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  • 1960-1964  (221)
  • 1950-1954
  • 1920-1924
  • 1961  (221)
  • Chemical Engineering  (221)
Material
Years
  • 1960-1964  (221)
  • 1950-1954
  • 1920-1924
Year
  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 2-2 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 14-20 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A description is given of the procedure and equipment used for the purpose of studying the effect of hydrostatic pressure upon the capillary flow properties of polymer melts. Flow properties are reported for a low density polyethylene over a wide range of temperatures, die sizes, different pressures and hydrostatic pressures.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 3-8 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study was designed to show the nature of weathering of an elastomer poly( ester-urethane), and to indicate methods of overcoining the deficiency. Unprotected polymer, when exposed to UV radiation in a Weatherometer, showed deterioration which is characterized by loss of tensile strength, some increase in modulus, and a decreased extensibility of surface skin.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 9-13 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Translated from: Vysokomolekuliarnye Soedineniia 2, 778-84 (May 1960). A thermomechanical study was made of the softening of crystalline polymers during uniform, uniaxial stretch and also of the effect of the rate of heating upon the softening or amorphous polymers. The effect of the tensile force on the thermo-mechanical behavior of various polymers was measured over the range 20 to 100 kg/cm2 and within wide temperature limits (-150° to 250°C). Ribbons 50 mm long, 2-4 mm wide and 0.05 to 0.5 mm thick served as specimens.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 26-30 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effectiveness of ultraviolet stabilizers of various types of polyolefin, cellulose ester, and poly (vinyl chloride) plastics was investigated. Most of these stabilizers were of the ultraviolet-absorbing type but two were of the nonabsorbing type. Exposures were made both outdoors and indoors in a Twin-Arc Weatherometer. The latter was modified by the addition of ten 20-watt fluorescent sun lamps to remedy the short-ultraviolet deficiency of the enclosed carbon arcs.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 21-25 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The degradation of plastics by ultraviolet energy and the use of protective ultraviolet absorbers to improve stability necessitate studies along several lines. These include (a) the measurement of the ultraviolet spectral energy distribution of sunlight and of the indoor accelerated test sources, (b) the measurement of the extent of degradation as a function of the wavelength of the incident radiation, (c) an estimate of the absorbing effectiveness of the added protective agents, and (d) the stability of the protective ultraviolet absorbers themselves.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 40-46 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The non-Newtonian flow behavior of polyethylene has been investigated with respect to the effects of molecular weight and molecular weight distribution. Effects of die geometry on melt fracture as well as preliminary extrudate orientation studies are discussed.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 31-39 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study was designed to show the nature of weathering of an elastomer poly(ester-urethane), and to indicate methods of overcoming the deficiency. Unprotected polymer, when exposed to UV radiation in a Weatherometer, showed deterioration which is characterized by loss of tensile strength, some increase in modulus, and a decreased extensibility of surface skin.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 52-52 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 11
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 47-51 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new curing system which yields room temperature curing epoxy adhesives with high bond strength and softening point has been developed for service in contact with high explosives. Bisphenol A type resins cured with hydroxyl alkyl phosphate acid esters are used. Short pot life and relatively low alkali resistance are drawbacks of the system.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 54-55 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 56-56 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 73-79 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This article includes a comparison of the adhesive properties of bisphenol-A expoxides at 300°K and 76°K with respect to the molecular weight of the uncured resins. Joints of 2024 aluminum were tested at 300°K and 76°K in tensile-shear and in impact-shear, and total linear thermal contraction of the cured resins was measured between the two temperatures. Results are discussed with respect to residual joint stresses and adsorptive properties of the resins.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 63-67 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new method for measuring heat stability and temperature of degradation of thermosetting plastics is described, as well as an improved method for the determination of transition temperature into glassy or viscous state for thermosetting resins. Magnitude of elastic deformation is tied in with length of polymer chain and lattice density.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 17
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 68-72 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: During the last thrity years, dielectric measurements have been employed extensively to provide a better understanding of the interactions between polymer and plasticizer in various thermoplastic formulations. Recently, a series of melamine resins, plasticized to the extent that shrinkage and internal stress were modified, became available. Since there is little information in the literature concerning the dielectric properties of such thermosetting resins, a study was made of the variation of dielectric constant and loss as a function of frequency and temperature.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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  • 18
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 57-62 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Derivatives of 2-hydroxybenzophenone are well-known stabilizers for such polymers as cellulose acetate butyrate and polyesters. Their stabilization effectiveness is commonly associated with their ability to screen a polymer from the harmful ultraviolet radiation found in sunlight. They also satisfy other requirements for effective stabilizers, namely, compatibility with many polymers and an inherent stability to ultraviolet light. Several other functions of 2 hydroxybenzophenones in stabilizing a polymer to ultraviolet light have been postulated, but little experimental data related to them are available. This paper deals with some of the additional functions of 2-hydroxybenzophenones in weathering stabilization as investigated by nuclear magnetic resonance spectroscopy (NMR) and electron paramagnetic resonance spectroscopy (EPR).
