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  • 1955-1959  (130)
  • 1956  (130)
  • Chemical Engineering  (130)
  • Nuclear reactions
Material
Years
  • 1955-1959  (130)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 59-62 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The chemical engineer frequently has to correlate kinetic data for heterogeneous reactions simply and accurately in order to make useful predictions of reaction rates over a range of conditions. The Langmuir-Hinshelwood approach, which is frequently used for this purpose, does not have the theoretical validity commonly attributed to it, and its use leads to unnecessary mathematical complexity. A simpler method of analysis is suggested which is based on power dependencies of the rate on concetrations, the powers being restricted to integral of half-integral values. The data for several reactions are shown to be adquately correlated by the suggested procedure, which is simple and convenient.
    Additional Material: 3 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 139-140 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 153-156 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Recent advances in purity control in sodium systems are covered. Emphasis is placed on results from the prototype S.I.R. system as well as other unpublished data. Included are chemical and nuclear activation analyses of sodium, filtration data, and details and operation of cold traps and plugging indicators.
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 169-173 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Plutonium and the fission products can be removed from irradiated uranium by liquidmetal extraction by use of another metal immiscible with uranium. Metals studied have been silver, cerium, and lanthanum. Plutonium removal by silver is high, by the rare-earth metals moderate. In all cases volatile elements, including cesium, strontium, and barium, are removed. Rare earths are efficiently removed. Ruthenium and molybdenum are largely unaffected. Experiments with synthetic fuels corresponding to long burn-up periods show improved removal of most elements. Repeated batch extractions indicate that a continuous process separating the fuel into uranium, plutonium, and fission-product fractions could be developed.
    Additional Material: 9 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 343-347 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method of estimating enthalpies of mixtures of light hydrocarbons is presented. Enthalpes so obtained are consistent with equilibrium-vaporization constants that have been correlated with the composition characterization factor, the molal average boiling point (M.A.B.P.).Values of the isothermal-pressure corrections to the enthalpy of ideal gas mixtures (H° — H) are presented on three plots with parameters of temperature, pressure, and molal-average boiling point. Pressures range from zero to 1,500 lb./sq. in. abs., temperatures from -200° to 500°F., and M.A.B.P. from -200° to 150°F.
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 359-362 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Visual observations by Fage and Townend of the behavior of a turbulent-flow strean near a boundary and experimental data by Lin, Moulton, and Putnam of concentratiol profiles near a boundary contradict the commonly held concept of the “laminar sublayer.” A model developed by Higbie and Danckwerts which is consistent with the visual obser vations of Page and Townend is used to describe the exchange of mass and heat between a turbulent fluid and a solid surface. It is postulated that masses of fluid are contiuously moving to and from the wall. The exchange process then depends on the average contact time of these fluid masses with the wall.The agreement of the concentration profile predicted on the basis of the proposed model with experimental mass transfer data where the exchange process is rate controlling lends support to the usefulness of the model. No equivalent data are available for velocity profiles. Velocity data represent a condition where the transport process within the fluid is playing an important role; however, in the immediate vicinity of the wall the proposed model might serve as a rough approximation of the profile. Such an approximation is made in this paper, and the agreement obtained is much better than should be expected.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 372-380 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measuring the spreading of a tracer dye from a point source yields information on diffusion in glass-sphere beds fluidized in water. Particulately fluidized beds, which are here formed, are well described by the statistical turbulence equations of Taylor. Mixing parameters - eddy diffusivity, scale, and intensity of turbulence - are established. Transition of these variables is traced from fixed beds through fluidized beds in different degrees of bed expansion.Mixing characteristics of these “ideal” types of fluidization may provide a frame of reference for consideration of more complex systems.
    Additional Material: 18 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 393-403 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 10 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 412-419 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study of rates of dissolution of organic solid from a flat surface into turbulent liquid in a mixing tank of 6 in. I.D. is reported for five systems - benzoic acid-n-water, salicylic acid-water, salicylic acid-benzene, succinic acid-n-butanol, and succinic acid-acetone. Previous theories for the rates of mass transfer are reviewed and compared, and experimental results analyzed and correlated by an equation in terms of dimensionless groups similar to that of Hixson and Baum, Sherwood and Gilliland, and Rushton and Oldshue. The close agreement between the theoretical and experimental values of the exponent of the Schmidt number in this equation may provide new and significant evidence for the applicability of the surface-renewal theory to mass transfer from a flat solid surface into a turbulent liquid.For free rotational agitation, a local mass transfer coefficient with respect to the position of a cast solid was detected quantitatively. However, the insertion of four baffles into the tank gave a uniform mass transfer coefficient regardless of the position of the cast solid. A decrease in the mass transfer coefficient was observed when baffles were used.The advantages of the constant and stationary interface, the stability and simplicity of the apparatus, the possibility of duplicating experimental results, and the success of the detection of a local mass transfer coefficient suggest that the present apparatus and procedures could be used for the study of the theory of mass transfer rates from flat surfaces.
    Additional Material: 12 Ill.
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  • 11
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 420-425 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The terminal velocity of air bubbles rising through distilled water, 61% glycerine, diethylene glycol, and a solution of a surface-active agent was measured in vertical cylindrical tubes of 2.09, 3.64, 4.91, 6.90, 9.50, and 15.25 cm. avg. I.D. An equation was developed to express a velocity-correction factor in terms of the ratio of bubble diameter to tube diameter and an empirical constant. The constant was a function of tube diameter and of the surface tension of the liquid. It seemed to be independent of liquid viscosity.
    Additional Material: 10 Ill.
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  • 12
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 463-467 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method for estimating adsorption equilibria based on a modification of the Polanyi adsorption-potential theory was developed for use in the investigation described in Part I of this article. In addition, the recently published correlation method of Lewis, Gilliland, Chertow, and Cadogan, suitably modified for the present application, was successfully employed in the correlation and extrapolation of the ternary equilibrium data.
    Additional Material: 5 Ill.
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  • 14
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 468-470 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rates of both the liquid-phase mass transfer and the internal-diffusion steps in ion exchange were studied by means of shallow-bed experiments. The mass transfer coeffcients obtained fitted the general correlations for other packed-bed operations when the Schmidt group was evaluated with experimentally determined ionic counterdiffusivities. An incremental calculation of the diffusion rates within the particles yielded a value of the counterdiffusivity in the resin phase. A general design procedure based on these findings is proposed.
    Additional Material: 3 Ill.
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  • 15
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 477-481 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The theoretical-plate concept in chromatography has been treated on the basis of continuous flow of eluent through the plates of the column. A treatment more precise in principle than the previous treatments is presented. General elution and deposition equations have been derived and applied to special cases of practical interest. The derived formulas have the advantage of precision, generality, and simplicity.The theory was found adaptable to the treatment of gradient elution and also to the calculation of the fraction of solute which has been eluted or still-adsorbed on the column during the elution process.A method for the determination of the number of theoretical plates in a chromatographic column is also described.
