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  • 1985-1989
  • 1960-1964  (240)
  • 1963  (240)
  • Chemical Engineering  (240)
  • Life Sciences
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Years
  • 1985-1989
  • 1960-1964  (240)
Year
  • 101
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 653-659 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 102
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 672-676 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 103
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 681-688 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 104
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 797-804 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 105
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 106
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 826-830 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 107
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 541-547 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 108
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 857-860 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 109
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 110
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 580-584 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The prediction of vapor-liquid equilibria with the Benedict-Webb-Rubin (BWR) equation of state has been restudied. It was found that the suitability of the equation of state to represent fully the behavior of the constituents is the main factor which affects the accuracy of the prediction. To improve the representation of the pure component data by means of equation of state it is necessary to modify the present form of the BWR equation of state. A tentative form of modification of the BWR equation of state has been chosen. Although the modified equation is still subject to further evaluation and refinement, satisfactory results have been obtained for the prediction of four binary systems containing nitrogen and carbon dioxide (nitrogen-methane. methane-carbon dioxide, propane-carbon dioxide, and n-butane-carbon dioxide).The method of nonlinear estimation has been used to fit the coefficients in the equation of state to either vapor-pressure data or P-V-T data.
    Additional Material: 5 Tab.
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  • 111
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 677-680 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rates of reaction were measured for the liquid phase hydrogenation of α-methyl styrene in a pulsed, fixed bed reactor. Data at 80 psia and 55°C., using 0.5 wt. % palladium on ⅛″ Al2O3 spheres as a catalyst, indicated that the mass transfer of dissolved hydrogen to the catalyst surface controlled the rate of conversion of styrene to cumene. Hence the data were employed to calculate mass transfer coefficients as a function of pulse frequency and amplitude.Comparison with non-pulse data at the same Reynolds number showed that pulsation increased the mass transfer rate as much as 80%.
    Additional Material: 6 Ill.
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  • 112
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 706-707 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 113
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 766-770 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Entrance-region studies, based on static-pressure measurements, were carried out with water flowing in annuli and a circular tube fitted with interchangeable square or rounded entrance sections. The tests covered the Reynolds number range from 16,000 to 70,000. For the annuli, the length of duct required to approach to within 5% of the fully developed pressure gradient was about 20 to 25 hydraulic diameters. This is in general accord with entrance length results for circular tubes and parallel-plate channels but differs from prior results for the annulus which had indicated entrance lengths larger by a factor of ten. The results for the sharp entrance showed a definite effect of separation and were characterized by high loss coefficients. For the rounded entrance, the initial part of the flow development was laminar; the entrance-region pressure drop did not substantially exceed (and in one case was less than) the corresponding fully developed pressure drop. Also for the rounded entrance, flow stability was improved and a monotonically decreasing pressure gradient obtained when a turbulent boundary layer was induced by means of a trip. Fully developed friction factors were calculated and compared with theory.
    Additional Material: 9 Ill.
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  • 114
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 115
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 5-11 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The volumetric properties of sixteen fluids of interest in cryogenic engineering have been used to calculate second virial coefficients over as large a temperature range as possible. These coefficients were then fitted to theoretical expressions based on the Kihara potential function. For helium, hydrogen, and neon quantum corrections were applied. For nitrogen, carbon dioxide, and acetylene corrections for quadrupole interactions were made. It was found that the theoretical expressions give an extremely good fit of all reliable experimental datu. The theoretical expressions may therefore be used with confidence to predict volumetric behavior at very low temperatures where data are frequently unavailable.With the aid of semiempirical mixing rules the theoretical expressions may be used to predict second virial coefficients for mixtures. Agreement with the very limited amount of experimental mixture data is satisfactory. Finally it is shown that calculations based on the Kihara potential may be employed to make useful predictions of phase equilibria such as the solubility of a solid in a compressed gas.
    Additional Material: 7 Ill.
