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  • 1960-1964  (1,194)
  • 1910-1914
  • 1890-1899
  • 1963  (612)
  • 1961  (582)
  • Life and Medical Sciences  (655)
  • Chemical Engineering  (461)
  • Biochemistry and Biotechnology  (78)
Material
Years
  • 1960-1964  (1,194)
  • 1910-1914
  • 1890-1899
Year
Keywords
  • 101
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 306-309 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 102
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dynamic response of height in liquid-solid fluidized beds to a change in fluidizing valocity was considered. A linearized model was developed such that the time constant for the system could be estimated with the parameters characterizing the system.Spherical particles, with sizes ranging from 6 to 7 to 70 to 80 mesh and densities ranging from 1.08 g./cc. to 2.5 g./cc., were fluidized by water in a 2-in. diameter glass column. The experimental response to step and rectangular pulse inputs in fluidizing velocity were measured and frequency response data were also obtained.Agreement between the experimental data and the model was quite reasonable in view of the known nonlinearity of fluidization systems. These results show that for control purposes the system behaves as a first order time constant process.
    Additional Material: 8 Ill.
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  • 103
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 154-160 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements of the fluctuations in the mass transfer rate to small circular electrodes mounted flush with a pipe wall are used to study the unsteady nature of the viscous sublayer. These fluctuations in the mass transfer rate reflect flow fluctuations at y+ ca 0.5. From these measurements it is concluded that the flow disturbances are elongated in the direction of flow and are characterized by a time scale equal to the diameter of the pipe divided by the bulk average velocity. An attempt is made to relate the mass transfer fluctuations to the fluctuation in velocity gradient at the wall. It is concluded that the ratio of the root-mean-square fluctuating velocity gradient at the wall to the average velocity gradient at the wall is at least 0.11.
    Additional Material: 11 Ill.
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  • 104
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 342-347 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Steady state constant pressure diffusion measurements were made on a series of alumina pellets using the nitrogen-helium system at 1 atm. and 80°F. The pellets were prepared from the same alumina powder but compressed to different densities. Pore size distribution data indicate that all the pellets had approximately the same micropore sizes and volume, but different macropore volumes. Flow measurements with nitrogen were also carried out for the same pellets over a pressure range, up to 1 atm. The data show that the pellet density, or macropore volume, has a pronounced effectOn the basis of a simplified model of the pellet, path lengths were evaluated from the flow data. On the assumption that the diffusion path length is the same, a method is presented for predicting diffusion rates. The results so computed are independent of the path tortuosity. The method correctly evaluates the effect of pellet density on diffusion, but measured rates are 40 to 80% of the calculated values.
    Additional Material: 9 Ill.
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  • 105
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 365-370 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 106
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 383-385 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 107
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 386-390 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 108
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 400-406 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 109
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 411-418 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 110
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 426-426 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 111
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 432-432 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 112
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 436-572 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 113
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 437-441 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study has been made of the effect of fixed packing on the properties of a gas-fluidized bed, including minimum fluidization velocity, pressure drop, and bed expansion. Experiments using a range of glass beads as fluidizing solid with smooth uniform spheres as packing indicate that both packing size and the ratio of particle to packing diameter are the main variables in correlating the results. Other solids of varying density and shape have also been used. In addition to smooth spherical packing, rough spheres and variously shaped packings such as Raschig rings, Berl saddles, and a cylindrical, open-ended screen packing have received preliminary study. With the screen packing, which occupies only 5% of the column volume, it has been possible to operate a fluidized bed at a much higher gas throughput without slugging than is possible with a conventional bed.A preliminary study has also been made of heat transfer rates, and the results indicate that the same factors are significant. With spherical packing, values of h of the order of 70% of that in a conventional bed have been obtained, while with screen packing values ranging up to 100% or greater have been observed.Possible applications of this technique and its limitations are also discussed.
    Additional Material: 8 Ill.