    Additional Material: 2 Ill.
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  • 16
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 489-497 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect on point and integral average conversion of chemical reaction, coupled with radial diffusion and radial distribution of reaction times in viscous-flow tubular reactors, is reported. Solutions are given for first-order reaction over an extensive range of dimensionless rate and time variables. An expression is given for a criterion of the conditions when the contribution of diffusion is so small that it may safely be disregarded as a variable. Another criterion also is given for the situation when diffusivity is so large, in comparison with other system constants, that the simple plug flow solution may be used without incurring more than a specified error.The hydrolysis of acetic anhydride was studied in 1/4- and 1/2-in.-diam. reactors in 10- and 15-ft. lengths. Reynolds numbers were between 40 and 400 and temperatures between 25° and 35 °C. It was found that the derived equations form a proper description of experiments in the smaller tube. Deviations from theory in the larger tube are explained in terms of free convection arising from nonisothermal conditions and from concentration gradients in the tube. Grashof criteria for initiation of convection in the system are discussed.
    Additional Material: 11 Ill.
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  • 17
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 518-524 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper reports a direct experimental comparison of the cracking of cumene in a fluidized bed of silica-alumina catalyst with the same reaction in a fixed bed. The effects of fluidization on the kinetics of this reaction are interpreted in terms of an empirical approach using effectiveness factors and by a simplified mathematical model.
    Additional Material: 10 Ill.
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  • 18
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 525-528 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An empirical method is suggested which permits the prediction of vapor-liquid equilibrium data for binary hydrocarbon mixtures at various total pressures on the basis of equilibrium data at one constant pressure. This method has been tested with the vapor-liquid equilibrium data of six nonideal systems measured at twenty-one different experimental conditions. The total pressure range varies from 50 mm. of mercury to 4 atm. In all cases the predicted results are in good agreement with the experimental data.
    Additional Material: 6 Ill.
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  • 19
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 539-544 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 20
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 21
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 38-41 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A procedure for obtaining equilibrium data and predicting ideal-stage requirements in a complex liquid-liquid extraction system is presented. Preliminary equilibrium data are obtained from a simulated column run involving a series of batch contacts operated in such a manner as to approach steady state countercurrent conditions. The flow ratios and stage requirements for continuous operation are then estimated by trial-and-error by use of a modified McCabe-Thiele method.The procedure lends itself particularly well to those systems with interdependent distribution of the two components. Data for the separation of hafnium from zirconium are presented to show the utility of the method.
    Additional Material: 9 Ill.
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  • 22
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 62-64 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The wide applicability of the Langmuir-Hinshelwood classical kinetics to surfaces which are known to depart strongly from ideal Langmuir behavior is a well-known paradox of surface catalysis. The applicability and limitations of the classical method are illustrated by means of a simple reaction. The generality of the method is demonstrated by its applicability to ammonia synthesis with and without water vapor. The limitations are often more than compensated for by the added insight into reaction mechanism which it can provide without unded complexity. A three-step approach to surface kinetics is suggested and discussed.
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  • 23
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 71-74 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An equation for correlating regeneration process variables in fluid-catalytic cracking has been developed from pilot plant data. This equation takes into account not only the chemical-reaction rate for burning coke deposited on the catalyst but also the diffusional resistance to oxygen transfer. The resistance presumably occurs between the bubbles within the fluidized bed and the void spaces in the relatively denser mass of particles. The coefficient of mass transfer was found to be inversely proportional to the 1.5 power of the average particle diameter and directly proportional to the square of the gas mass velocity. The specific reaction-verlocity constant was found to be a function to temperature and catalyst activity as well as the nature of the feed from which the coke was deposited. Comparison of pilot plant data with commercial data suggests that nonuniform gas distribution in larger beds makes some of the catalyst ineffective.
    Additional Material: 5 Ill.
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  • 24
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 88-93 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical equation is presented for predicting the specific heat at constant volume and constant pressure of organic liquids as a function of temperature from data on the velocity of sound, infrared and Raman spectra. By use of this equation, the average deviation of the calculated from the experimental values of specific heat for 100 organic liquids at 68°F. is ±1.5%.An alternate correlation for hydrocarbon liquids based on a modified statement of the theory of corresponding states is also presented. Based on it, the average deviation of the calculated from the experimental values for 100 points representing the entire temperature range is ±0.9%.
    Additional Material: 6 Ill.
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  • 25
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 107-112 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Although vacuum crystallizers are used widely, crystal-size-control methods have not been adequately analyzed. This paper supplies in part the deficiency of technical information on this problem. Industrial crystallizers may have inherent nucleation rates in excess of or below the seed-crystal requirement for the desired product-crystal size. This paper deals specifically with means of crystal-size control by removal of excess nuclei from mixed circulating suspensions as encountered in vacuum crystallizers. It is shown that under certain conditions the cumulative size distribution in the suspension varies as the fourth power of the size. Therefore, it may also be shown that the key to effective size-control procedures is the segregation time of nuclei in the fines-removal system. Procedures based mainly on crystal-size classification by hydraulic elutriation can hardly be effective unless they are also designed to meet the segregation-time requirements.
    Additional Material: 7 Ill.
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  • 26
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 139-139 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 27
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the proposed system for counting variables in separation processes the processes are resolved into their simpler component classes, e.g., theoretical plates, heat exchangers, reboilers, distillation columns, etc., and a distinction is made between those variables which are inherent in the systems and those which may be specified for design. Results are presented for the most commonly occurring component classes, and all possible process relations existing among these classes are expressed by a set of generalized equations [(16) to (19)]. The procedure of counting variables is therefore reduced to compositon from variables for the component classes by use of the generalized equations.
    Additional Material: 4 Ill.
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  • 28
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 498-507 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Direct enthalpy measurements were carried out for the methanol-benzene system as a function of composition, temperature (250° to 500°F.), and pressure (30 to 1,400 lb./sq. in. abs.). From these data pressure-enthalpy diagrams were prepared to show the enthalpy and entropy above a reference state of saturated liquid at 77°F. Similar results were obtained for a single binary system of methanol and n-hexane and a single ternary mixture.The conventional generalized correlations were not satisfactory for predicting vapor-phase enthalpies for mixtures involving methanol. A new method requiring a knowledge of the heat of dimerization, the equilibrium constant for the reaction, and the interaction constant, is proposed for such polar-nonpolar systems based upon association of the polar component.The most striking feature of the data for mixtures was the large heat of mixing in the vapor phase for the systems containing methanol. The same type of equation found suitable for the heat of mixing in the vapor phase was applicable to the liquid data.From the enthalpy data across the two-phase region, it was possible to predict a limited amount of information on the compositions of the liquid and vapor phases in equilibrium. An azeotrope exists in the methanol-benzene system, which at 325°F. contains 75 mole % methanol.
    Additional Material: 15 Ill.