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  • 116
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 19-24 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 117
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 30-34 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Brine-air and kerosene-hydrogen systems were used for the mixed phase tests. No specific gas phase effects were detected. The measured variability, encompassing all three flow mechanisms, correlated well with particle Reynolds number for each system and decreased with increasing flow rate. However the variability component resulting solely from bulk liquid flow through the main bed channels was found to be relatively constant over a wide range of Reynolds number and independent of whether the bed was uniformly packed or contained large packing faults. The significance of these results to liquid-solids contacting efficiency is discussed.
    Additional Material: 6 Ill.
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  • 118
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 42-45 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study has been made of the cation exchange equilibria between Dowex 50W-X8 resin and aqueous solutions of copper nitrate, nitric acid, and sodium nitrate in binary and ternary mixtures. Experiments were carried out at room temperature with solutions having total cation concentrations of approximately 0.1N, 0.05N, and 0.01N. It was found that the equilibria for any two ions were essentially the same in binary and ternary mixtures. Moreover single valued selectivity coefficients were determined which characterize these data quite well for all three concentration levels. This makes possible the complete description, for engineering purposes, of ternary equilibria in terms of the simpler and more accessible binary exchange reactions, as previously suggested (1).
    Additional Material: 8 Ill.
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  • 119
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 64-67 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 120
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 73-76 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 121
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 49-54 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 122
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 106-108 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The characteristic velocities in binary and particular ternary cases allow straightforward calculation of equilibrium partition coefficients for components present in both flowing and fixed phases. It is shown in the case of a general N-component flowing phase that N-1 characteristic velocities arise. In theory N-1 equilibrium partition coefficients can be obtained from measurements of these velocities. It is also shown that radioactive tagging of one component provides a distinct characteristic velocity, which can be used either to obtain the Nth equilibrium coefficient or to eliminate a parameter which is especially subject to experimental error.The analytically determined characteristic velocities are compared with pulse velocities obtained from numerical solution of the original balance equations. The agreement over a range of solute concentrations is excellent.
    Additional Material: 1 Tab.
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  • 123
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 103-106 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 124
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 134-138 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 125
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The unsteady state flow of ammonia gas has been investigated to determine its viscosity at elevated pressures and moderate temperatures. This was accomplished in an experimental unit of the transpiration type which was calibrated with nitrogen, for which viscosity data at high pressures were available in the literature. To obtain the viscosity at the operating conditions the basic differential equation for the unsteady state flow caused by the experimental procedure was developed and solved with an IBM-650 digital computer.Experimental runs were conducted for pressures ranging from 250 to 5,000 lb./sq. in. and temperatures from 100° to 200°C. This information has been used to establish the viscosity of ammonia at these dense phase conditions for which no viscosities had been previously reported. These values were used to develop a unique correlation between the residual viscosity and the density. This correlation then enabled the determination of ammonia's viscosity at the critical point μc = 2,395×10-5 centipoises.The Enskog viscosity equation has been used with the values resulting from this study and PVT data for ammonia to develop a relationship for the probability of nearness. This relationship enables viscosities to be calculated for densities up to 0.450 g./cc. which are in close agreement with the experimental values.
    Additional Material: 7 Ill.
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  • 126
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 190-195 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 127
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 196-202 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When two liquid phases are contacted in a stirred tank reactor, dispersed phase mixing can affect average reaction rate and product selectivity in nonfirst order or mass transfer controlled reactions, as shown theoretically in Part I. This work is concerned with experimental measurement of the dispersed phase mixing rate. Various organic phase dispersions in water were studied in stirred tanks with a dye transfer light transmission technique. Batch experiments were performed in 0.30, 5.5, and 86-gal. vessels. The variables studied were power input per unit volume, phase fraction, impeller type, and vessel scale. Dispersed phase mixing rates were found to be in the range where they can have significant effects on chemical reactions. A typical value of the mixing rate is 10 volumes of dispersed phase/min. at a power input of 10 hp./1,000 gal. The information given here and in Part I shows for the first time the importance of these effects in reactor design.