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  • 114
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 448-451 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The usefulness of the Pai power series representation for the velocity distribution has been limited because of the lack of knowledge about the functional dependence of the empirical integer constant on the Reynolds number. Correlations are given for this constant for both Newtonian and non-Newtonian materials; however, certain limitations are found as a result of actual velocity distribution calculations.The equation represents the distribution over most of the turbulent core at all Reynolds numbers, but deviates widely at about a y+ of 75 for Reynolds numbers greater than 100,000. Below this, the equation provides a satisfactory representation over the entire flow field.
    Additional Material: 6 Ill.
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  • 115
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 536-540 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 116
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 555-555 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 117
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 599-605 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 118
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 3-3 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 119
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 12-19 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A stirred vessel is maintained in a quasisteady state by continuously introducing water and a conductive tracer solution and continuously removing the resulting mixture by overflow. Detailed properties of the system are elucidated by measuring tracer concentration changes with a conductivity probe in a volume element of the order of 0.3 cu. mm. By the use of suitable electronic equipment the following statistical concentration parameters are measured in experiments with three diameters of flat-bladed turbines and with a tenfold range of rotational speed: temporal mean, total root-mean-square fluctuation, spectral distribution of fluctuations, and Eulerian micro time scale. Results are interpreted in terms of behavior of time-average and fluctuation measures in three regions, the generation region within the impeller volume, the decay region which starts in the horizontal fluid sheet issuing from the impeller, and the recirculation flow region in the vessel.Generation of concentration fluctuations within the confines of the impeller is described in terms of a model involving gross mixing, without significant decay, in the wake of each flat blade. Distributions of mean and fluctuating concentrations are suggested to provide a measure of uniformity in the vessel as a whole. The former, in particular, was remarkably constant throughout the vessel.
    Additional Material: 16 Ill.
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  • 120
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 35-41 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effective scattering and absorption cross sections were determined from measurements of radiant transmission through isothermal beds of glass, aluminum oxide, steel and silicon carbide spheres, cylinders, and irregular grains. The radiant conductivities were calculated from these cross sections. Back scattering was found to be the principal mechanism of attenuation for all of the packings. Absorption was a significant mechanism only for the silicon carbide grains. At 2,000°F. The radiant contribution to the total heat flux was estimated to vary from 35% for the silicon carbide packings to 85% for the glass packings.
    Additional Material: 12 Ill.
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  • 121
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 49-54 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 122
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements were made of heat transfer rates and peak heat flux for atmospheric-pressure pool boiling, and of adiabatic and diabatic friction factors, nonboiling and local-boiling heat transfer rates, and burnout heat fluxes for both axial- and twisted-tape swirl-flow forced convection of pure ethylene glycol. Test sections were electrically heated copper, 347 stainless steel, and A-nickel tubes.Both axial- and swirl-flow friction factors are in good agreement with available generalized correlations. At the higher Reynolds numbers and heat fluxes axial-flow nonboiling heat transfer coefficients show a dependence of Nusselt number on NRe0.98 rather than the traditional NRe0.80. Swirl-flow nonboling heat transfer coefficients from both the glycol data and previously obtained water data are satisfactorily correlated by a single equation. Nucleate-boiling heat transfer coefficients for both ethylene glycol and water fall approximately 50% above Kutateladze's suggested average line. The atmospheric-pressure pool-boiling peak flux is 168,000 Btu/hr. sq. ft. Forced-convection burnout heat fluxes are correlated in a number of ways, including a new additive method which appears to be generally applicable to a large variety of coolants, geometries, and flow conditions.
    Additional Material: 6 Ill.
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  • 123
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 141-143 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 124
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 144-144 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 125
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 147-147 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 126
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 168-175 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 9 Ill.