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  • 29
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 226-234 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer was measured for water flowing parallel to 5/8-in. rods in a triangular lattice (0.914-in. spacing). Velocity was varied from 5 to 20 ft./sec., temperature from 150° to 325°F., and heat flux from 50,000 to 200,000 B.t.u./(hr.)(sq. ft.). Reynolds numbers ranged from 70,000 to 700,000. Coefficients were 40% higher than predicted from the Colburn equation for flow in pipes by use of the equivalent diameter. The effect of heated length was studied. No variation in local coefficient around the rod periphery was found. Pressure drops were 65% higher than predicted by the Fanning equation (by use of De).
    Additional Material: 10 Ill.
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  • 30
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 17J 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 31
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 20J 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 32
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 34-37 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the usual method of calculating the solvent extraction of complex mixtures it is assumed that the complex mixture behaves like a binary mixture. However, the hypothetical binary composition of the mixture is never explicitly used; rather, an additive property of the mixture is used as an indication of its composition. The calculation must be done graphically on a triangular diagram or its equivalent.On the assumption that the complex mixture consists of only two hypothetical components, empirical equations have been arrived at relating the distribution coefficients of these two components and of the solvent to the phase compositions. These equations contain three arbitrary constants. By use of the data from a minimum of three simple laboratory batch extractions of a given complex mixture, the three constants, plus the hypothetical binary composition of the original complex mixture, can be determined.With the equations for the distribution coefficients, the equilibrium curve and tie lines for the system can be calculated. Properties of the raffinates and extracts can be measured and related to the hypothetical binary compositions of these mixtures.The use of the method is demonstrated by comparing calculated results with laboratory yields and properties. The calculated results show good agreement with the experimental results. Calculations can be carried out not only on the triangular diagram, but by any of the other graphical methods that have been developed for the solvent extraction of binary mixtures. Equally important, calculations can be done analytically, and therefore the use of automatic computers is feasible.
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  • 33
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 55-58 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The physical processes are discussed by which a fluid is displaced from a porous medium during steady state viscous flow by another fluid of the same density and viscosity under conditions of complete miscibility of the two fluids. The displacement occurs on a microscopic scale as a result of combined convective and diffusional mixing. The length of the zone of mixing which comprises the displacement front is predicted to be dependent upon the rate of flow, the diffusion coefficient for the two-fluid system, the characteristics of the pore geometry, and the distance the front has traversed at the time of its observation.Experimental data are presented for the displacement of benzene by ethyl n-butyrate at several rates of flow from packed sand columns. These data show that the length of the frontal mixing zone after a prescribed distance of flow is greater at the higher rates of flow. The postulated dependence of the length of the front upon the diffusion coefficient and the pore geometry has not yet been investigated.
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  • 34
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    AIChE Journal 2 (1956), S. 74-78 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Internally agitated extraction columns generally require increasing heights for a theoretical state for the larger column diameters. The present work describes a design developed to minimize this objection and presents the performance data on a system considered easy to extract and on systems considered difficult to extract. H.E.T.S. values as low as 3 in. on the first system and 4 in. on the second type of system were obtained in an 11½ in I.D. glass column. The stage efficiencies were correlated as a function of power input per unit volume of solvent throughput and the ratio of the flow rate of the dispersed phase to that of the continous phases. The supplementary effect of packing was studied and found to be most beneficial in the system which has a low interfacial tension and is considered easy to extract. By the use of this particular arrangement of internal baffles, it is believed possible, in the larger diameter columns, to reduce the height to a ratio of H.E.T.S. to diameter below the value of ¼ obtained in the present column.
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  • 35
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    AIChE Journal 2 (1956), S. 184-189 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rate of mass transfer was measured for solid metal shapes dissolving into mercury at room temperature. Sherwood numbers for horizontal tin, cadmium, zinc, and lead cylinders dissolving by natural convection agreed with Nusselt numbers for heat transfer in nonmetallic liquids at the same Rayleigh (Grashof × Prandtl) numbers. Dissolving of zinc tubes by mercury flowing turbulently within them agreed with heat transfer to nonmetals in tubes. Dissolving of random beds of lead spheres by mercury flowing through the bed agreed with similar nonmetal systems. It is concluded that mass transfer processes in liquid metals follow substantially the correlations for other fluids in heat or mass transfer, which with moderate safey factors may thus be used for at least preliminary design purposes.
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  • 36
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    AIChE Journal 2 (1956), S. 215-218 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The design and operation of a windowed autoclave suitable for studying corrosion of materials by pressurized hot water are described. The technique for taking time-lapse motion pictures of a specimen from the instant of contact with the high-temperature water until the corrosion is complete is explained, and a set of typical pictures is presented showing the progress of the attack. Pressure and temperature measurements provide a means for rough computation of corrosion rates, as is shown by the results of two tests of uranium specimens subjected to pressurized hot water.
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  • 37
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 20J 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 38
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    AIChE Journal 2 (1956), S. 283-289 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The operating characteristics of a Podbielniak model 5,000 centrifugal extractor, having a combined-stream capacity of 450 cc./min. at 5,000 rev./min. and a rotor holdup of 529 cc., were investigated. Variables studied were density difference, rotor speed, light-liquid-out pressure, flow rates, holdup, and number of stages.A technique for holdup determination that comprises displacing either phase in the extractor with the other phase is described and experimentally demonstrated. An equation useful in predicting flooding limits is verified. It is suggested that the effective values of the rotor dimensions in this equation be determined by the behavior of the extractor.A relationship among number of stages, light-liquid-out pressure, and flow-rate ratio is demonstrated by extracting boric acid from isoamyl alcohol with water. With only a few runs this relationship should permit one to map in a family of curves for a particular system and thus rapidly to estimate optimum operating conditions.A procedure is outlined for applying the methods to other systems using similar extractors. First the constants in an equation are estimated from holdup measurements in order to predict flooding limits. Then a few extraction runs are made to estimate optimum operating conditions.
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  • 39
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    AIChE Journal 2 (1956), S. 290-295 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Three viscosity correlations were tested for liquids at their boiling points. Compounds studied included normal paraffins, branched-chain hydrocarbons, aromatics, halogenated methanes and ethanes, water, and aliphatic alcohols. The correlations were tested for the most part with viscosity and thermodynamic data found in the literature. Some experimental viscosity measurements were made, however, for normal paraffins from pentane to octane at temperatures up to about 300°F., which is higher than has previously been reported.Two correlations are based on Eyring's theory of absolute reaction rates. The third is based on the compressibility factor of the saturated liquid, and this correlation is unique, as all available data for normal paraffins with eight or more carbon atoms are represented by a single curve. The three correlations presented here can be used to extrapolate viscosity data over large temperature ranges up to the critical temperature. Logical predictions of the viscosities of related compounds are possible.
