ISSN:
0570-0833
Keywords:
Valence tautomerism
;
Cyclooctatetraenes
;
Bicyclooctatriene
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The Diels-Alder adducts of cyclooctatetraene and its derivatives are derived from the bicyclo[4,2,0]octane structure. A kinetic investigation shows that the Diels-Alder addition of dienophiles to cyclooctatetraene and phenylcyclooctatetraene is preceded by a valence tautomerism equilibrium with bicyclo[4,2,0]octa-2,4,7-triene or its 7-phenyl derivative.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.196400831
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