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  • 127
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 128
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 161-167 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The present paper concerns the mechanism of mass transfer accompanied by a first-order irreversible chemical reaction between two phases. Based on the film-penetration concept a general mathematical model to describe the physico-chemical behavior at the interface has been formulated. Mass transfer mechanism may be analyzed and evaluated in terms of the dimensionless groups appearing in the derived equations.For limiting conditions the derived general equations can be reduced to those based on the simple postulations such as the film theory, the penetration theory, and the surface renewal theory. For nonlimiting cases the film-penetration concept provides information which cannot be obtained by either the film theory or the surface renewal theory alone.Experimental results appearing in literature show that the physical mass transfer coefficient is proportional to the molecular diffusivity to the v-th power and that v varies widely between 0.15 and 1.0. The film-penetration concept theoretically predicts this v-variation, whereas, in accordance with the film theory or the surface renewal theory, v has to be a certain fixed value.It is shown that if an accurate physical mass transfer coefficient is available, the film-penetration concept, the film theory, and the surface renewal theory all predict practically the same effect of chemical reaction on the mass transfer rate. However if the chemical mass transfer coefficient is to be predicted without an accurate physical transfer coefficient, the choice of the theory or the mechanism may become important.
    Additional Material: 3 Ill.
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  • 129
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 175-181 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When drops in a two-liquid phase chemical reactor are able to mix with one another by coalescences and redispersions, any spread of concentration among the drops tends to be averaged out. This phenomenon can affect average reaction rate and selectivity in non first-order reactions or mass transfer rate controlled reactions in the dispersed phase. It was found that for mass transfer rate controlled reactions, or the equivalent zero-order reaction, quite large dispersed phase mixing rates are required to bring conversions close to the level obtained with complete mixing.
    Additional Material: 8 Ill.
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  • 130
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 202-206 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 131
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 269-272 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental pressure-volume-temperature data available in the literature for argon have been utilized to produce relationships for the prediction of densities for reduced temperatures up to TR = 3.38 and reduced pressures up to PR = 50. A plot of reduced pressure vs. reduced temperature for constant reduced density was made for argon, in which each isochor terminates at the vapor-pressure curve. This information was utilized to develop a third degree polynomial relationship between the normalized pressure and the normalized temperature for each isochor by the method of least squares. This method was also used to establish the dependence of the coefficients of the polynomials on reduced density.The resulting relationships permitted the calculation of desities for argon from the critical constants, vapor pressure function, and the saturated vapor and liquid densities of the substance with a trial-and-error procedure. For fifty-seven densities for the dense gaseous and liquid phases of argon an average deviation of 1.29% with a maximum value of 3.66% resulted between calculated and reported values. The relationships developed in theis study have also been found to be applicable to nitrogen, oxygen, carbon monoxide, and methane, whose critical compressibility factors are similar to that of argon.
    Additional Material: 5 Ill.
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  • 132
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 133
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 290-432 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 134
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    AIChE Journal 9 (1963), S. 293-296 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Based on the data reported by Rossini et al. (9) analytical expressions have been developed for the calculation of enthalpies at zero pressure as functions of temperature for normal paraffins ranging from methane through octane. The coefficients of these equations have been found to correlate linearly with molecular weight, thus allowing the enthalpy relationships for hydrocarbons heavier than octane to be determined by extrapolation. The enthalpy of mixtures at zero pressure can then be obtained by combining the enthalpies of the individual components on an additive basis, weighted by the mole fractionsCorrections due to nonideal gaseous behavior have been developed in equation form from the work of Lydersen, Greenkorn, and Hougen (7) in terms of the reduced temperature TR and the critical compressibility factor zc of the substance. These corrections have been developed for both the saturated vapor and saturated liquid states and can be applied to the determination of the enthalpy of mixtures at these conditions. The results of this method have been compared with the experimental enthalpy data available for three ternary mixtures and were found to be in excellent agreement.
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  • 135
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 139-141 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 136
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 316-320 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 137
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    AIChE Journal 9 (1963), S. 338-342 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 138
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 352-358 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 13 Ill.
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  • 139
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 362-364 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 140
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 375-383 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 10 Ill.