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  • 40
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study has been made of the rate of flow and mechanics of bubble formation from single submerged orifices 1/64, 1/32, 1/16, and 1/8 in. in diameter installed in an 8-in. I.D. column operating in the air-water system. The coefficients of discharge obtained for sharpedged orifices operating with this system indicate that the effective orifice discharge area for this type of operation is greater than that for an orifice of the same size and type operating at the same pressure ratio in the air-air system. The effective orifice discharge areas for a round-edged orifice operating in either the air-water or air-air systems appear to be identical at the same pressure ratio. The thick-plate orifice operating in the air-water system exhibits a constancy of discharge coefficient at ratios of the downstream to upstream pressures less than 0.33. Inasmuch as bubble formation occurring close to the downstream face of a sharp-edged orifice operating in the air-water system influences the effective orifice discharge area, liquid physical properties may be expected to be important in determining the rate of flow from this type of orifice for other gas-liquid systems.In Part II photographic studies of bubble formation reveal that nonuniformity of bubble size is initiated by the onset of turbulence in the air stream flowing through the orifice. In the section of the laminar-flow range studied in this investigation (200 〈 NRe 〈 2,100) the frequency of bubble formation is nearly constant with respect to Reynolds number. The bubble size is relatively uniform at a given Reynolds number and depends markedly upon orifice diameter. Stroboscopic examination reveals that as turbulence is fully developed for the air flow through the orifice, a counterclockwise spiraling, swirling motion of the air jet is initiated. In the turbulent-flow range the bubblesize-distribution data are fitted reasonably well by a logarithmic-normal-probability distribution. More data for bubble formation in other liquids (particularly liquids of low surface tension) are necessary before a general correlation for bubble size in gasliquid systems can be developed.
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  • 41
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    AIChE Journal 2 (1956), S. 429-429 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 42
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    AIChE Journal 2 (1956), S. 437-443 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The film theory of liquid-side resistance to gas absorption, embodying the assumption of a thin stagnant liquid film adjacent to the interface in which steady state diffusion occurs, has long been open to question, particularly in packed columns. Higbie's penetration theory, believed to be more reasonable, pictures the liquid as flowing over a piece of packing for a very short period of time before being mixed as it flows to the next piece of packing. In the penetration model absorption occurs during a series of brief contacts, and unsteady state mass transfer conditions prevail in the liquid.Several short glass-wetted-wall columns 1.9 to 4.3 cm. long were constructed to simulate the assumptions of the penetration theory. Because of the short length ripples were absent except when the gas rate was higher than ReG = 2,200. The desorption of carbon dioxide from water and of chlorine from dilute hydrochloric acid (0.16 to 0.18 N) was studied. The desorption rate of carbon dioxide was unaffected by gas velocity up to ReG of 2,200 and increased 1.1%/°C. over the temperature range of 22° to 31°C.
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  • 43
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    AIChE Journal 2 (1956), S. 448-450 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 44
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    AIChE Journal 2 (1956), S. 12D-12D 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 45
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  • 46
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    AIChE Journal 2 (1956), S. 12D-12D 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 47
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    AIChE Journal 2 (1956), S. 12D-12D 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 48
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    Notes: In this paper extensive calculations on the quasi isothermal tubular reactor are presented. Temperature and concentration profiles were obtained on an analogue computer (R.E.A.C.). The calculations tend to show that there are regions of operation in which the reactor effluent is very sensitive to operating conditions. For example, it is shown that in some regions of operation a small change in the heat transfer coefficient at the reactor wall or a small dilution of the feed will produce large changes in the effluent. In such cases the reactor is said to exhibit parametric sensitivity. It is shown analytically that this sensitivity may be predicted by analyzing the frequency response or transient response of the reactor approximated by a local linearization. This linearization requires complete solutions of the steady state problem. Semiquantitative results are then obtained for the regulation required from a given specification of product limits. The frequency-response analysis should be useful in connection with the control problem.If the reactor is fed partially with a recycle stream, then experience with electrical systems indicates that the possibility of instability exists. It is shown that at least theoretically these instabilities do exist, and a method based on the transfer function is developed for derivation of criteria of stability or instability.
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  • 49
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    AIChE Journal 2 (1956), S. 190-194 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Extensive pilot plant studies of the continuous, mercury-catalyzed nitric acid dissolution of uranium-aluminum alloy materials similar to possible reactor fuel elements were carried out. Marked differences were observed in the dissolution rates of cast and wrought alloys. Optimum feed-acid concentrations varied with the type of alloy. At constant acid feed conditions dissolving rates varied approximately with the cube root of catalyst concentration up to a limiting concentration. The metal dissolving rate was proportional to the 0.8 power of the nitric acid feed rate. A general empirical correlation was developed.
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  • 50
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    AIChE Journal 2 (1956), S. 428 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 51
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    AIChE Journal 2 (1956), S. 471-476 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The photographic method was used to measure bubble sizes and frequencies for methanol boiling at atmospheric pressure outside a 3/8-in. O.D., steam-heated, horizontal copper tube. The average temperature of the tube was measured by use of the tube as a resistance thermometer. For nucleate boiling at heat fluxes up to 80% of the maximum, the product of bubble diameter and frequency was constant at 4 in./sec. In this region both the Rohsenow equation and the Forster-Zuber equation gave good predictions of the heat transfer. At higher fluxes the product f × D increased and the equations were much less suitable. The critical temperature difference for copper to methanol was not a single value but was a region extending from 52° to 62°F. The heat flux was nearly constant throughout this range at a maximum of 115,000 B.t.u./(hr.)(sq. ft.). For film boiling, f × D was nearly constant at 11 sec.-1 Bromley's equation was unsuitable for ΔT values less than 180°F., but it became applicable at this ΔT. The use of Nusselt's equation for steam condensing inside the tube was found to be satisfactory, proof that the slight slope of the tube was sufficient to permit adequate condensate drainage.
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  • 52
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    AIChE Journal 2 (1956), S. 482-488 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A fluidized-bed heat transfer mechanism is proposed that assumes that the chief resistance to heat exchange between a confining wall and a fluidized bed is in the laminar film at the vessel boundary. Heat flow through the film is by conduction. As the solids-particle velocity along the wall will modify film thickness, correlation of film coefficients in terms of particle velocities or the equivalent suggests itself. That heat transport from the boundary of the heating element to the fluidized core proceeds by way of turbulent solids mixing seems indicated by the considerable effect that the solids heat capacity appears to exert on over-all coefficients.The resulting correlation is examined critically in relation to pertinent literature data. The effect of fluidized-bed parameters on heat transfer coefficients is considered, and applicability and limits of the correlation are ascertained.
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  • 53
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    AIChE Journal 2 (1956), S. 3-12 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data on liquid entrainment are reported for rectangular-cap bubble trays on 24-in. tray spacing for an air-water system. Several tray variations were studied, and entrainment is given for trays containing eight, twelve, and sixteen caps a tray. Some hydraulic characteristics (pressure drop, liquid backup, minimum vapor velocity, and downflow froth height) are also reported. It was found in this study that decreasing liquid path lenght increased the entrainment from a bubble-cap tray and increasing tray bubbling area decreased entrainment. It was also found that decreasing slot area generally had no effect on liquid entrainment over the range investigated.