    Additional Material: 5 Ill.
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  • 128
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 230-239 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 11 Ill.
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  • 129
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 253-260 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 17 Ill.
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  • 130
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 273-277 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 131
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 269-272 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental pressure-volume-temperature data available in the literature for argon have been utilized to produce relationships for the prediction of densities for reduced temperatures up to TR = 3.38 and reduced pressures up to PR = 50. A plot of reduced pressure vs. reduced temperature for constant reduced density was made for argon, in which each isochor terminates at the vapor-pressure curve. This information was utilized to develop a third degree polynomial relationship between the normalized pressure and the normalized temperature for each isochor by the method of least squares. This method was also used to establish the dependence of the coefficients of the polynomials on reduced density.The resulting relationships permitted the calculation of desities for argon from the critical constants, vapor pressure function, and the saturated vapor and liquid densities of the substance with a trial-and-error procedure. For fifty-seven densities for the dense gaseous and liquid phases of argon an average deviation of 1.29% with a maximum value of 3.66% resulted between calculated and reported values. The relationships developed in theis study have also been found to be applicable to nitrogen, oxygen, carbon monoxide, and methane, whose critical compressibility factors are similar to that of argon.
    Additional Material: 5 Ill.
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  • 132
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 133
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 139-141 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 134
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 135
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 293-296 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Based on the data reported by Rossini et al. (9) analytical expressions have been developed for the calculation of enthalpies at zero pressure as functions of temperature for normal paraffins ranging from methane through octane. The coefficients of these equations have been found to correlate linearly with molecular weight, thus allowing the enthalpy relationships for hydrocarbons heavier than octane to be determined by extrapolation. The enthalpy of mixtures at zero pressure can then be obtained by combining the enthalpies of the individual components on an additive basis, weighted by the mole fractionsCorrections due to nonideal gaseous behavior have been developed in equation form from the work of Lydersen, Greenkorn, and Hougen (7) in terms of the reduced temperature TR and the critical compressibility factor zc of the substance. These corrections have been developed for both the saturated vapor and saturated liquid states and can be applied to the determination of the enthalpy of mixtures at these conditions. The results of this method have been compared with the experimental enthalpy data available for three ternary mixtures and were found to be in excellent agreement.
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  • 136
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    AIChE Journal 9 (1963), S. 310-316 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Both the rheological and the hindered-settling characteristics of small particle size suspensions (0.1 to 50 μ) are primarily determined by the degree of flocculation and the concentration of the suspension. Previous studies have shown that when the laminar shear diagrams are fitted by the Bingham plastic model, the parameters τy/φ3 and φ-1 In η/μ are constants which are proportional to the degree of flocculationThe present study showed that these rheological parameters were proportional to the value of α determined from the hindered-settling measurements (α is defined as the ratio of the volume of fluid immobilized by the floc structure to the volume of solids in the floc structure). The materials studied included suspensions of thorium oxide in water and methanol and of titania, kaolin, alumina, and graphite in water. The particle size range was from 0.40 to 17.0 μValues of the attractive force between particles calculated from the rheological and hindered-settling data were in good agreement with each other and with the theoretical values calculated from the Derjaguin-Verwey-Overbeek theory of colloid stability. The good agreement among the different values suggests that the present approach may be generally applicable to a variety of different systems.
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  • 137
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    AIChE Journal 9 (1963), S. 321-331 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: If the temperature level or free stream reactant concentration is deliberately changed, the resulting change in the observed global reaction rate on a catalytic surface in a flow system will not necessarily reflect the true chemical kinetics at the fluid/solid interface. General expressions, reminiscent of those applicable to a static system, are derived for the relation between the diffusional falsification of activation energy and reaction order in terms of a logarithmic derivative of the isothermal diffusion correction (effectiveness factor). Approximate solutions are given for the case of the thin, nonturbulent diffusion layer which develops along an impermeable catalytic flat plate, for arbitrary values of the true reaction order and Prandtl number for diffusion (Schmidt number). Comparisons with exact solutions to the boundary-layer equations and alternate approximate methods are given for the special case of first-order surface reactions. Of the various quantities of interest in the diffusional theory of heterogeneous reactions in flow systems, it is shown that the accuracy of the Frank-Kamenetskii quasi-stationary method can become unacceptably poor for the calculation of these falsification parameters. The physicochemical conditions under which these errors are likely to be largest are discussed. Applications are given to the study of the chemical kinetics of fast surface reactions.