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 19
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 80-85 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The magnitude and temperature dependence of the electrical resistivities of a number of thermoplastic and thermosetting high polymers have been determined. Activation energies for the electrical conduction process Ee have been calculated and found to vary from 12 to 60 Kcal/mole depending upon the structure of the polymer. Results are interpreted in terms of an ionic diffusion process and discussed in terms of the structure of the polymers.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 20
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 102-103 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 21
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 22
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 86-92 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: For broad ranges of operating conditions and a wide variety of high pressure polyethylenes, the flow data obtained from a high shear viscometer and a commercial extruder are identical. Discrepancies between flow data can result from non steady state viscosities in the high shear viscometer, or from cooled screw extruder operation. In the broad regions in which the flow data concur, the readily obtained viscometer data are suitable for predictions of extruder performance. The principle is illustrated by the good correlation of a viscometer flow curve parameter and the screw power consumption in the extruder. Principles outlined for flow data identity and extruder performance prediction are believed to be general, but the quantitative limits defined are specific to the extrusion devices involved.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 23
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 93-100 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Recent technology has evolved a number of dissimilar thermoplastics which under conditions of ambient temperature and impact loading show both the high modulus, which is mainly a property of brittle polymers in the glassy state, and also the impact resistance, such as may be expected of polymers in the rubbery state. Several of these special plastics were examined by electronmicroscopy and also with respect to several aspects of their mechanical behavior to establish by direct observation and inference whether or not different types of plastics exhibit some common features of structure which promote impact resistance. These observations suggest the hypothesis that special circumstances of domain heterogeneity can override many other variables of composition or molecular structures in controlling the fracture mechanism.
    Additional Material: 24 Ill.
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  • 24
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 104-104 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 25
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 105-108 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: For resins of room temperature density 0.91 to 0.96 g/cc, enthaply and internal energy diagrams have been developed from 0 to 200°C and up to 1000 atmospheres. These diagrams can be used for estimating properties for which data are not available, and provide unified view of many properties of polyethylene under conditions of fabrication and use. Extent of crystallinity estimates can be made from enthalpy, internal energy, specific volume, compressibility and melting point data provided for hypothetical amorphous, crystalline and actual resins.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 26
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 109-112 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The Griffith theory for brittle fracture predicts that the tensile strength should be inversely proportional to the square root of the size of a defect or flaw in the sample tested. The validity of this relation has been investigated for the glassy polymers, poly(methyl methacrylate) and polystrene. The results indicate that the strength of the polymers depends on two factors: (1) the surface energy, and (2) the inherent flaw size. The surface energy is primarily that dissipated in a viscous flow process and the inherent flaw size is related to the tendency of the polymer to craze under stress.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 27
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 121-132 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The mechanism of formation of tubular polythene film is a complicated process, and extensive studies have shown that the properties of the film made are influenced profoundly and in a complex way both by the processing conditions used by certain design features of the equipment. Studies of the effect of the extrusion variables on the more important film properties, both optical and mechanical, are reviewed in this paper. The results are discussed in terms of the fundamental nature of polythene film, its surface, its crystalline structure and its orientation.
    Additional Material: 12 Ill.
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  • 28
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 113-120 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Flow patterns in the channel of a screw extruder have been investigated in a study utilizing a model extruder with stationary screw and a rotating, transparent barrel. Photographs of flow streamlines at conditions over the full range of output restriction are presented for a non-Newtonian fluid. A technique employing photographs of particle tracers was used with the same apparatus to permit quantitative measurement of velocity profiles with both a Newtonian and a non-Newtonian fluid.
    Additional Material: 16 Ill.
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  • 29
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 139-142 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new series of inorganic-organic high polymers have been synthesized namely; the metaloxene polymers of phenolaldehyde. Titanium (IV), Zirconium (IV) and Hafnium (IV) phenolaldehyde have been prepared and other metals especially the refractory type metals may merit further development as calorobic plastic materials. The hafnium resin has been compression molded into a rocket-nozzle insert shape with satisfactory rocket-firing results.
    Additional Material: 5 Ill.
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  • 30
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 147-148 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 31
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 143-146 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This article describes preparation of resins as described in the title above, and the effect of concentration of the diepoxide, dimer acid, and initiator (stannous octoate). Proportion of dimer acid and diepoxide has a marked influence on hardness and tensile properties of resins. Change in tensile properties upon aging correlates very well with change in hardness. Higher proportions of dimer acid produce softer, more flexible resins. The resins have unique electrical properties at temperature up to 175°C, apparently because of the high proportion of hydrocarbon in the resin.
    Additional Material: 1 Ill.
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  • 32
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961) 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 33
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 133-138 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Twelve plastics representing various chemical structures were studied as part of a program to determine the utility of plastics as packaging materials in the high radiation presentation of food. The plastics were exposed to selected dosages of Cobalt-60 gamma radiation in vacuum and in air. Gas evolution and changes in infrared spectra as a result of irradiation were used to hypothesize the relative stability of these plastics to irradiation. Based on these facts it was found that plastics containing conjugated ring systems, ionic linkages, and chlorine in side groups were the most stable.
    Additional Material: 3 Ill.
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  • 34
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 150-151 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 35
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 152-152 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 36
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    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 153-163 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Permeability properties depend on the size, shape and polarity of the permeating molecule. Permeability of organic liquids, polar or non-polar, can be quite accurately predicted if the chemical composition of the permeant is known. By the choice of an arbitrary value (unity) as an indicator for the carbon atom, numbers specific to each structural element of the permeating molecule can be computed from previous experimental data. These numbers, herein called “Permachor” values (π), then combine by simple addition to relate the logarithm of a liquid's permeation in polyethylene.