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  • 54
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data correlations are presented for equilibrium adsorption of pure hydrocarbon vapors and their mixtures. The systems represented are C1 to C4 hydrocarbons (olefins and paraffins) on gas-adsorbent grades of activated charcoal. The mixture data are limited to binary and ternary gas systems. The adsorption conditions represented among the correlated data cover ranges of 77° to 175°F. temperature and 0 to 100 lb./sq. in. gauge. With the use of empirical adsorption constants, a common correlation of specific adsorption capacity for the various hydrocarbons is presented; it applies for either pure components or their mixtures. A correlation is given also for adsorption relative volatilities. Approximate adsorption heats, a limited amount of high-temperature steam adsorption data, and sample calculations on applications of the correlations are included. The prediction methods are recommended for adsorption conditions up to 250°F. and 250 lb/sq. in. gauge for the particular systems studied.
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  • 55
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    AIChE Journal 2 (1956), S. 177-183 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Knowledge of local heating rates is needed for estimation of operating temperatures, thermal stresses, and cooling requirements in nuclear reactor components. Heat is liberated by the dissipation of the energy of fission fragments, beta particles, fast neutrons, and gamma photons. Heating rates are formulated in terms of either neutron or gamma flux densities, the corresponding collision probabilities, and appropriate energy transfer coefficients, the forms of which are given. Special methods of estimating the flux densities are discussed. The data on the magnitudes of the various energy sources are reviewed.
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  • 56
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    AIChE Journal 2 (1956), S. 195-198 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Diffusion rates of uranium through graphite were determined in the temperature range of 3,000° to 4,350°F. The diffusion couples consisted of sintered UC2 disks in contact with graphite rods. The observations indicated two distinct types of uranium transport which could be associated with volume diffusion and with migration along pores respectively.Volume diffusion was characterized by steep concentration gradients and shallow penetration. The diffusion coefficient Dv, in sq. cm./sec. between 3,300° and 4,250°F., is given by an equation. Above 4,250°F. incipient melting of the UC2 was evident and the diffusion coefficients were much higher than those given by the equation.As an example of the penetration resulting from volume diffusion, calculations show that, after 1,000 hr. at 4,200°F. the uranium concentration at 0.1 cm. from the interface will be 1,000 mg./cc., compared with 10,000 mg./cc. for pure UC2.Pore migration resulted in uranium penetration far beyond that arising from volume diffusion at equivalent temperatures and diffusion times. However, uranium concentrations were very small compared with those corresponding to volume diffusion. Pore migration is strongly temperature dependent.To estimate the practical importance of pore migration, the uranium flow through a graphite wall at 3,000°F. was measured. With a wall thickness of 0.32 cm., the average flow per unit area was 0.015 mg./ (sq. cm.)/ (hr.) for a 40-hr. test.
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  • 57
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    AIChE Journal 2 (1956), S. 249-250 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Natual and forced convection have always been correlated on different bases although the two phenomena have much in common. Accordingly, a method for correlating both types of convection on the same basis, at least for heat transfer outside horizontal cylinders, would be of interest.A tentative method of accomplishing this for transverse convection is presented, involving certain simplifying assumptions relating to drag and buoyancy, from which an “effective velocity” for natural convection is calculated (by means of the well-known drag correlation) and incorporated in a Reynolds number. The Nusselt number for natural convection is then correlated in terms of the Prandtl number and this Reynolds number in much the same manner as that for McAdams's well-known correlation for forced convection. For 150 different combinations of independent variables covering seven different fluids and wide ranges of diameter, surface temperature, and bulk fluid temperature, the transformed natural-convection data agree with Douglas and Churchill's recent refinement of McAdams's relationship for forced convection with an average deviation of about ±10%.
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  • 58
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    AIChE Journal 2 (1956), S. 271-272 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method, based upon the pertinent flat-plate heat transfer equation, is presented for computing the local heat transfer coefficients for a boundary layer subjected to streamwise velocity and pressure gradients. No extensive mathematical background is required as the complexity of a rigorous solution for this type of problem is avoided. The validity of the method for gases is demonstrated by comparison of the predicted coeffcients with the experimental data for two widely different problems.
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  • 59
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    AIChE Journal 2 (1956), S. 273-276 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Because little information is available concerning the behavior of hydrocabons under conditions far from equilibrium, it appears desirable to obtain data for the diffusion coefficients of the lighter hydrocarbons in the gas phase.The Maxwell diffusion coefficients of n-heptane in the gas phase of the ethane-n-heptane and propane-n-heptane systems were measured at temperatures from 100° to 220° F. and for pressures up to 60 lb./sq. in. The fick diffusion coefficient was calculated as a function of state from these measurements.The experimental results indicate that the interfacial resistance between the liquid and the gas phases into which the transport was taking place is small. It was found that pressure exerted a significant influence upon the Maxwell diffusion coefficient for both of the binary systems investigated. There is a marked decrease in the Maxwell diffusion coefficient with an increase in molecular weight of the stagnant component.
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    AIChE Journal 2 (1956), S. 141-141 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 61
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    AIChE Journal 2 (1956), S. 157-162 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A natural-circulation loop with water as the circulating fluid was studied for a range of operation covering two-phase flow. The work reported in this paper is concerned with the periodic oscillations of the flow rate and fluid temperature. The oscillations occurred even with constant heat input and constant cooling-water properties for the heat exchanger. The analytical approach includes a theoretical analysis of an open-ended system and numerical solutions obtained with an analogue computer for a simplified loop system. Also presented are the equations of motion, continuity, and energy, which were developed for a transient two-phase flow model for adaptation to more detailed numerical evaluations.
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  • 62
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    AIChE Journal 2 (1956), S. 173-176 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The attractive nuclear properties of zirconium make it a highly desirable core material for sodium-cooled reactors. The elevated temperature strength while low is sufficient for certain applications. Development of higher strength alloys is underway. Sodium in itself is completely compatible with zirconium; however, the nonmetallic contaminants, namely oxygen, hydrogen, and nitrogen, can effect serious damage. The primary problem in the use of zirconium in a sodium system, then, lies in controlling these impurities in the sodium.
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  • 63
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    AIChE Journal 2 (1956), S. 264-270 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of chemical reaction on plate efficiency has been given little attention in the determination of bubble-plate efficiencies, although it is of importance in many operations. A typical example is the absorption of carbon dioxide in monoetnanolamine solutions.The over-all Murphree gas-phase plate efficiency can be shown to be a function of Kg(A/V) where A/V is the interfacial surface area formed per tray per unit volume of gas. In order to evaluate variations in tray efficiency due to factors influencing Kg, data available in the literature for the absorption of carbon dioxide in monoethanolamine were considered. These showed that the liquid film was controlling and that for a packed column at constant liquid rate the absorption coefficient could be satisfactorily expressed by an equation that resembles somewhat equations which have been developed for the effect of rapid secondorder reactions on kL. However, the observed effect of carbon dioxide partial pressure in the gas is not so great as the theoretical equations would predict.By use of the equation mentioned above to predict Kg, satisfactory correlation of observed plate efficiencies is obtained for a commercial column over a considerable range of conditions. It appears that the correlation can be extended to other pressures, flow rates, and column designs by an evaluation of the effect of these variables on A/V and Kg.
