Abstract
IT is possible to prepare silica gels in the presence of an organic substance, for example, methyl orange, in such a manner that the dried extracted gel exhibits greater adsorptive power for the dye than a gel prepared in its absence1. A specific silica gel has been used to effect a partial resolution of camphor sulphonic acid2.
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References
Vysotskii and Polyakov, Zhur. fiz. Khim., 30, 1901 (1956). Dickey, J. Phys. Chem., 59, 695 (1955). Haldeman and Emmett, ibid., 59, 1039 (1955). Also references cited in those papers.
Curti, Colombo and Clerice, Gazz. chem. ital., 82, 491 (1952).
Beckett and Casy, J. Pharm. Pharmacol., 6, 986 (1954).
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BECKETT, A., ANDERSON, P. A Method for the Determination of the Configuration of Organic Molecules using ‘Stereo-selective Adsorbents’. Nature 179, 1074–1075 (1957). https://doi.org/10.1038/1791074a0
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DOI: https://doi.org/10.1038/1791074a0
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