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  • 1970-1974  (356)
  • 1800-1809
  • 1973  (356)
  • Chemical Engineering  (356)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 58-67 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new model for porous media comprised of monosized, or nearly monosized grains, is developed. In applying this model to a packed bed, the bed is assumed to consist of a series of statistically identical unit bed elements each of which in turn consists of a number of unit cells connected in parallel. Each unit cell resembles a piece of constricted tube with dimensions which are random variables. The problem of flow through each unit cell is reduced, subject to reasonable assumptions, to the determination of the flow in an infinitely long periodically constricted tube. The solution of this flow problem is given in a companion publication. This model, together with the solution of the flow through it, can be used for the modeling of processes which take place in the void space of a bed.As a preliminary test, theoretical friction factor values, based on the proposed model, were compared with experimental ones for two different beds and found to be in good agreement even in the region of high Reynolds numbers where the nonlinear inertia terms are significant.
    Additional Material: 6 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 94-101 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analytical study was carried out on the effects of mixing on radiation-induced polymerization in which the species initiating the polymerization were not uniformly produced because of a nonuniform dose rate distribution. The analysis is based on the periodic irradiation of fluid elements circulating in a stirred-tank reactor having a high dose rate region and a very low dose rate region. It is shown that the rate of polymerization increases with agitation speed and that the bimodal molecular weight distribution of the polymer formed at low agitation speed moves to a unimodal distribution as the agitation speed increases.
    Additional Material: 11 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 145-151 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid-vapor phase equilibria measurements were made at 112.00 K on the binary systems nitrogen-argon, nitrogen-methane, and argon-methane and the ternary system nitrogen-argon-methane. Values of gE, the excess Gibbs free energy, have been calculated from the experimental data for all the systems studied. The data and derived gE values for the binary systems were compared with the results of previous investigations with satisfactory agreement.
    Additional Material: 8 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 167-173 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A generalized equation of state is developed by combinin a hard-sphere equation with a truncated virial equation and generalizing the reduced hard-sphere diameter as a function of reduced temperature and acentric factor. The new equation quantitatively agrees with Pitzer's table of compressibility factor over wide ranges of gas and vapor states and is always better than the truncated virial equation. Since the terms in the equation are physically meaningful it is capable of being improved systematically by including higher virial coefficients and by using hard-core equations of state for nonspherical cores. The equation is extended to mixtures with well-developed combination rules.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 183-185 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 112-119 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A geometric model for an homogeneous and isotropic porous medium composed of spherical particles is proposed. This model requires a minimum of geometric simplifications and lends itself to the study of hydrodynamic as well as diffusive flow processes, permitting in each application a mathematically rigorous and fully predictive analysis leading to mathematical representations of the respective flow parameters.This particular investigation seeks to evaluate, and to provide physical insight into, diffusive flow processes occurring within an homogeneous swarm of spherical particles.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 371-372 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 8
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    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 379-381 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 335-343 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Structured design systems are systems which may be represented by generally nonlinear equality and inequality constraints, each of which contains few of the variables in the system. Assuming the existence of an automatic capabity to derive and modify as needed effective solution procedures for sets of structured equality constraints, a two-step strategy for optimizing design systems is presented in the form of two algorithms. An earlier paper presented an algorithm for locating a first feasible point, and this paper presents a companion algorithm based on the strategy known as restriction to optimize the system once feasible.This companion algorithm divides the set of inequality constraints into three sets: the set of those currently being held as equality constraints, the set currently released but being used as search coordinates, and the set of all remaining constraints which are not currently part of the problem. Solution procedures are modified as inequality constraints and are moved from one set to another. Added constraints in the set being held tend to aid the optimization process by reducing the dimension of search space for what is usually a marginal added burden in solving an enlarged set of (structured) equations.The strategy has proved remarkably effective on three relatively simple examples, including a nonlinear 31 constraint, 10 variable alkylation problem.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 356-364 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Models are developed to describe sintering of metal crystallites during heat treatment. The growth rate of such crystallites is assumed to depend upon particle migration over the surface of the support as well as on the rate the colliding particles merge (sinter) into a single unit. The theory predicts that the rate of decay of exposed metal surface area S is given as in Equation (1a). The exponent n is related to the assumed size dependence of the diffusion coefficients or of the rate constant of the merging process. It varies from 4 to 8 for diffusion controlled decay and it is less than 3 for sintering controlled decay, that is, when the rate controlling step is the merging of two colliding particles. Diffusion control is associated with strong interactions between the metal and the support, but in sintering control there is a weaker metal-support interaction.