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  • 64
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    AIChE Journal 2 (1956), S. 280 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 65
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    AIChE Journal 2 (1956), S. 18J 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 66
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 67
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    AIChE Journal 2 (1956), S. 307-315 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The internal structure of various types of filter media and the nature of fluid flow through them are examined. Methods of characterizing the internal pore structure of filter media are reviewed, and the permeability, bubble-pressure, and mercury-intrusion methods are applied to ten typical media, with resulting values of average and maximum pore radius and pore-size distribution being reported. These data on internal pore structure are related to the construction variables characteristic of the media examined, in particular the effect of yarn construction, yarn twist, fabric weave, and fabric finish on textile-type filter media.
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  • 68
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    AIChE Journal 2 (1956), S. 337-342 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Air bubbles were formed in water and in mineral oil by use of single, circular, horizontal, square-edged orifices facing upward. Twenty orifices were tested, ranging from 0.017 to 0.79 cm. (0.0067 to 0.31 in.) in radius. Incieasms the whime, of the gas chamber below the orifice (over the range of 4 to 4,000 cc.) was found to increase the bubble size. The gas-chamber volume was minimized in most of the work in order to confine attention to the effects of orifice size and gas-flow rate. The liquid containers were large enough to eliminate significant wall effects, and operations were conducted at atmospheric pressure.The gas-flow rate was varised from about 0.01 to about 250 cc./sec. over the course of the work. At relatively low rates, the orifices generally formed single “static” bubbles, the volumes of which were proportional to the surface tension and orifice radius and independent of the gas-flow rate. At high flow rates the bubble frequency became high and the bubble volume became proportional to the gas-flow rate and independent of the surface tension. The bubble frequency reached a maximum value for each orifice, this value being a function of the orifice radius. For air bubbles in water, the correlation of the maximum bubble frequency, nm bubbles/sec., with the orifice radius, r cm., and the air-flow rate, q cc./sec., was found to be nm = 9.1q0.13/r0.43. The maximum frequencies ranged from about 25 bubbles/sec. for the largest orifices to about 75 bubbles/sec. for the smallest orifices used.It was found that consecutive bubbles paired or coalesced in definite ways in certain ranges of the gas-flow rate. A description is given of this bubble behavior, based on stroboscopic and photographic observation.
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  • 69
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    AIChE Journal 2 (1956), S. 347-353 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A rigorous analysis of the available data presented in the literature for all the saturated aliphatic hydrocarbons from methane through n-eicosane was conducted to establish the constants A, B, C, and D of the vapor-pressure equation developed by Frost and Kalkwarf (21). With all the constants determined, vapor pressures can be calculated accurately from the triple to the critical point. The actual constants A, B, C, and D have been calculated from the available reported vapor-pressure data of eighty-seven saturated aliphatic hydrocarbons and include all the normal paraffins through eicosane and all the isomeric paraffins through the nonanes.In order to ascertain the validity of calculated-vapor-pressure constants, values of A, B, C, and D were produced from the molecular structure and normal boiling point for all the normal paraffins through eicosane and all the thirty-four isomeric nonanes. The normal paraffins were selected to cover the range of the saturated aliphatic hydrocarbons; whereas the nonanes were chosen because they represent the most complex structures for which reported vapor pressures are available.With the calculated constants, vapor pressures were evaluated from the equation at several representative points and were compared with reported values to produce an overall absolute average percentage of deviation of 0.58 for the normal paraffins and 0.73 for the isomeric nonanes, or 0.68 for these fifty-four saturated aliphatic hydrocarbons.
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  • 70
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    AIChE Journal 2 (1956), S. 381-384 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The removal of a trivalent ion (Fe+++) from acidic nitrate solutions by a fixed bed of Dowex-50 cation-exchange resin was studied at entering iron concentrations from 14 to 4 meq./liter, flow rates of 0.073 to 1.20 liters/(hr.)(sq. cm.), and bed sizes from 3.7 to 5.4 g. of dry resin/sq. cm. Acid strengths were below 0.45 N. The results were correlated is a relatively simple break-through equation based on the assumptions of an equilibrium extremely favorable to iron adsorption and liquid-film diffusion being the rate-controlling factor. The capacity of the resin for iron was dependent upon the acid concentration of the sulation.The results provide a design equation requiring a minimum of experimental work.
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  • 71
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Various methods are known for interpreting experimental data for linear-equilibrium cases or constant-pattern break-through curves where either external or internal diffusion alone controls the rate in the ion exchange column. The present paper provides interpretive techniques for nonlinear equilibrium cases where the rate is controlled by a combined diffusion mechanism. The techniques can be applied whether or not the value of the equilibrium constant is known.A completely general correlational method is derived for adding the mass transfer resistances under conditions of nonlinear equilibrium. Published break-through results from numerous sources and from new measurements, evaluated by the techniques described, are used to determine the numerical constants for the general correlation.
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  • 72
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    AIChE Journal 2 (1956), S. 426-427 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 73
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    AIChE Journal 2 (1956) 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 74
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    AIChE Journal 2 (1956), S. 431-436 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Chemical equilibrium in this reaction has been determined experimentally by a static or nonflow method at temperatures of 400° and 450°C. and at pressures of 1,000 to 3,500 atm. Equilibrium was approached from both sides and the two reacting gases were always in the stoichiometric ratio. The results are presented both as mole percentage of ammonia in the equilibrium mixture and as the equilibrium constant Kp. The constant, Kp, which is a function of pressure, was calculated from Kp°, its value at p = 0, by five different methods and from them the corresponding mole percentages of ammonia were derived for comparison with the experimental results. All such calculations involve assumptions of varying degrees of validity, and no calculated value can be considered accurate. However two of the calculation methods give values which agree reasonably well with the experimental values.
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  • 75
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    AIChE Journal 2 (1956), S. 444-447 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements of the terminal velocity of liquid drops immersed in an insoluble liquid were made for eleven liquid systems, covering a wide range of physical properties: continuous-phase density 0.960 to 1.145 g./cc., viscosity 0.93 to 1.56 centiposes; dispersed-phase density 0.807 to 1.674 g./cc., viscosity 0.59 to 72.1 centipoises; interfacial tension 0.3 to 42.4 dynes/cm. A correlation of the data was developed for each of the two velocity-drop-diameter regions which permits easy computation of the drop velocities. The correlations are shown to reproduce the present data and much of the published data very satisfactorily. Photographs permitted measurement of the drop eccentricities, which are shown to be a function of the drop diameter, density difference, and interfacial tension.