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  • 37
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 169-176 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Mobile ions can be introduced thereby increasing the conductivity, with a limiting operating temperature range of 200°-250°C. Conductivity can be increased with the formation of conjugatd double bonds. Polymeric compounds may be synthesized with metallocyclic groups, where an atom of metal is bound to nitrogen atoms in a heterocyclic system in the basic chain of conjugation of the macromolecule. Here phtalocyanimes possess the greatest thermal stability. Lastly there are semiconducting polymers with conjugated double bonds containing hetero-atoms in the principle chain, having unpaired electrons of oxygen and nitrogen.
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  • 38
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: If temperature variations of forces in both directions are observed simultaneously at constant simple dimensions, internal energy and entropy changes on elongation in those directions may be calculated at constant volume and in the more common experimental condition of constant pressure. Thermodynamic derivatives at constant volume are important for fundamental molecular interpretation being related to configuration change. Constant pressure quantities were therefore changed into constant volume ones by the use of an evaluated correction term, involving average Young Moduli and thermal expansion coefficient.
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  • 39
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 177-179 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Equipment is described for measurement of Young's and shear modulus on the same identical polymer sample, by a free-vibration method. Strain gauges are used as sensors in an automatic recorder. Young's modulus and damping, shear modulus and damping and Poisson's ratio are reported over a range of temperature for polypropylene, Nylon 66 and poly (methylmethacrylate). It is found that Poisson's ratio shows a dip in the glass transition region and that values greater than the infinitesimal strain limit of 0.5 are obtained in the rubbery region.
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  • 40
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 180-180 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 41
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 181-190 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Adsorption studies on powdered and planar surfaces yield significant information regarding the rate and degree of interaction between the substrate and the organic adsorbate. Investigative tools include contact angle measurement, radiotracer methods, ellipsometry, x-ray diffraction, electron diffraction, elegant infrared techniques, dynamic desorption techniques, and film balance applications.
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  • 42
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 214-223 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A solution of substituted alkyl alkoxy silanes was applied to E-glass filament strands before forming glass-resin composite hoops, which were tested to relate changes in hoop physical properties to the nature of the coupling agent-size application. Continuously heat cleaning E-glass in oxygen-enriched air gives a strand that, when properly coated with size and laminated, makes a hoop with superior strength and modulus properties.
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  • 43
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 224-233 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Theoretically a monolayer or insignificant weight per cent of coupling agent should give optimum properties for fiber glass-resin composites, contrary to commercial practice. Studies of variation of chemical bonding between the coupling agent and the resin and the study of the degree of bonding of the coupling agents to the glass by extraction techniques have not explained this effect. However, new techniques of electron microscopy have revealed details of loading distribution and agglomeration on the glass fiber which tend to explain this effect.
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  • 44
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 199-213 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The chromium complex is chemically bonded by ion exchange with alkali cations to strongly acidic sites in the glass surface. These sites are formed by the isomorphous replacement of silicon by boron and aluminum in the network structure. Polymerized complexes are better bonding agents than monomeric ones. Specific interactions between organic groups on the chrome complex and the bonding resins also determine laminate strength and water resistance.
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  • 45
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 191-198 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Interfacial reactions between organosilane-treated fiberglass and styrene, and bond conditions in these and in polymerized ethylene oxide and epichlorhydrin-E-glass systems were investigated. The vinyl functionality of some alkenylsilanes showed little effect on the polymerization of styrene on E-glass. The polymerization of this aromatic monomer on vinyltrichlorosilane-reacted fiberglass did not result in interfacial bond formation. Sorption of water on organosilane-coated glass at different temperatures suggested that permeation of the adsorbate into the bulk of the substrate was determined by diffusive transfer of water molecules.
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  • 46
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    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 1 (1961), S. 234-244 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Evidence indicates that there is a chemical bond between the coupling agent of either silane or chrome complex type and the glass substrate, but that this chemical bond may be strong or weak, depending on the elements making up the bond and the other elements in the immediate area surrounding the bond. These elements can exert either a beneficial or detrimental effect on the strength of that bond. Other evidence is given to show that a vapor phase treatment that applies silane coupling agents like A-1100 to “E” glass gives the highest known strength retention values. A mechanism is advanced to explain the bridging of unreactive sites on glass surfaces by silane coupling agents applied from solution.
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  • 47
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 10-12 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rates of diffusion of helium, nitrogen, and carbon dioxide through alumina pellets were measured at atmospheric pressure and room temperature. The cylindrical pellets, ¾ in. diameter and ⅜ in. in length, were prepared from α-alumina particles with a mean pore radius of 65 Å. Surface area and pore volume data indicated that the corresponding mean pore radius of the micro and macropores in the whole pellet was 96 Å.The results showed that Knudsen type of diffusion was the controlling transport process despite the large fraction of void volume in the macropores. Carbon dioxide diffused more rapidly than expected, suggesting the possibility of migration of physically adsorbed molecules along the pore walls.The diffusion rates were about 16% higher than predicted, with a mean pore radius (Wheeler model) based upon the void volume of both micro and macropores used. However there is no logical basis for using this mean pore radius for a pellet having widely separated, micro and macropore size distributions.