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  • 141
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 390-393 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 142
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    AIChE Journal 9 (1963), S. 422-424 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 143
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    AIChE Journal 9 (1963), S. 509-513 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 144
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    AIChE Journal 9 (1963), S. 514-516 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 145
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    AIChE Journal 9 (1963), S. 516-523 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The flow of a highly rarefied gas in a parallel-plate channel and the transfer of heat owing to simulataneous thermal radiation and free-molecule convection has been investigated analytically. The analysis is facilitated by analogies which exist between the processes. The mass throughflow has been determined as a function of the temperatures and pressures of the system and of the channel dimensions. The heat transfer analysis is first carried out in general and then specialized to the boundary conditions of uniform wall temperature, uniform wall heat flux, and the adiabatic wall. It was found that at temperature levels corresponding to room temperature and above, the results for the combined convective-radiative transport differed little from those for a purely radiative transport.
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  • 146
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    AIChE Journal 9 (1963), S. 555-558 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 147
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    AIChE Journal 9 (1963), S. 566-566 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 148
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    AIChE Journal 9 (1963), S. 575-575 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 149
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    AIChE Journal 9 (1963), S. 579-579 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 150
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    AIChE Journal 9 (1963), S. 596-599 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 151
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    AIChE Journal 9 (1963), S. 606-614 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The time-dependent behavior of Newtonian oscillating manometers was studied experimentally and mathematically. The manometers were simulated by numerically integrating the axial component of the equation of motion in cylindrical coordinates. Modifications in the driving-force term were made to include end effects of surface tension and flow reversal. The integrations showed that the velocity profiles in the manometer were not parabolic and contained many maxima and minima, particularly when the fluid had a low viscosity. Good agreement was obtained between experimental and simulation frequencies and damping factors.
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  • 152
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    AIChE Journal 9 (1963), S. 630-635 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Interphase mass transfer between carbon dioxide gas and water has been investigated. The physical model used was the laminar concurrent flow of gas and liquid in a wide rectangular channel. Because of the high aspect ratio employed, the model was effectively one of parallel plates of infinite width.Three methods of solving the equations of change - the eigensolution method, the boundary layer theory, and penetration theory - were used to compute the diffusion coefficient of carbon dioxide in water from the experimental data. Calculated values of diffusion coefficients from the penetration theory checked well with those from the eigensolution method, but the values computed from the integrated boundary layer equation were about 10% higher.Results from the eigensolution agreed within 5% with the data of other investigators in the temperature range of 20° to 30°C.
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  • 153
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A complete analytical solution is developed for the number of equilibrium stages in separations processes for which operating and equilibrium lines are not necessarily straight. The resulting equations are solutions of a Riccati difference equation and are applied to liquid-liquid extraction and the distillation of a binary mixture where the liquid and vapor flows are not constant because of the variation of the saturated liquid and vapor enthalpies with concentration. A specific example is given for the separation of ethyl alcohol and water in which the equilibrium curve is highly nonlinear and where a large number of plates are required in a pinch region. Another example is given for the extraction of methylcyclopentane from its solution in n-hexane using aniline as a selective solvent.
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  • 154
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    AIChE Journal 9 (1963), S. 660-663 
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  • 155
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    AIChE Journal 9 (1963), S. 689-693 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 156
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    AIChE Journal 9 (1963), S. 561-566 
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  • 157
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    AIChE Journal 9 (1963), S. 567-569 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 158
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    AIChE Journal 9 (1963), S. 548-554 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data are reported for mass transfer from a flat plate under the influence of a laminar, radial wall jet initiated by a free jet of water.Present theory has been extended to mass transfer for the case of the above wall jet. An exact solution of the mass transport equation was obtained as well as an approximate solution of the integral mass balance equation, using assumed forms of the velocity and concentration profiles.Point mass transfer data were obtained by measuring the thickness decrease of coatings of acetanilide and benzoic acid. In the Reynolds number range of 1,000 to 3,000 (based on the nozzle diameter) data were in good agreement with theory. Boundary-layer separation and the formation of a toroidal vortex were observed at lower Reynolds numbers. Dye streak photographs of these vortices were obtained and correlated with mass transfer data in this region.
