Acid—base and redox properties of Blepharismin photoreceptor pigments. A pulse radiolysis and flash photolysis study
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Primary photoprocesses in oxyblepharismin interacting with its native protein partner
2007, Journal of Photochemistry and Photobiology A: ChemistryCitation Excerpt :As we mentioned in the Introduction it had been suggested that intermolecular electron transfer could be the primary mechanism involved in the photophobic response of B. japonicum [9,10]. Indeed, the 680-nm spectral feature of Fig. 5 reminds the spectrum of the radical cation of blepharismin (BP) obtained both by radiolysis and flash-photolysis experiments [36]. In the following, we recorded the spectral signature of the radical cation of OxyBP (OxyBP+) with a photooxidation experiment and compared it directly to the pure reactive OBIP transient spectrum at 10 ps (Fig. 5).
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