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  • 48
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 17-19 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The problem of defining an average diffusion coefficient of a gas arises in the application of the film resistance model for mass transfer to systems involving multicomponent mixtures of simultaneously diffusing gases and in the application of mass, momentum, and heat transfer analogies in such systems. It is shown that, in some cases, integration of the diffusion equation with an average value of the diffusion coefficient will not be valid. An approximate solution of the diffusion equation is obtained with the concentration dependence of the diffusion coefficient taken into account. Some numerical examples are constructed for comparison of this method and several methods for defining an average diffusion coefficient with an exact solution of the Stefan-Maxwell relations.
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  • 49
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 1-1 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 50
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    AIChE Journal 7 (1961), S. 107-112 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theoretical analysis of heat transfer to liquid metals in parallel flow through a tube bundle, following the method of Lyon, results in an equation which agrees within 10% with the calculated values. The conditions are fully developed turbulent flow, constant heat flux at the wall, and an infinite number of tubes arranged on an equilateral triangular pitch. The hexagonal flow area assignable to any tube is approximated by a circle of equal area, and the velocity distribution of Bailey for an annulus is assumed to apply from the inner wall to the circle of maximum flow. The range of conditions is: pitch-to-diameter ratio, 1.375 to 10; Reynolds number, 104 to 106; Prandtl number, 0 to 0.1; and Peclet number, 0 to 105. Laminar and slug flow Nusselt numbers are also determined.
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  • 51
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A theory of design of chemical reactors is developed for two-phase fluid systems where the rates of chemical reaction are low relative to the rates of mass transfer. Equations are presented for batch, column, and continuous stirred tank operations. Experimental data on the continuous hydrolysis of acetic anhydride in a benzene-water system operating countercurrently in a pulsed-flow sieve plate column and in a packed column are analyzed in terms of the theory.
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  • 52
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    AIChE Journal 7 (1961), S. 133-137 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The vapor-liquid equilibrium in ammonia complex systems has been studied with a view toward design methods for separational and leaching processes. It is felt that the previously reported equilibrium constants for these systems are subject to considerable question with regard to the method used to measure the activity of the free ligand, or coordinating species. It is shown how this difficulty can be surmounted by the use of ammonia vapor pressure measurements and fugacities. A method of correlating complex equilibrium data from measurements of over-all metal concentration and free metal ion concentration is proposed. Vapor liquid equilibrium measurements have been made on the systems copper hydroxide, ammonia, water, nitrogen and nickel hydroxide, ammonia, water, nitrogen at 40° and 60°C. under 1 atm. total pressure with a continuously recirculating batch contactor. The correlation method is illustrated with the data of these measurements.
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  • 53
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 172-172 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 54
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 174-174 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 55
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 8M 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 56
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 190-195 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new isothermal calorimeter with no vapor space is described. It allows the accurate and rapid determination of heats of mixing of endothermic liquid systems. Data are presented for eighteen binary systems composed of a lower alcohol and a simple benzene derivative at 25°, 35°, and 45°C. Precise equations for representing these data are also presented.
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  • 57
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    AIChE Journal 7 (1961), S. 199-202 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Glass cylinders and spheres were crushed by slow compression in a hydraulic press. In all experiments the elastic energy stored in the specimen prior to fracture was measured. In some experiments the surface area of the resultant powder was measured by gas adsorption; in others the heat generation upon fracture was measured. The latter experiments show that considerable additional energy is fed into the fracturing specimen from the press. Local stress concentrations, and hence energy level at fracture, varied widely with particle shape. Calorimetric experiments suggest that real differences in crushing effectiveness, that is new surface per unit actual work done on the specimen, do occur. These differences are not due directly to the magnitude of the energy fed in from the press but rather to the effectiveness with which the stored or feed-in energy is used.
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  • 58
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    AIChE Journal 7 (1961), S. 221-225 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The laminar boundary-layer behavior on a moving continuous flat surface is investigated by two methods. One method involves the numerical solution of the boundary-layer equations. The other is an integral method, based on an assumed velocity profile that satisfies the appropriate boundary conditions. Good agreement is obtained between the results of these two methods of solution. The turbulent boundary-layer behavior on a moving continuous flat surface is investigated by the integral method only. Equations for the boundary-layer thickness, displacement thickness, momentum thickness, and skin friction are presented for both laminar and turbulent boundary layers. Comparison is made with the boundary-layer behavior over a flat plate of finite length.
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  • 59
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    AIChE Journal 7 (1961), S. 243-249 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: From the equations expressing mass and energy transfer in the solid and void regions of a catalyst of micropores, conversion and temperature profiles are evaluated as a function of the properties of the particle and the reaction system. The method developed is illustrated with numerical calculations for a first-order, irreversible reaction. Microeffectiveness factors Ec are derived from these profiles for several distribution functions for the size (radius) of the micropores.The results indicate that the nature of the pore-size distribution cannot affect Ec more than about 10%. However effectiveness factors greater than unity are possible for exothermic reactions with high heats of reaction and particles of reasonable size.To treat pelletted catalysts, equations are also developed for determining conversion and temperature profiles in pellets formed by compressing the microporous particles These results are interpreted in terms of macroeffectiveness factors Es, with values of Ec applicable at various positions in the pellet. To illustrate the method of solution numerical values of Es are determined for a limited range of parameters. The results indicate that in pelletted catalysts large temperature gradients may exist. For an exothermic reaction this can lead to a significant increase in macroeffectiveness factor.