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  • 159
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    AIChE Journal 9 (1963), S. 585-589 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: An approximate solution to the problem of freezing of an isotropic, semi-infinite slab is proposed for the situation where Newton's cooling at the surface of the slab applies. Comparison with the existing exact solution shows the approximate solution to be practical.The heat-balance integral method is used with the assumptionof linear temperature distribution in the frozen zone and of a parabolic temperature profile in the liquid zone. The final expression for the depth of solidification, however, seems to be only little affected by the particular temperature profiles chosen.
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    AIChE Journal 9 (1963), S. 620-624 
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  • 161
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    AIChE Journal 9 (1963), S. 636-640 
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  • 162
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    AIChE Journal 9 (1963), S. 653-659 
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  • 163
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    AIChE Journal 9 (1963), S. 672-676 
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  • 164
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    AIChE Journal 9 (1963), S. 469-474 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The absorption of carbon dioxide in pure diethanolamine was studied in a gas-liquid stirred reactor at 85°, 95°, and 105°F. Over forty runs were made but only nineteen were reported here since several were invalidated by difficulties with the stirring mechanism and reaction-temperature control. The absorption was followed by pressure-time measurements with the carbon dioxide pressure ranging between 30 and 4 cm. of mercury. Experimental data were consistent and reproducible.An equation describing the gas-liquid absorption system was derived and then simplified by considering only the kinetic region. The experimental data were correlated with the simplified equation by both integral and differential methods and indicate that the reaction follows a third-order rate equation: first order in carbon dioxide and second order in diethanolamine. A mechanism explaining the observed order is described.Justification for assuming kinetic control of the absorption was demonstrated by doubling and tripling the stirring speed which produced no significant change in the absorption rate. Also, the temperature dependence of the pseudo-rate constants was out of the range of ordinary mass transfer control. This agrees with the results of a theoretical model reported previously (6).
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  • 165
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    AIChE Journal 9 (1963), S. 863-863 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 166
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    AIChE Journal 9 (1963), S. 751-754 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: No Abstrect.
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  • 167
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    AIChE Journal 9 (1963), S. 755-760 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Theoretical and experimental work is described which leads to a novel hypothesis for explaining the selectivity in heterogeneous vapor phase hydrocarbon oxidation catalysis. Two essential postulates of the hypothesis are: The oxygen atoms must be distributed on the surface of a selective oxidation catalyst in an arrangement which provides for limitation of the number of active oxygen atoms in various isolated groups.The metal-oxygen bond energy of the active oxygen atoms, at the conditions of reaction, must be in a range where rapid removal (hydrocarbon oxidation) and addition (regeneration by oxygen) is assured. Monte Carlo methods are used to illustrate the distribution of isolated sites on catalytic surfaces under the dynamic conditions of hydrocarbon oxidation reactions. Differences in catalyst and process requirements between oxidation processes operating in an overall oxidizing or reducing atmosphere are discussed.
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  • 168
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    AIChE Journal 9 (1963), S. 528-535 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 169
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    AIChE Journal 9 (1963), S. 641-645 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bubbles were formed in water when air was passed through a single square-edged orifice which had been drilled in a glass plate. The glass plate was 0.05 in. thick, and the orifice diameter was 1/8 in. The air chambers above the liquid surface and below the orifice plate were varied. The extreme values of these volumes were 0.00975 and 0.195 cu. ft. The air rate through the orifice, Q was as great as 200 × 10-5 cu. ft./sec. Bubble frequencies, f, were as great as 16 sec.-1Both the upper and lower chamber volume influenced markedly the relationship between f and Q. A relationship that predicts sets of upper and lower chamber volumes that result in the same f vs. Q relation is given. A two-parameter equation that gives f as a function of Q is presented.Wettability of the orifice plate and the liquid depth over the orifice plate were also considered as independent variables.