    Additional Material: 8 Ill.
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  • 138
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 342-347 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Steady state constant pressure diffusion measurements were made on a series of alumina pellets using the nitrogen-helium system at 1 atm. and 80°F. The pellets were prepared from the same alumina powder but compressed to different densities. Pore size distribution data indicate that all the pellets had approximately the same micropore sizes and volume, but different macropore volumes. Flow measurements with nitrogen were also carried out for the same pellets over a pressure range, up to 1 atm. The data show that the pellet density, or macropore volume, has a pronounced effectOn the basis of a simplified model of the pellet, path lengths were evaluated from the flow data. On the assumption that the diffusion path length is the same, a method is presented for predicting diffusion rates. The results so computed are independent of the path tortuosity. The method correctly evaluates the effect of pellet density on diffusion, but measured rates are 40 to 80% of the calculated values.
    Additional Material: 9 Ill.
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  • 139
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    AIChE Journal 9 (1963), S. 365-370 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 140
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    AIChE Journal 9 (1963), S. 383-385 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 141
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    AIChE Journal 9 (1963), S. 386-390 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 142
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    AIChE Journal 9 (1963), S. 400-406 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 143
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    AIChE Journal 9 (1963), S. 411-418 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 144
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    AIChE Journal 9 (1963), S. 509-513 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 145
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    AIChE Journal 9 (1963), S. 514-516 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 146
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    AIChE Journal 9 (1963), S. 516-523 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The flow of a highly rarefied gas in a parallel-plate channel and the transfer of heat owing to simulataneous thermal radiation and free-molecule convection has been investigated analytically. The analysis is facilitated by analogies which exist between the processes. The mass throughflow has been determined as a function of the temperatures and pressures of the system and of the channel dimensions. The heat transfer analysis is first carried out in general and then specialized to the boundary conditions of uniform wall temperature, uniform wall heat flux, and the adiabatic wall. It was found that at temperature levels corresponding to room temperature and above, the results for the combined convective-radiative transport differed little from those for a purely radiative transport.
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  • 147
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    AIChE Journal 9 (1963), S. 555-558 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 148
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    AIChE Journal 9 (1963), S. 448-451 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The usefulness of the Pai power series representation for the velocity distribution has been limited because of the lack of knowledge about the functional dependence of the empirical integer constant on the Reynolds number. Correlations are given for this constant for both Newtonian and non-Newtonian materials; however, certain limitations are found as a result of actual velocity distribution calculations.The equation represents the distribution over most of the turbulent core at all Reynolds numbers, but deviates widely at about a y+ of 75 for Reynolds numbers greater than 100,000. Below this, the equation provides a satisfactory representation over the entire flow field.
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  • 149
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    AIChE Journal 9 (1963), S. 479-484 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: To account for the differences in the gas-phase mass transfer coefficients obtained by the use of vaporization and absorption techniques, data were obtained for ring and saddle packings in a 12-in. diam. column employing water vaporization and methanol absorption. The ratio of the vaporization to absorption coefficient, corrected for differences in diffusivity, is found to be directly proportional to the ratio of the total holdup to the operating holdup in confirmation of the proposed model in which the effective interfacial area for each type of operation is proportional to the holdup of the liquid active for that operation.