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  • 60
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    AIChE Journal 7 (1961), S. 264-267 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Dimensional analysis has been applied for the correlation of the thermal conductivity of a gas to its temperature, molecular weight, heat capacity, and critical constants. This approach indicates that the group k*λ/Cp should be a function of zc and TR, where λ = M1/2Tc1/6/Pc2/3. Experimental thermal conductivities of hydrocarbons at normal pressures (approximately 0.2 to 5 atm.) have been used to develop two relationships. The first is applicable to all types of hydrocarbons for 0.6 〈 TR 〈 3.0 with the exception of methane and the cyclic hydrocarbons below TR = 1.0, for which the other relationship is applicable. These two relationships have been used to calculate thermal conductivities for twenty-eight gaseous hydrocarbons for which experimental data are available. Calculated values for normal paraffins, isoparaffins, olefins, diolefins, acetylenes, naphthenes, and aromatics produce an average deviation of 2.4% from experimental values for 154 points considered.
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  • 61
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    AIChE Journal 7 (1961), S. 282-287 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Analysis was made of the behavior of entrained particles in the zone between trays in a sieve tray column for the air-water system. The effects of drop-size distribution, projection velocity, drag, and gravity were evaluated with respect to the quantity of entrained liquid between trays. The drop-size distribution was found to be logarithmic in nature.The entrainment as a function of distance above the froth is estimated in Equation (12) where dH may be calculated from projection velocities and column superficial velocity for particle sizes greater than 400 μ.Confirmation of the proposed entrainment equation via experimental data was achieved within an average deviation of 28%.It was anticipated from the relationships developed that a leveling off of entrainment at zones in proximity to the froth and at escape velocity heights would be observed. Confirmation was evident at zones in proximity of the froth and upper zone tendencies were observed.
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  • 62
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    AIChE Journal 7 (1961), S. 303-307 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The formation of a solid phase as the result of isothermally increasing pressure on a binary solution is analyzed from a thermodynamic point of view. Exact thermodynamic equations are presented for the case in which there are no more than one liquid and one solid phase in equilibrium for the entire range of compositions. Approximate relations incorporating the additional assumption of ideality in both solid and liquid phases are also presented. Experimental data for the system ethylene bromide-ethylene chloride are reported and compared with predicted values. Incomplete data for the system benzene-n-heptane are also reported.
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  • 63
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    AIChE Journal 7 (1961), S. 324-328 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The analytical solution to the equation of motion is given for the steady laminar flow of a uniformly conducting incompressible non-Newtonian fluid between two parallel planes. The fluid is under the influence of a constant pressure gradient and is subjected to a steady magnetic field perpendicular to the direction of motion. Two non-Newtonian models are considered: the Bingham plastic model and the power-law model. Flow rates and the velocity profiles for various values of the Hartmann number and the generalized Hartmann number are presented and compared with those corresponding to Newtonian fluids.
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  • 64
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    AIChE Journal 7 (1961), S. 346-347 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 65
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    AIChE Journal 7 (1961), S. 337-342 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of mass transfer resistance in reducing the effectiveness of porous catalysts has been known since the publication of Thiele's classical paper in 1939. The variation in temperature caused by resistance to heat transfer may bring about equally significant changes in effectiveness in some cases. An extension of Thiele's treatment to take exact account of heat transfer resistance leads to a set of nonlinear differential equations that can only be solved numerically.This paper presents an approximate treatment of the simulataneous effects of resistances to mass and heat transfer. With the limitations imposed by linearizing the equations the formulas derived give the activity and selectivity for any combination of reactions. The use of the results is illustrated by three examples. It is shown that the principal effects are associated with the variation of concentration within the pellet of catalyst and with the difference in temperature between the surface of the pellet and the bulk fluid.
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  • 66
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A Burnett type of apparatus for the study of the volumetric behavior of gases at low temperatures and high pressures was constructed. The apparatus was used to study the volumetric behavior of methane and four mixtures of hydrogen and methane from +50° to -200°F. and pressures as high as 7,000 lb./sq. in.The experimental data were used to obtain the second virial coefficients for pure methane and for the mixtures. The results of approximately 600 experimental points were used to obtain a table of compressibility factors for methane and the mixtures at even increments of pressure and temperture.
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  • 67
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    AIChE Journal 7 (1961), S. 288-294 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The growing availability of fast, large memory digital computers has made it practical to consider the physical implementation of control system designs incorporating appropriate strategies for automatic process optimization. The control system is taken to consist of the process to be optimized together with the interconnected digital computer. The control strategy is realized in the program of the digital computer. In the present paper a number of such programs or algorithms are discussed for carrying out a search of the possible settings of the process input (independent) variables in such a way as to locate an extremal of the possible values of a chosen objective function. The magnitude of these variables is determined from measurements taken of the dependent variables in the process. It is shown that for the particular process used as an example it is desirable to alter the search strategy as the optimization proceeds in order to locate the extremal in a minimum amount of time. The emphasis at the beginning of the search is on speed in moving towards the optimum and at the end on accuracy.Further, a computational technique is described whereby the dynamic response of the process to the various search steps (or settings) is under time-optimal control. This procedure is important for the fast execution of the search programs and consequent rapid location of the extremal of the chosen objective function.