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  • 170
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    AIChE Journal 9 (1963), S. 663-671 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 171
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    AIChE Journal 9 (1963), S. 677-680 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rates of reaction were measured for the liquid phase hydrogenation of α-methyl styrene in a pulsed, fixed bed reactor. Data at 80 psia and 55°C., using 0.5 wt. % palladium on ⅛″ Al2O3 spheres as a catalyst, indicated that the mass transfer of dissolved hydrogen to the catalyst surface controlled the rate of conversion of styrene to cumene. Hence the data were employed to calculate mass transfer coefficients as a function of pulse frequency and amplitude.Comparison with non-pulse data at the same Reynolds number showed that pulsation increased the mass transfer rate as much as 80%.
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  • 172
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    AIChE Journal 9 (1963), S. 694-702 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 173
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    AIChE Journal 9 (1963), S. 706-707 
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  • 174
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    AIChE Journal 9 (1963), S. 5-11 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The volumetric properties of sixteen fluids of interest in cryogenic engineering have been used to calculate second virial coefficients over as large a temperature range as possible. These coefficients were then fitted to theoretical expressions based on the Kihara potential function. For helium, hydrogen, and neon quantum corrections were applied. For nitrogen, carbon dioxide, and acetylene corrections for quadrupole interactions were made. It was found that the theoretical expressions give an extremely good fit of all reliable experimental datu. The theoretical expressions may therefore be used with confidence to predict volumetric behavior at very low temperatures where data are frequently unavailable.With the aid of semiempirical mixing rules the theoretical expressions may be used to predict second virial coefficients for mixtures. Agreement with the very limited amount of experimental mixture data is satisfactory. Finally it is shown that calculations based on the Kihara potential may be employed to make useful predictions of phase equilibria such as the solubility of a solid in a compressed gas.
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    AIChE Journal 9 (1963), S. 73-76 
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    AIChE Journal 9 (1963), S. 103-106 
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    AIChE Journal 9 (1963), S. 134-138 
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    AIChE Journal 9 (1963), S. 183-185 
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    AIChE Journal 9 (1963), S. 190-195 
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    AIChE Journal 9 (1963), S. 196-202 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When two liquid phases are contacted in a stirred tank reactor, dispersed phase mixing can affect average reaction rate and product selectivity in nonfirst order or mass transfer controlled reactions, as shown theoretically in Part I. This work is concerned with experimental measurement of the dispersed phase mixing rate. Various organic phase dispersions in water were studied in stirred tanks with a dye transfer light transmission technique. Batch experiments were performed in 0.30, 5.5, and 86-gal. vessels. The variables studied were power input per unit volume, phase fraction, impeller type, and vessel scale. Dispersed phase mixing rates were found to be in the range where they can have significant effects on chemical reactions. A typical value of the mixing rate is 10 volumes of dispersed phase/min. at a power input of 10 hp./1,000 gal. The information given here and in Part I shows for the first time the importance of these effects in reactor design.
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    AIChE Journal 9 (1963), S. 88-92 
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    AIChE Journal 9 (1963), S. 253-260 
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    AIChE Journal 9 (1963), S. 273-277 
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    AIChE Journal 9 (1963), S. 223-228 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rate of permeation of hydrogen through a highly purified iron (Ferrovac E) was measured over a pressure range of 1/30 to 300 atm. and a temperature range of 126° to 693°C. The effect of cold working of the annealed metal and of hydrogen purity were also studied. Permeability, diffusivity, and solubility were obtained from the data. Permeation rate was linear with square root of fugacity rather than pressure. No difference in φ or D between the annealed and cold worked tube was observed. Log D vs. 1/T was linear over the whole range of temperature, in disagreement with recent work showing a break in the plot at about 400°C. The calculated activation energy was lower than values reported in the literature. Solubility agreed well with most previous work and did not show the break in the solubility vs. temperature curve found by some recent investigators. No ageing effect was observed nor any difference between the two grades of hydrogen. All the evidence shows that diffusion through the metal is the controlling rate process in this case.