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  • 150
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    AIChE Journal 9 (1963), S. 630-635 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Interphase mass transfer between carbon dioxide gas and water has been investigated. The physical model used was the laminar concurrent flow of gas and liquid in a wide rectangular channel. Because of the high aspect ratio employed, the model was effectively one of parallel plates of infinite width.Three methods of solving the equations of change - the eigensolution method, the boundary layer theory, and penetration theory - were used to compute the diffusion coefficient of carbon dioxide in water from the experimental data. Calculated values of diffusion coefficients from the penetration theory checked well with those from the eigensolution method, but the values computed from the integrated boundary layer equation were about 10% higher.Results from the eigensolution agreed within 5% with the data of other investigators in the temperature range of 20° to 30°C.
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  • 151
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    Notes: A complete analytical solution is developed for the number of equilibrium stages in separations processes for which operating and equilibrium lines are not necessarily straight. The resulting equations are solutions of a Riccati difference equation and are applied to liquid-liquid extraction and the distillation of a binary mixture where the liquid and vapor flows are not constant because of the variation of the saturated liquid and vapor enthalpies with concentration. A specific example is given for the separation of ethyl alcohol and water in which the equilibrium curve is highly nonlinear and where a large number of plates are required in a pinch region. Another example is given for the extraction of methylcyclopentane from its solution in n-hexane using aniline as a selective solvent.
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  • 152
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    AIChE Journal 9 (1963), S. 660-663 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 153
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    AIChE Journal 9 (1963), S. 689-693 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 154
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    AIChE Journal 9 (1963), S. 424-425 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 155
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    AIChE Journal 9 (1963), S. 707-720 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method of evaluating catalytic effectiveness in systems of variable diffusivity is proposed. These systems are encountered when catalysts with bi-disperse pore-size distributions are employed or when multicomponent mixtures are involved. The diffusivity is taken to be a linear function of length, and an effectiveness factor is defined for this case. Application of the method is discussed and a numerical example is given.
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  • 156
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    AIChE Journal 9 (1963), S. 722-863 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 157
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    AIChE Journal 9 (1963), S. 435-435 
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  • 158
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    AIChE Journal 9 (1963), S. 573-575 
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    Keywords: Chemistry ; Chemical Engineering
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  • 159
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    AIChE Journal 9 (1963), S. 442-447 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mass diffusion studies were carried out in a diaphragm diffusion cell with the liquid system methyl alcohol, n-propyl alcohol, isobutyl alcohol. Experiments were conducted over a wide range of separating agent counterflow. The separation factor was approximately doubled and the yield decreased three orders of magnitude when the counterflow was increased one order of magnitude. Using the four ternary diffusion coefficients for the system and a diaphragm geometry based on previous calibration, the concentration and separation factors could be predicted within the range of experimental error. The theory indicates that at high counterflow considerably larger separation factors would be obtained if the diaphragm were uniform.
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  • 160
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    AIChE Journal 9 (1963), S. 469-474 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The absorption of carbon dioxide in pure diethanolamine was studied in a gas-liquid stirred reactor at 85°, 95°, and 105°F. Over forty runs were made but only nineteen were reported here since several were invalidated by difficulties with the stirring mechanism and reaction-temperature control. The absorption was followed by pressure-time measurements with the carbon dioxide pressure ranging between 30 and 4 cm. of mercury. Experimental data were consistent and reproducible.An equation describing the gas-liquid absorption system was derived and then simplified by considering only the kinetic region. The experimental data were correlated with the simplified equation by both integral and differential methods and indicate that the reaction follows a third-order rate equation: first order in carbon dioxide and second order in diethanolamine. A mechanism explaining the observed order is described.Justification for assuming kinetic control of the absorption was demonstrated by doubling and tripling the stirring speed which produced no significant change in the absorption rate. Also, the temperature dependence of the pseudo-rate constants was out of the range of ordinary mass transfer control. This agrees with the results of a theoretical model reported previously (6).
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  • 161
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    AIChE Journal 9 (1963), S. 507-508 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Tab.