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  • 76
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    AIChE Journal 2 (1956), S. 451-455 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study was made of the effect of physical properties and of geometrical and dynamical characteristics of several liquid-liquid extraction systems on the mass transfer coefficients. The two-component systems studied consisted of the following solvents with water: cyclohexanol, methyl ethyl ketone, furfural, normal butanol, and nitromethane. The transfer studies were made in a horizontal glass pipe with the phases flowing counter-currently at velocities from 1,000 to 15,000 lb./(hr.)(sq. ft.). The transfer of solvents into the water phase and of the water into the solvent phase was measured. The film coefficients of mass transfer for a solvent through the water film and for water through the solvent film were correlated by new dimensionless equations which include interfacial tension and diffusivity.
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  • 77
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    AIChE Journal 2 (1956), S. 456-463 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The design and operation of a pilot-scale-moving bed adsorber to separate the various components of a gas mixture using activated carbon as the preferential adsorbent are described. A binary system, methane-acetylene, and a ternary system, methane-carbon dioxide-acetylene, were studied. The performance of the unit was analyzed by means of the transfer-unit-height (H.T.U.) concept based on the observed changes in gas composition during tower operation. For both the binary and ternary systems the transfer-unit height was independent of feed-gas composition but was found to vary linearly with the ratio of feed gas to carbon flow. The over-all transfer-unit-height values based on either the gas or the adsorbed phase were observed to vary from 6.5 in. at 1.39 std. cu. ft./lb. carbon to 36.9 in. at 4.81 std. cu. ft./lb. carbon.
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  • 78
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    AIChE Journal 2 (1956), S. 514-517 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Thermodynamic properties of n-hexane have been calculated over a temperature range of 32° to 540°F. and up to a pressure of 600 lb./sq. in. abs. These properties were determined from vapor pressure, volumetric, heat capacity, and latent heat of vaporization data through the application of rigorous thermodynamic relationships. The calculated data have been found to be internally consistent. The enthalpy values are believed to be accurate to within 0.5 B.t.u./lb. and the entropy values to 0.0005 B.t.u./(lb.)(°R.).
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  • 79
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    AIChE Journal 2 (1956), S. 508-513 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Group-contribution values are presented and, together with those already developed for the aliphatic hydrocarbons (10, 11), make possible the evaluation of both van der Waals' constants for the naphthenic hydrocarbons. These constants can be used to produce the critical temperatures, pressures, and volumes of these compounds entirely from a knowledge of their chemical structure.Critical constants have been calculated for several naphthenes, and from a comparison of them with the constants resulting from the methods of Riedel (5, 6) and Lydersen (3) it was found that the critical constants calculated by these three methods were in fair agreement for naphthenes having short alkyl side chains and progressively deviated from each other as the chains were permitted to lengthen. An appraisal has been made on five naphthenes along the lines proposed by Sondak and Thodos (9) in order to see whether these calculated critical constants properly represent the vapor-pressure function resulting from vapor-pressure data found in the literature for these hydrocarbons.Critical constants have been produced for more than fifty naphthenes, for which vapor-pressure data are available in the literature, and will be used in a separate, comprehensive vapor-pressure study for hydrocarbons of this type.
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  • 80
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    AIChE Journal 2 (1956), S. 555-560 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes an investigation of the factors affecting the change in composition with vaporization of a binary-component spray in heated air at atmospheric pressure. The behavior of the system orthodichlorobenzene-tetrachloroethylene was studied in air ranging from 400° to 1,000°F. Initial drop diameters in the sprays were in the 20- to 400-µ range. The experimental data obtained indicated that the rate of change of spray composition during vaporization was affected only by the chamber-air temperature, the initial feed composition, and the nozzle characteristics.Equations are presented which mathematically describe the vaporization process, liquid diffusion being assumed within the drop controls. These equations have been solved by a stepwise procedure for three initial drop sizes. Results of these calculations have been added statistically according to the initial-drop-size distribution in order to predict the vaporization behavior of the spray. Details of this process of statistical combination have been summarized by Culverwell (1).The calculations agreed with the experimental data previously obtained during the first 5 in. of nozzle-to-tray travel. After 5 in. the deviation was great. Future experimental work to determine more precise values of drop-size distribution, initial drop velocity, and liquid diffusion coefficient may result in more complete agreement.
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  • 81
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    AIChE Journal 2 (1956), S. 26-33 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rates of nitration of benzene by nitric acid in mixed acid to produce mononitrobenzene have been measured in well-emulsified reaction mixtures in the temperature range from 34° to 54°C. The acid-phase compositions ranged from 1.6 mole % nitric acid and 27 mole % sulfuric acid to 35 mole % nitric acid and zero % sulfuric acid; the organicphase composition ranged from 4 to 95 mole % benzene, and the relative extent of the acid and organic phases was varied from 25 to 80 volume % acid phase.The reaction rate based on the total volume of the reacting mixture is shown to be a function of the phase compositions, temperature, and volume % of acid phase.
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  • 82
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    AIChE Journal 2 (1956), S. 46-54 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The hydrogenation of carbon monoxide and carbon dioxide on various steel catalysts was studied in the temperature range of 800° to 1,300°F. and at pressures from 5 to 30 atm. The feed gases (3.75 to 20 SCFH) were passed over a catalyst bed of 1/8-in. steel balls supported in a brass-lined reactor 0.81 in. in diam. The percentage of carbon oxides in the feed was 30% in the runs using a H2—CO2 feed and varied from 15 to 38% in the runs with a H2—CO feed. The effects of temperature, pressure, feed composition, space velocity, and mass velocity were studied. Carbon deposition did not affect the activity of the catalyst and could be removed readily.
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  • 83
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Fluid flow data are presnted for beds of uniformly sized spheres consolidated with resin over a porosity range from 36.4 to 12.3%. The data are analyzed in terms of an effective pore volume and equations are given for predicting pressure drop by use of a friction-factor-Reynolds-number plot.
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  • 84
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    AIChE Journal 2 (1956), S. 94-100 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An apparatus for the determination of relative permeability under simulated reservoir conditions has been designed, constructed, and operated successfully. Complete water-oil relative-permeability data, with kerosene and simulated reservoir brine have been taken on four natural-sandstone cores at fluid pressures to 5,000 1b./sq. in. and overburden pressures to 10,000 1b./sq. in. One run was made at low pressure at a temperature of 160°F. for comparison with the results at low temperature. The apparatus is now being expanded so that gas-oil relative-permeability data may be taken, and crude oil containing gas in solution may be employed as the oil phase.The results indicate that essentially the same water-oil relative-permeability data are obtained at fluid pressures of 5,000 1b./sq. in. as at 30 1b./sq. in. gauge. The application of overburden pressure causes a reduction in both water and oil effective permeability in about the same proportion as it affects the single-phase permeability. Consequently the calculated relative permeabilities are affected to only a moderate extent. The results of the one run at 160°F. were in good agreement with the values obtained at room temperature.