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  • 185
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    AIChE Journal 9 (1963), S. 310-316 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Both the rheological and the hindered-settling characteristics of small particle size suspensions (0.1 to 50 μ) are primarily determined by the degree of flocculation and the concentration of the suspension. Previous studies have shown that when the laminar shear diagrams are fitted by the Bingham plastic model, the parameters τy/φ3 and φ-1 In η/μ are constants which are proportional to the degree of flocculationThe present study showed that these rheological parameters were proportional to the value of α determined from the hindered-settling measurements (α is defined as the ratio of the volume of fluid immobilized by the floc structure to the volume of solids in the floc structure). The materials studied included suspensions of thorium oxide in water and methanol and of titania, kaolin, alumina, and graphite in water. The particle size range was from 0.40 to 17.0 μValues of the attractive force between particles calculated from the rheological and hindered-settling data were in good agreement with each other and with the theoretical values calculated from the Derjaguin-Verwey-Overbeek theory of colloid stability. The good agreement among the different values suggests that the present approach may be generally applicable to a variety of different systems.
    Additional Material: 6 Ill.
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  • 186
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    AIChE Journal 9 (1963), S. 321-331 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: If the temperature level or free stream reactant concentration is deliberately changed, the resulting change in the observed global reaction rate on a catalytic surface in a flow system will not necessarily reflect the true chemical kinetics at the fluid/solid interface. General expressions, reminiscent of those applicable to a static system, are derived for the relation between the diffusional falsification of activation energy and reaction order in terms of a logarithmic derivative of the isothermal diffusion correction (effectiveness factor). Approximate solutions are given for the case of the thin, nonturbulent diffusion layer which develops along an impermeable catalytic flat plate, for arbitrary values of the true reaction order and Prandtl number for diffusion (Schmidt number). Comparisons with exact solutions to the boundary-layer equations and alternate approximate methods are given for the special case of first-order surface reactions. Of the various quantities of interest in the diffusional theory of heterogeneous reactions in flow systems, it is shown that the accuracy of the Frank-Kamenetskii quasi-stationary method can become unacceptably poor for the calculation of these falsification parameters. The physicochemical conditions under which these errors are likely to be largest are discussed. Applications are given to the study of the chemical kinetics of fast surface reactions.
    Additional Material: 8 Ill.
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  • 187
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    AIChE Journal 9 (1963), S. 182-183 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 188
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    AIChE Journal 9 (1963), S. 186-190 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 189
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    AIChE Journal 9 (1963), S. 207-210 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 190
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    AIChE Journal 9 (1963), S. 452-459 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 191
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    AIChE Journal 9 (1963), S. 459-468 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Microorganisms undergo a cycle of maturation during their life-span in a proliferating culture. This gives rise to a distribution of degrees of cellular maturation in the culture. The gross rate of any metabolic process carried on by the culture is therefore an average over all degrees of maturation present.Equations embodying the life-cycle concept are developed for cultures of organisms which proliferate by binary fission and do not form spores. The equations are solved for the age distribution in the special case of a continuous, steady state fermentation. Expressions for calculating gross metabolic rates and cell size distributions are derived. Finally, the stability of the steady state fermentor is discussed.
    Additional Material: 4 Ill.