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  • 68
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    AIChE Journal 7 (1961), S. 312-318 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 13 Ill.
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  • 69
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    AIChE Journal 7 (1961), S. 413-417 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The extension of the rules proposed by Cailletet and Mathias for the sum of the saturated vapor and liquid densities and by Guggenheim for the difference of these densities enabled the development of a method for the prediction of liquid densities for binary hydrocarbon systems at saturated conditions. The theorem by corresponding states indicated that unique relationships should exist between the reduced temperature and the sum and difference of the reduced saturated liquid density and the reduced saturated vapor density.Density data reported by Kay for the systems n-butane - n-heptane, ethane - n-butane, ethane - n-heptane, and ethane - cyclohexane were used to determine the exponents and the coefficients of the resulting equations. The exponents were found to be functions of two temperature parameters, which take into account both the components and composition of the mixture, while their coefficients have been found to depend only on their exponents.It has been previously shown that critical temperatures of binary hydrocarbon systems can be predicted with the two temperature parameters. In this study it has been found that these two parameters can also be applied to determine the critical densities for these binary hydrocarbon systems. Using these critical properties one can directly obtain the saturated liquid densities of binary systems from the two reduced-density relationship.The method developed in this work reproduces the saturated liquid densities of the four systems within 4.8%. In addition saturated densities have been calculated for the ethylene - n-heptane system and checked the experimental values within 3.2%.Because saturated vapor densities are small compared with the saturated liquid densities for conditions removed from the critical point, the sum and difference of the liquid and vapor densities are approximately the same. Thus this method cannot be used with any reliability to determine the densities of saturated vapors.At present this method can be applied only to hydrocarbon mixtures whose atmospheric dew point does not exceed twice its atmospheric boiling point.
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  • 70
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    AIChE Journal 7 (1961), S. 442-444 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mass transfer studies were conducted for the flow of air through fluidized beds. These studies were concerned with the sublimation of p-dichlorobenzene spherical particles, approximately 0.04 to 0.08 in. in diameter, and with the evaporation of nitrobenzene and water from alumina spheres. 0.1168 in. in diameter.Void volumes for these fluidized beds were calculated from pressure-drop measurements. The results of this investigation were used to establish mass transfer factors which were in agreement with values obtained for fixed beds for corresponding modified Reynolds numbers, DpG/μ(1-ε).
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  • 71
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    AIChE Journal 7 (1961), S. 453-455 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An equation of state which describes vapor and liquid states of nitrogen in the temperature and density range to three times the critical and the two-phase boundary is presented. The root mean square error is less than 0.7% in describing the available data for nitrogen. The equation contains thirteen coefficients, only three or four of which are independent, and can be written in virial form.
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  • 72
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    AIChE Journal 7 (1961), S. 524-526 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 73
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    AIChE Journal 7 (1961), S. 336-337 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A modified Edwards density balance was used to measure compressibility of carbon dioxide and nitrous oxide at pressures under 2.0 atm. and over a temperature range of -30° to 75°C. Second virial coefficients were calculated for the temperatures covered in this investigation and compared with data presented in the literature for both gases. The compressibility data are estimated to be accurate within ±0.10% of the actual compressibility factor.
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  • 74
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    AIChE Journal 7 (1961), S. 565-573 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements have been made of the simultaneous rates of transfer of acetone and benzene between a liquid film and a turbulent three component gas mixture. The measurements were made in a wetted-wall column with both mixtures of acetone, benzene and nitrogen, and acetone, benzene and helium.As predicted by the equations of Part I the mass transfer differs qualitatively as well as quantitatively from mass transfer in the corresponding binary system in which one component is stagnant. In several experiments acetone was transferred from low to high concentrations in accord with the predictions.Both the ternary film and Prandtl-Taylor models satisfactorily predict the rates of transfer of acetone and benzene, and, except possibly for very high Reynolds numbers, the simpler film model is recommended.
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  • 75
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    AIChE Journal 7 (1961), S. 584-587 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of the reduction of ferrous oxide with hydrogen in a steady state fluidized bed have been correlated with a rate equation based on a reaction controlled at the oxide-metal interface and on a differential material balance which assumes that a close approach to piston flow prevails. The correlation gives an enthalpy of activation of 29,500 b.t.u./lb. mole for the reaction, which is in good agreement with McKewan's reported value of 27,500 b.t.u./lb. mole. The relationships developed are used to predict the effect of the important independent variables on the over-all kinetics of the system.
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  • 76
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    AIChE Journal 7 (1961), S. 606-610 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mechanical and dynamical characteristics of semifluidized beds of single-size particles in solid-liquid system were investigated. A semifluidized bed is a type of fluidized bed in which the bed expansion is partially restricted. The emphasis was placed on the study of packed bed formation and pressure drop increase when the semifluidized beds were formed by the compression of fluidized beds. The data showed good agreement with the theoretical and semiempirical equations based on a simple model of fluidized beds.The results of this investigation would also contribute to the understanding of fluidized beds.