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  • 85
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    AIChE Journal 2 (1956), S. 143-147 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A problem arose as to what would happen if there were sudden failures of power to one or more pumps of a large-scale complex pumping circuit composed of several individual pumping systems. This paper describes the application of several published methods of hydraulic transient analysis to the problem. The performance of the system computed under several assumptions is discussed, and a comparison is made with experimentally determined values.
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  • 86
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    AIChE Journal 2 (1956), S. 163-168 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The liquid-metal-fuel reactor under development at the Brookhaven National Laboratory uses a fuel which is a solution of U233, Mg, and Zr in liquid bismuth. For a power breeder thermal reactor, high neutron economy is essential, and this calls for low concentrations of those fission products in the fuel which are high neutron capturers. Roughly 45% by weight of the fission products can be continuously removed from the fuel by salt extraction with alkali and alkaline-earth fused-salt mixtures. These fission products contain the highly “poisonous” rare earths. This paper will present a discussion of processdesign considerations and proposed flow sheets.
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  • 87
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    AIChE Journal 2 (1956), S. 211-214 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mixtures of ethylene and oxygen dissolved in water under pressures ranging from 200 to 700 lb./sq. in. were irradiated with Co60 gamma rays at a dose rate of 180,000 r./hr. G values (molecules/100 ev.) for aldehyde production as high as 200 were observed. Increasing total pressure and dose were found to decrease these G values. Alcohol, acids, hydrogen peroxide, and organic peroxide are also products of the reaction; however, the yields are much smaller.
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  • 88
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    AIChE Journal 2 (1956), S. 1-1 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 89
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    AIChE Journal 2 (1956), S. 18-25 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method of estimating the true conditions of operation of a bubble-cap tray is presented. Intermediate between the Murphree and the Lewis methods, which represent the extremes of actual operation, this method involves the use of a correlation to determine the degree of liquid mixing on the tray and the use of new relations between the Murphree vapor efficiency, the Lewis case I efficiency, and the true local efficiency. For the last, partial liquid mixing is taken into account.Data were obtained on an 18-in. O.D. three-tray bubble-cap tower containing ten 3-in. bubble caps a tray. Partial liquid mixing was correlated for changes in vapor and liquid rates, pressure, temperature, and weir height for the system ethylene dichloride-toluene.Efficiency data on acetone-water, ethanol-water, and ethylene dichloride-toluene showed the following effects: (1) low concentration of lwo boiler usually, but not always, resulted in low true local efficiencies, always with high Murphree efficiencies; (2) vapor velocity effects are more intimately connected with slot velocity than superficial velocity (and hence entrainment); (3) raising the pressure gives higher efficiencies; (4) an increase in liquid depth increases the true local efficiency but may have no effect on the Murphree efficiency.
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  • 90
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    AIChE Journal 2 (1956), S. 82-87 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 91
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    AIChE Journal 2 (1956), S. 101-106 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The object of this study has been the measurement of concentration profiles of water vapor in a wetted-wall column with fully developed turbulent pipe flow of air for several positions downstream of the inlet. The air Reynolds number was 25,000. The mathematical formulation of this problem involves the Navier-Stokes equations and the mass transfer equation with a boundary condition of constant concentration at the wall. No attempt has been made toward an analytical solution of this problem, as the exact solution of the turbulence problem has not been developed. Instead, values of the mass and momentum transfer correlation, urh, and urux, have been computed as a function of the radius. The eddy diffusivity for momentum and mass and the local mass transfer rates are shown for engineering purposes.
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  • 92
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    AIChE Journal 2 (1956), S. 113-117 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Extension of the understanding of properties of films of metals produced on glass surfaces by vacuum evaporation has permitted the fabrication of film-resistance thermometers that with simple instrumentation accurately measure surface or average surface temperatures without altering the geography of that surface. Formerly unknown and unstabled related properties of such films have been classified and may be anticipated or eliminated by recommended experimental procedures. Films of several of the most chemically inert and refractory metals 300 to 3,000 Å. thick have been shown to attain accuracies as high as 0.01°C. for practical periods of time. Their use, which is described, is developing satisfactorily, and the technique and equipment for their preparation are relatively simple.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 93
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    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 199-205 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The coolant flow distribution among parallel tubes in a nuclear reactor (or boiler or heat exchanger) can be very sensitive to variations in heat input, dimensions, etc. Analytical expressions are given for partial derivatives which measure flow variations for several situations. The utility of orifices and valves in reducing flow sensitivity is discussed. Numerical results are reported for a system using water at supercritical pressurs with an eightfold expansion from inlet to outlet.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 94
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 235-240 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The advantages of factorial design are first illustrated by a simple experiment devoted to the effect of two pH factors and an iron-concentration factor on the efficiency of a decontamination process employing iron sulfide as a scavenging agent. The broadening of the base of an investigation by the expansion of a factorial is illustrated by addition of the sulfide concentration as a factor. Finally the principle of expanded factorials is further utilized in the later phases of the study, in which additional levels are assigned to the pH factors in order to arrive at a closer estimate of the optimum conditions for the process.
    Additional Material: 8 Tab.
    Type of Medium: Electronic Resource
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  • 95
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 251-258 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Interest in the course of chemical reactions in turbulent flow has made desirable detailed knowledge of the temperature distribution in flowing streams. One method of predicting the temperature distribution under a variety of conditions is reviewed here, the approach being limited to conditions of local uniform transport of momentum. A discussion of some of the aspects of eddy conductivity is included along with a brief review of the velocity distribution in uniform flow.The results serve to illustrate the relation of microscopic conditions of flow to the temperature distribution in a turbulently flowing stream. The importance of the molecular Prandtl number upon the transfer process is stressed.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
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  • 96
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 259-264 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 97
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 277-279 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The various forms of Bernoulli's equation as customarily written express static pressure energy in terms of absolute pressure, thereby restricting their direct application to systems situated in vacuo. It is shown here that recognition (1) of the universal presence of a fluid outside all systems over which Bernoulli's equation is written, and (2) of the practical necessity of measuring pressure within such systems as gauge pressures relative to the pressure of the exterior fluid leads to a more general set of equations and to a concept of buoyant static pressure and potential energies, as opposed to strictly abslute values.Failure properly to distinguish between these two types of energy quantities may result in error and confusion in the application of the various forms of Bernoulli's equation.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 98
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 16J 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 99
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 18J 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 100
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 389-392 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By use of saturated-vapor enthalpies determined by accepted procedures in conjunction with differential latent heats of condensation, the saturated-liquid enthalpies are established for the system methane-ethane at 200, 400, and 600 lb./sq. in. abs. and for the system ethane-n-butane and propane-n-butane at the two lower pressures. Where comparison is possible, the liquid-enthalpy values obtained by this method are in general agreement with those previously determined by Edmister and Canjar. The procedure used is thermodynamically rigorous and may be applied to any binary mixture, provided the Benedict-Rubin-Webb equation of state is valid in the vapor phase and P-V-T-x data are available.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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