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  • 162
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    AIChE Journal 9 (1963), S. 702-703 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 163
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    AIChE Journal 9 (1963), S. 715-718 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 164
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    AIChE Journal 9 (1963) 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 165
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    AIChE Journal 9 (1963), S. 863-863 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 166
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    AIChE Journal 9 (1963), S. 528-535 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 167
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    AIChE Journal 9 (1963), S. 755-760 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Theoretical and experimental work is described which leads to a novel hypothesis for explaining the selectivity in heterogeneous vapor phase hydrocarbon oxidation catalysis. Two essential postulates of the hypothesis are: The oxygen atoms must be distributed on the surface of a selective oxidation catalyst in an arrangement which provides for limitation of the number of active oxygen atoms in various isolated groups.The metal-oxygen bond energy of the active oxygen atoms, at the conditions of reaction, must be in a range where rapid removal (hydrocarbon oxidation) and addition (regeneration by oxygen) is assured. Monte Carlo methods are used to illustrate the distribution of isolated sites on catalytic surfaces under the dynamic conditions of hydrocarbon oxidation reactions. Differences in catalyst and process requirements between oxidation processes operating in an overall oxidizing or reducing atmosphere are discussed.
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  • 168
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    AIChE Journal 9 (1963), S. 778-782 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 9 Ill.
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  • 169
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    AIChE Journal 9 (1963), S. 590-595 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 10 Ill.
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  • 170
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    AIChE Journal 9 (1963), S. 614-619 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 171
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    AIChE Journal 9 (1963), S. 624-629 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Laminar-flow heat transfer in a cylindrical tube was studied experimentally in order to test a recent analytical method of predicting temperature profiles (1). The experimental equipment was designed to measure wall temperatures to better than 0.1°C. and to utilize small radial heat fluxes so as to minimize effects of natural convection.A series of experiments was carried out on five different types of prescribed wall heat flux with water flowing in a vertical tube. The measured wall temperatures in these experiments compared well with those predicted by the theoretical solution. Small deviations which did exist were explained in terms of experimental errors.The agreement found indicates that the analytical method may be safely used in the study of experimental data in such heat transfer and analogous mass transfer problems.
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  • 172
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    AIChE Journal 9 (1963), S. 641-645 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bubbles were formed in water when air was passed through a single square-edged orifice which had been drilled in a glass plate. The glass plate was 0.05 in. thick, and the orifice diameter was 1/8 in. The air chambers above the liquid surface and below the orifice plate were varied. The extreme values of these volumes were 0.00975 and 0.195 cu. ft. The air rate through the orifice, Q was as great as 200 × 10-5 cu. ft./sec. Bubble frequencies, f, were as great as 16 sec.-1Both the upper and lower chamber volume influenced markedly the relationship between f and Q. A relationship that predicts sets of upper and lower chamber volumes that result in the same f vs. Q relation is given. A two-parameter equation that gives f as a function of Q is presented.Wettability of the orifice plate and the liquid depth over the orifice plate were also considered as independent variables.
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    AIChE Journal 9 (1963), S. 663-671 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 174
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    AIChE Journal 9 (1963), S. 694-702 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 175
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    AIChE Journal 9 (1963), S. 715-715 
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  • 176
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    AIChE Journal 9 (1963), S. 771-777 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 177
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    AIChE Journal 9 (1963), S. 804-809 
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    Keywords: Chemistry ; Chemical Engineering
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 178
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    AIChE Journal 9 (1963), S. 810-820 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The time constant of a continuous stirred-tank reactor and the transfer function of a simulated second-order system with two random inputs were determined. In the first case the experimental result agreed within 11% of the known value; in the second case the results agreed with those predicted from a theoretical analysis. To determine the transfer matrix of a fifth-order system an impractical amount of medium speed computer time was required; the results were not considered satisfactory. However the length of calculation compares favorably with other methods of total identification for processes which have extraneous noise associated with them. Because of this the application of the present technique in adaptive control systems appears to be favorable.
