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  • 1985-1989
  • 1980-1984
  • 1960-1964  (2)
  • 1850-1859
  • 1964  (2)
  • Oxides  (2)
  • 1
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 3 (1964), S. 47-54 
    ISSN: 0570-0833
    Schlagwort(e): Oxides ; Water ; High-pressure chemistry ; Hydrolysis ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The reactions of the oxides SiO2, MoO3, and WO3 with steam at temperatures between 400 and 700 °C and pressures of 5 to 500 atm were studied by means of the transfer method. The results were evaluated by a new method. In the system Sio2/H2O the formation of gaseous Si(OH)4, Si2O(OH)6, and [SiO2(OH)2]x was found to occur in three different water-density ranges. In the systems MoO3/H2O and WO3/H2O the gaseous compounds MoO2(OH)2 and WO2(OH)2, which were already known, exist up to densities of approximately 0.05g/cm3. At higher densities, at which the supercritical phase begins to show the properties of a liquid to an ever increasing extent, isopolymolybdic or isopolytungstic acids appear.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 3 (1964), S. 669-677 
    ISSN: 0570-0833
    Schlagwort(e): Surface chemistry ; Oxides ; Carbon ; Graphite ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: On oxidation of graphitic carbon, acidic surface oxides (or hydroxides in the presence of water) are formed at the boundaries of the carbon layers. It was found that the reaction of oxygen with microcrystalline carbon at 400-450°C yields four groups of different acidities. One strongly acidic group and one weakly acidic carboxyl group have been detected, as well as a phenolic hydroxyl group; a carbonyl group is probably also present. With dissolved oxidizing agents, one equivalent of another strongly acidic carboxyl group is formed in addition at room temperature. The possible constitutions of the acidic surface oxides are discussed. Chemically detectable surface oxides are also formed on the surface of diamond. In the presence of oxygen at 800-900°C under reduced pressure, diamond is transformed into black carbon. Surface oxides play a part in this transformation.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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