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  • 192
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    AIChE Journal 9 (1963), S. 474-479 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 193
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    AIChE Journal 9 (1963), S. 216-222 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper deals with a new concept for predicting burnout conditions for forced convection of boiling water in fuel elements of nuclear boiling reactors.The concept states the importance of considering the ratio of heated channel perimeter to total channel perimeter.The perimeter ratio concept was arrived at from an experimental study of burnout conditions in rod clusters consisting of three rods of 13 mm. outside diameter and 830 mm. heated length. Data were obtained for pressures between 2.5 and 10 kg./sq. cm., surface heat fluxes between 50 and 120 W./ sq. cm., mass flow rates between 0.03 and 0.33 kg./sec., and steam qualities between 0.01 and 0.52.The rod clearance for the experiment were 2 and 6 mm. The diameter of the channel was 41.3 mm. Additional runs were also performed after unheated displacement rods were introduced in the channel. The rod clearance in this case was 6 mm.In the ranges investigated the measured burnout steam qualities at the outlet of the channel decrease with increasing heat flux and decreasing pressure. Furthermore it has been found that the influence of rod clearance is, in the range investigated, of small significance for engineering purposes.It has also been observed that the present burnout steam quality data for the rod clusters are much lower than those earlier obtained for round ducts. This may be explained physically by means of the perimeter ratio concept.It has also been found that the surface shear stress distribution around the channel perimeter and especially the position of maximum shear stress is of great importance for predicting burnout conditions for flow in channels.Finally the new method has helped in understanding and interpreting experimental results which earlier may have seemed inconsistent.
    Additional Material: 14 Ill.
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  • 194
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    AIChE Journal 9 (1963), S. 240-246 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The isothermal effects of pressure and composition on the mixture and partial enthalpy differences of the methane-propane binary were derived from PVTy data. A graphical and numerical technique was used to derive the enthalpy differences from 100° to 460°F. and 200 to 2,000 lb./sq. in. abs. for the complete composition range of the binary.The isothermal effects of pressure and composition on the mixture enthalpy data of the methane-propane binary were also calculated with the Benedict-Webb-Rubin and the Redlich-Kwong equations of state. The results of the three methods of calculation are compared. The comparison showed that the two-constant Redlich-Kwong equation of state is as good as the eight-constant Benedict equation of state in the superheated vapor region.The data derived in this work were combined with other methane binary enthalpy data from the literature to construct a general correlation of the effect of pressure and composition on the enthalpy of methane-light hydrocarbon binaries. The correlating parameters are the pseudo reduced temperature and pressure and a mole-average acentric factor.
    Additional Material: 6 Ill.
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  • 195
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    AIChE Journal 9 (1963), S. 261-268 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: There are certain semiempirical equations for estimating heat transfer coefficients for liquid metals flowing through regular shapes. These contain the factor ψ, which is the average, effective value of the ratio of the eddy diffusivity of heat transfer to that for momentum transfer. The main problem in liquid metal heat transfer has been to evaluate this quantity.
    Additional Material: 12 Ill.
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  • 196
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    AIChE Journal 9 (1963), S. 279-282 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 197
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    AIChE Journal 9 (1963), S. 283-283 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 198
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    AIChE Journal 9 (1963), S. 287-288 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 199
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    AIChE Journal 9 (1963), S. 297-302 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 200
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    AIChE Journal 9 (1963), S. 303-306 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Existing theories on the effect of mass transport on the rate (uniformity) of chemical reaction within a porous solid assume that the reaction is of integer order. However the carbon-carbon-dioxide reaction has the kinetic rate form, rate = k1pCO2/(1 + k2pCO + k3pCO2). For conditions where the retarding effect of carbon monoxide is very pronounced, the buildup of small concentrations of carbon monoxide within the porous graphite can lead to appreciable nonuniformity of gasification. Thus the criteria normally used to predict uniformity of gasification break down. A numerical integration of the combined differential equation of mass transport and chemical reaction has been performed, with rate constants for the carbon-carbon dioxide reaction taken from the literature. The results indicate that extreme nonuniformity of reaction can exist even when the change in carbon dioxide concentration from the exterior of the sample to the interior is small. The results are similar to experimental determinations of non-uniformity of gasification, obtained by determining the porosity of reacted graphite samples as a function of depth from the reacting face. Experimentally nonuniformity of reaction was observed for gasification rates a hundredfold lower than the usual Thiele criteria would predict, probably because of carbon monoxide inhibition.
    Additional Material: 4 Ill.
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