Abstract
THAT the cupric salts of alkanoic acids occur in the solid state in the form of dimeric molecules is shown by van Niekerk and Schoening's X-ray analysis of cupric acetate hydrate (I, R = CH3, L = H2O)1 and by Martin and Waterman's magnetic studies of the acetate and some higher homologues in hydrated and anhydrous forms2. Tsuchida and Yamada have shown that a further characteristic of this structure is the occurrence of an absorption band about 375 mµ, polarized in the copper–copper axis, in addition to the usual ‘copper band’ about 700 mµ3,4.
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References
van Niekerk, J. N., and Schoening, F. R. L., Nature, 171, 36 (1953).
Martin, R. L., and Waterman, H., J. Chem. Soc., 3545 (1957).
Tsuchida, R., and Yamada, S., Nature, 176, 1171 (1955).
Tsuchida, R., Yamada, S., and Nakamura, H., Nature, 181, 479 (1958).
Martin, R. L., and Waterman, H., J. Chem. Soc., 1394 (1958).
Graddon, D. P., J. Inorg. Nuc. Chem., 11, 337 (1959).
Martin, R. L., and Waterman, H., J. Chem. Soc., 1359, 2960 (1959).
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GRADDON, D. Nature of Cupric Alkanoate Solutions. Nature 186, 715–716 (1960). https://doi.org/10.1038/186715b0
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DOI: https://doi.org/10.1038/186715b0
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