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    AIChE Journal 9 (1963), S. 3-3 
    ISSN: 0001-1541
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  • 180
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    AIChE Journal 9 (1963), S. 12-19 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A stirred vessel is maintained in a quasisteady state by continuously introducing water and a conductive tracer solution and continuously removing the resulting mixture by overflow. Detailed properties of the system are elucidated by measuring tracer concentration changes with a conductivity probe in a volume element of the order of 0.3 cu. mm. By the use of suitable electronic equipment the following statistical concentration parameters are measured in experiments with three diameters of flat-bladed turbines and with a tenfold range of rotational speed: temporal mean, total root-mean-square fluctuation, spectral distribution of fluctuations, and Eulerian micro time scale. Results are interpreted in terms of behavior of time-average and fluctuation measures in three regions, the generation region within the impeller volume, the decay region which starts in the horizontal fluid sheet issuing from the impeller, and the recirculation flow region in the vessel.Generation of concentration fluctuations within the confines of the impeller is described in terms of a model involving gross mixing, without significant decay, in the wake of each flat blade. Distributions of mean and fluctuating concentrations are suggested to provide a measure of uniformity in the vessel as a whole. The former, in particular, was remarkably constant throughout the vessel.
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    AIChE Journal 9 (1963), S. 35-41 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effective scattering and absorption cross sections were determined from measurements of radiant transmission through isothermal beds of glass, aluminum oxide, steel and silicon carbide spheres, cylinders, and irregular grains. The radiant conductivities were calculated from these cross sections. Back scattering was found to be the principal mechanism of attenuation for all of the packings. Absorption was a significant mechanism only for the silicon carbide grains. At 2,000°F. The radiant contribution to the total heat flux was estimated to vary from 35% for the silicon carbide packings to 85% for the glass packings.
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    AIChE Journal 9 (1963), S. 85-88 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 183
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    AIChE Journal 9 (1963), S. 98-102 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 184
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements were made of heat transfer rates and peak heat flux for atmospheric-pressure pool boiling, and of adiabatic and diabatic friction factors, nonboiling and local-boiling heat transfer rates, and burnout heat fluxes for both axial- and twisted-tape swirl-flow forced convection of pure ethylene glycol. Test sections were electrically heated copper, 347 stainless steel, and A-nickel tubes.Both axial- and swirl-flow friction factors are in good agreement with available generalized correlations. At the higher Reynolds numbers and heat fluxes axial-flow nonboiling heat transfer coefficients show a dependence of Nusselt number on NRe0.98 rather than the traditional NRe0.80. Swirl-flow nonboling heat transfer coefficients from both the glycol data and previously obtained water data are satisfactorily correlated by a single equation. Nucleate-boiling heat transfer coefficients for both ethylene glycol and water fall approximately 50% above Kutateladze's suggested average line. The atmospheric-pressure pool-boiling peak flux is 168,000 Btu/hr. sq. ft. Forced-convection burnout heat fluxes are correlated in a number of ways, including a new additive method which appears to be generally applicable to a large variety of coolants, geometries, and flow conditions.
    Additional Material: 6 Ill.
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  • 185
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    AIChE Journal 9 (1963), S. 141-143 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 186
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    AIChE Journal 9 (1963), S. 144-144 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 187
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    AIChE Journal 9 (1963), S. 147-147 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 188
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 189
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    AIChE Journal 9 (1963), S. 183-185 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 190
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    AIChE Journal 9 (1963), S. 88-92 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 191
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    AIChE Journal 9 (1963), S. 93-98 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The permeation rate of hydrogen through cylindrical membranes of type 321 stainless steel was determined under a wide range of conditions. The pressure was varied from 0.1 to 30.0 atm. and the temperature from 300° to 800°C. Four permeation membranes were used with wall thicknesses of 0.0252, 0.1003, 0.1011, and 0.2475 cm.The permeation rate was found to deviate from the square-root-of-pressure and inverse-thickness relations predicted by the Richardson equation. Slow surface reactions are considered to be the cause of the observed deviations. The permeation data were correlated by a semiempirical interfacial resistance model.Permeation rates were observed to increase with time of membrane exposure to hydrogen. It is believed this resulted from changing surface activity.
