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The Oxidation of Olefins with Palladium Chloride Catalysts (1962)

Smidt, Juergen ; Hafner, W. ; Jira, R. ; [weitere]

Weinheim : Wiley-Blackwell

Angewandte Chemie International Edition in English 1 (1962), S. 80-88

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Details

ISSN: 0570-0833

Schlagwort(e): Oxidation ; Palladium ; Catalysis ; Alkenes ; Chemistry ; General Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The oxidation of olefins to carbonyl compounds with palladium compounds, especially the oxidation of ethylene to acetaldehyde, is at present carried out on a technical scale. The reaction takes place via a palladium-olefin complex, the formation of which is inhibited by halide ions. Hydrolysis to the carbonyl compound is inhibited by hydrogen ions. The knowledge gained by studying the reaction of olefins with pure solutions of palladium salts allows important conclusions to be drawn concerning the action of technical catalyst solutions containing copper and palladium chloride.

Zusätzliches Material: 9 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/anie.196200801

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