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    AIChE Journal 7 (1961), S. 631-634 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The liquid film coefficient is related to bubble diameter and velocity in pure water and to the physical properties of the liquid. The addition to water of organic substances which influence the surface tension and viscosity will decrease the size of the air bubble released from a diffuser and reduce the transfer of oxygen into the solution. The maximum reduction in oxygen transfer occurs in the region of maximum surface tension change. The effect of the addition of several organic substances on the oxygen transfer characteristics are shown.
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  • 78
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    AIChE Journal 7 (1961), S. 653-657 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: One of the numerous equations needed to define the dynamics of a distillation column has been derived. This equation relates the feed composition to the product composition. Thederivation is accomplished by the reduction of the signal flow diagram. The poles and zeros of the equation are almost entirely determined by the ratio of the tray holdup to the liquid flow rates and the number of trays.
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  • 79
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    AIChE Journal 7 (1961), S. 666-671 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The unconfined growth of a filter cake on a circular filter cloth was theoretically and experimentally studied as the simplest example of a three-dimensional filtration. The results are compared with the one-dimensional cake growth which ensues when the cake is laterally restrained by a cylindrical sleeve.
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  • 80
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    AIChE Journal 7 (1961), S. 682-687 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Low-pressure solubility data have been correlated for eleven gases in nine solvents over a wide temperature range by considering the dissolution process in two steps. First the gas is condensed isothermally to a hypothetical liquid at 1 atm. pressure, and then this hypothetical liquid is dissolved in the solvent. The free energy of the first step depends only on the properties of the solute, which in the case of nonpolar gases can be adequately described by the theorem of corresponding states. The second step depends on the properties of both solute and solvent and, in the case of nonpolar systems, can be described by the theory of regular solutions. The correlation depends on three solute parameters: the solubility parameter, the molar volume, and the fugacity of the hypothetical liquid; the last of these has been plotted as a generalized function for the reduced temperature range of 0.7 to 3.2. A separate plot is given for hydrogen. These parameters may be used to make good estimates of low-pressure gas solubilities (or K values) in nonpolar solvents over a wide range of temperature.A semiempirical method for correlating the solubilities of gases in polar solvents is also described and illustrated for several cases.Since the correlation presented in this paper covers a wide temperature range, it is possible to make estimates of the heats of solution of gases in liquids. These may be useful in enthalpyblance calculations as required in certain phase-separation operations.
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  • 81
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    AIChE Journal 7 (1961), S. 3D-4D 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
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  • 82
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    AIChE Journal 7 (1961), S. 3-9 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Viscous fluids are frequently agitated by multiple impellers and in vessels only slightly larger than the impeller. This paper presents data for both Newtonian and non-Newtonian fluids agitated under such conditions. The large decreases in power requirements (at a given level of mixing rate in the non-Newtonian system) which are possible by use of low tank diameter, impeller diameter ratios and/or two impellers, have been quantitatively studied.The types of impellers used in the non-Newtonian work and the ranges of conditions over which power requirement correlations were developed are summarized as follows: TextDT/DnNReMarine propeller0.42-1.01.4 -4.80.16-1.00.67-1320Fan turbine0.33-0.671.3 -3.00.21-1.46.6 -160Flat-Bladed turbine: one impeller0.17-0.671.3 -5.50.20-1.52.0 -1800two impellers per shaft0.33-1.001.023-3.50.14-1.000.15-620The results generally confirm an approach developed earlier, for the broader ranges of variables listed above. For the non-Newtonian fluids of primary interest in this study, that is purely viscous materials having flow behavior indexes of less than unity (pseudoplastics, Bingham plastics), the prediction of power requirements has been developed to nearly the same level of perfection as for Newtonian fluids.
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    AIChE Journal 7 (1961), S. 26-28 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This study deals with boundary-layer flow on continuous solid surfaces. Flow of this type represents a new class of boundary-layer problems, with solutions substantially different from those for boundary-layer flow on surfaces of finite length. In this paper the boundary-layer behavior on continuous surfaces is examined, and the basic differential and integral momentum equations of boundary-layer theory are derived for such surfaces. In subsequent papers these equations will be solved for the boundary layer on a moving continuous flat surface and a moving continuous cylindrical surface, for both laminar and turbulent flow in the boundary layer.
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  • 84
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    AIChE Journal 7 (1961), S. 38-41 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental study of superposed free and forced convection for air in a horizontal tube is reported. The laminar Nusselt number, based on the log mean temperature difference, ranged from 29.9 to 15.2; the laminar flow Graetz number, based on the bulk or average temperature of the air, ranged from 33 to 1,300, the Grashof-Prandtl modulus based on properties of air at the wall temperature ranged from 1.1 × 106 to 2.2 × 106. The Grashof number utilized the log mean temperature difference. An analysis of the system from a macroscopic viewpoint led to the determination of an equation which fits the laminar flow experimental data in the range of Graetz numbers from 60 to 1,300. An equation was also found for the turbulent data.
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  • 85
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    AIChE Journal 7 (1961), S. 61-63 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A continuous velocity distribution is derived which is based on an arbitrary modification of Prandtl's mixing length expression. The resulting velocity distribution agrees well with experiments for transition and fully developed turbulent flow throughout the entire cross section of the conduit. Furthermore the mixing length expression applies to parallel flow in smooth circular tubes and between infinite parallel plates with the same set of constants.