    Additional Material: 3 Ill.
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  • 192
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    AIChE Journal 9 (1963), S. 116-120 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Enthalpies of components in ideal gas mixtures can be computed from existing data. However the isothermal effects of pressure and composition on partial enthalpies of mixture components have not been completely characterized. An investigation of the application of the Redlich-Kwong equation of state to the calculation of partial enthalpies is reported here. Methods are developed for convenient hand calculations and for computations on the IBM-650.Calculated partial enthalpies are compared with values derived from experimental P-V-T-C data for binary hydrocarbon mixtures. The calculated values agree fairly well with the derived data for pressures up to 2,500 lb./sq. in. abs. Best agreement is generally obtained when the mixture is well above the critical temperature of the more abundant component. No consistent bias was indicated however.
    Additional Material: 3 Ill.
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  • 193
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    AIChE Journal 9 (1963), S. 109-115 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Single drops supported on hypodermic tubing have been studied in a wind tunnel to determine the effect of drop oscillation on mass transfer. The systems studied for the case where internal resistance controls consisted of absorption of sulfur dioxide gas by drops of glycerine, propylene glycol, and ethylene glycol. The results may be expressed in terms of effective diffusivity.No significant effect was noted in glycerine, whereas the glycols gave effective diffusivity values two to eight times greater than theoretically calculated values of molecular diffusivities.Frequencies, amplitudes, and internal circulation velocities in the drops were studied by cinematography.The effect of oscillation on external mass transfer coefficients was studied by sublimation of naphthalene spheres in air. In the cases where the vibrational velocity was less than the stream velocity, no effect was noted; this is in agreement with heat transfer studies.A technique has been developed for studying the effect of internal circulation on effective diffusivity by the use of forced circulation through a drop suspended on hypodermic tubing. A pseudofilm thickness is determined as a function of circulation velocity and presents a means of predicting effective diffusivities for the systems studied. This technique has been demonstrated, giving results in fair agreement with the correlation of Garner and Lane.
    Additional Material: 12 Ill.
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  • 194
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    AIChE Journal 9 (1963), S. 129-133 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A digital computer model of the adiabatic-fixed bed catalytic reactor is developed which includes axial dispersion of heat and mass, interparticle heat and mass transport, and intraparticle diffusion of reacting species. The influence of these transport processes upon conversion and yield is discussed. The model is readily extended to nonisothermal, nonadiabatic cases in the absence of radial gradients.The technique of computer solution avoids the inherent instability problem associated with explicit techniques as applied to flux boundary condition problems which involve flow, diffusion, and reaction.
    Additional Material: 5 Ill.
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  • 195
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    AIChE Journal 9 (1963), S. 290-432 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 196
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dynamic response of height in liquid-solid fluidized beds to a change in fluidizing valocity was considered. A linearized model was developed such that the time constant for the system could be estimated with the parameters characterizing the system.Spherical particles, with sizes ranging from 6 to 7 to 70 to 80 mesh and densities ranging from 1.08 g./cc. to 2.5 g./cc., were fluidized by water in a 2-in. diameter glass column. The experimental response to step and rectangular pulse inputs in fluidizing velocity were measured and frequency response data were also obtained.Agreement between the experimental data and the model was quite reasonable in view of the known nonlinearity of fluidization systems. These results show that for control purposes the system behaves as a first order time constant process.
    Additional Material: 8 Ill.
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  • 197
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    AIChE Journal 9 (1963), S. 306-309 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 198
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    AIChE Journal 9 (1963), S. 316-320 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 199
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    AIChE Journal 9 (1963), S. 338-342 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 200
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    AIChE Journal 9 (1963), S. 352-358 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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