electrodes for the optical and electrochemical sensing of hydrogen peroxide
2011, Analytica Chimica ActaCitation Excerpt :This hemepeptide offers some advantages such as simpler design, smaller size and commercial availability. MP-11 is a small size redox enzyme obtained by proteolytic digestion of cytochrome-c (Cyt-c) [9]. It is an oligopeptide consisting of eleven amino acids and a covalently linked FeIII – protoporphyrin IX heme.
Encapsulation of Microperoxidase-8 into MIL-101(Cr/Fe) Nanoparticles: A New Biocatalyst for the Epoxidation of Styrene
2023, European Journal of Inorganic Chemistry
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Present address: Dept. of Chemistry, University of Surrey, Guildford GU2 5XH, England.