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  • 86
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    AIChE Journal 7 (1961), S. 143-147 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experiments on the continuous catalytic water-gas shift reaction have been carried out making full use of the principles of statistical design to elucidate the reaction mechanism. Instantaneous reaction rates were determined for sixteen different combinations of the five variables: partial pressures of carbon monoxide, hydrogen, carbon dioxide, and temperature. Nitrogen gas was used as an inert diluent to make up the total pressure to 1 atm. From the analysis of variance of these sixteen runs it can be shown that the Temkin mechanism for the water-gas shift reaction cannot represent the data within the experimental accuracy. A tentative alternative mechanism which is consistent with the data obtained is presented. The work shows that while it is possible to obtain useful empirical kinetic data from small, well-planned experiments, both highly precise experimental data and very careful statistical treatment are required. When these are available, a very marked reduction in the amount of experimental work can be effected.
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    AIChE Journal 7 (1961), S. 163-171 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Residence-time studies are reported for water trickling down through a 4-in. column packed with spheres. The transient response of the column to pulse- and step-function inputs in tracer concentration applied to the water stream was determined for both porous and nonporous packing. Significant radial variations in the distribution of residence times and the volumetric rate of flow were observed. The contribution to the response curves of diffusion into the porous packing and flow in the interparticle voids can be separated. The diffusion rates may then be characterized in terms of an effective pore diffusivity for the packing.
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    AIChE Journal 7 (1961), S. 176-176 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 89
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    AIChE Journal 7 (1961) 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 7 (1961), S. 216-220 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Forced convection mass transfer between circular tubes and liquid lithium was experimentally investigated over a range of Schmidt numbers from 40 to 57 and Reynolds numbers from 5,550 to 22,500. Information concerning the mechanism for mass transfer was obtained by measuring local solution and deposition rates as a function of distance along the tubes. Observed entrance effects for the solution process suggest that it involves the parallel mechanisms of diffusion through a solid film and through occluded liquid in grain boundaries. It is indicated that the relative contributions of these processes changes with increasing temperature.A j-factor correlation of existing liquid metal mass transfer data for fully developed conditions in circular conduits is presented and indicates that an exponent of 0.112 for NRe best represents the data. This result agrees well with other studies (9).
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    AIChE Journal 7 (1961), S. 329-335 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The principles involved in designing a process for the production of fixed nitrogen by the direct use of fission fragment recoil energy are reviewed. The problems concerned with the radiation chemistry, development of fuel element, reactor design, and chemical process design are pointed out. Possible solutions to these problems incorporated in a complete plant design are presented. An economic evaluation, comparing the chemonuclear process with other conventional processes, is made. The conclusion is reached that at the present state of knowledge there does not seem to be any clear-cut advantage over conventional processes, even based on a nuclear economy. However moderate research efforts should continue for further evaluation of this process.
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    AIChE Journal 7 (1961), S. 347-348 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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    AIChE Journal 7 (1961), S. 350-351 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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    AIChE Journal 7 (1961), S. 352-352 
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  • 95
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    AIChE Journal 7 (1961), S. 5J 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 7 (1961), S. 355-355 
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    Keywords: Chemistry ; Chemical Engineering
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    AIChE Journal 7 (1961), S. 371-375 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A recirculation type of apparatus with a novel liquid-sampling system was used to obtain liquid-vapor equilibrium data for the hydrogen-nitrogen and deuterium-nitrogen systems at 90° and 95°K. and pressures up to 1,000 lb./sq. in. abs. The data obtained show an average scatter in liquid compositions of the order of 0.01%, thus proving the feasibility of the new liquid-sampling system. The vapor samples are shown by thermodynamic analysis to scatter less than 0.1%. Deuterium is slightly more soluble in liquid nitrogen than hydrogen; the relative volatility is 1.198 at 90°K. and about 1.177 at 95°K. The relative volatility is practically independent of pressure; thus at 90°K. the relative volatility decreases from 1.198 at 100 lb./sq. in. abs. to 1.196 at 1,000 lb./sq. in. abs., but this range of values is well within the experimental error.
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    AIChE Journal 7 (1961), S. 295-298 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The solubilities of acrylonitrile and styrene in low-density polyethylene were measured at 0° and 27°C. over the entire range of compositions.The ternary solubility data were analyzed in terms of the relationships developed by Krigbaum and Carpenter. It is shown that the behavior of the ternary system may be predicted from the Flory-Huggins interaction constants of the three pairs of binaries.The rates of desorption of acrylonitrile and styrene from 48 mil thick sheets of polyethylene were measured at 27°C.
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    AIChE Journal 7 (1961), S. 308-311 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An equation is derived for the multimolecular adsorption isotherm in the range where capillary adsorption is insignificant. The equation is demonstrated to apply quantitatively to the entire range of relative vapor pressure. It is shown that this equation reduces to the equation of Brunauer, Emmett, and Teller at lower relative vapor pressures.Application of this equation to data in the literature showed good agreement. The standard deviation of the data from the equation was in the same order of magnitude as the scatter of the data themselves. Although the application of this equation was largely to water vapor adsorption systems, several applications to other systems correlated equally well.
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    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 530-530 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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