    Additional Material: 4 Ill.
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  • 11
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 373-375 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 12
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 382-384 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 13
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 395-398 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 403-407 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 15
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 412-413 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 414-414 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 17
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 540-546 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The isothermal compressibility (at constant composition x) kT,x, was calculated in the neighborhood of the critical locus for seven mixtures containing 3.5 to 19.6 mole % heptane and analyzed in terms of the reduced pressure variable σ = (P - P̂)/P̂ where P̂ is the pressure at which kT,x becomes very large. The data can be represented by the equation kT,x = const. σ-λ along the critical isotherm and one near it and by the locus P̂(T). λ was found to be a strong function of x. The divergence of the isothermal compressibility of the mixtures near the critical locus is in conflict with predictions from classical equations of state but in accordance with modern concepts of the critical region.
    Additional Material: 10 Ill.
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  • 18
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 546-551 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The extension of the Enskog theory by Tham and Gubbins for the calculation of diffusivities is applied to the prediction of infinite dilution diffusion coefficients in binary organic systems. The resulting expression is a function only of the size and mass of the diffusing species. Excellent agreement is obtained for nonassociating n-alkane mixtures as well as for associated systems. Extension of the expression to alcohol and aqueous systems is shown to require Only an empirical correction factor. It is also shown that the quantity Dij∞ ηj Mj/ρjT is independent of temperature for all systems.
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  • 19
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 566-574 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Techniques are developed for using the structural information contained in algebraic equation sets to aid in the study of convergence properties of iterative equation loops.The concept of inverse mapping is applied directly in order to study convergence properties of sequences. For problems in which there exist both a direct and inverse path for the computation of iterative loops, direct substitution techniques will converge via one path and diverge via the other path. When an inverse path existed, the direct substitution method was superior to simultaneous solution techniques for the problems studied. Not all iterative loops have an inverse path. For problems in which inverse paths do not originally exist, rearrangement of the equations of an iterative loop can result in a modified loop for which an inverse path does exist. The digraph representation of an iterative loop aids in deciding whether rearrangements are feasible for a particular problem. When inverse paths cannot conveniently be obtained, direct substitution cannot be successfully used and simultaneous solution techniques such as quasi-linearization are recommended.
    Additional Material: 13 Ill.
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  • 20
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 602-608 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Particle size measurements of chromium hydrous oxide sols using electron microscopy and light scattering techniques were in excellent agreement. Comparison was based on the most probable diameter and width of the distribution. The normal, lognormal, and zero-order logarithmic density functions provided good first-order approximations to the particle size measurements. The chromium hydrous sols were less than 0.5 μm in size.A closed wet cell specimen holder in an electron microscope was developed to observe, in situ, the chromium hydrous oxide sols. The colloidal particles had a uniform spherical shape with a narrow size distribution. Observation of the particle formation process in the closed wet cell qualitatively supports the mechanism that basic polymeric sulfates act as embryos in the formation of these particles.
    Additional Material: 12 Ill.
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  • 21
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 628-635 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect on the liquid-phase effective diffusivity in fine pores of the ratio of solute molecular diameter to pore diameter and of preferential solute adsorption was studied by measurements on homogeneous silicaalumina bead catalyst (pore diameter = 3.2 nm). A proposed empirical correlation is based on the investigation of a variety of binary systems of paraffins and aromatic hydrocarbons and of aqueous solutions of sugars.
    Additional Material: 4 Ill.
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  • 22
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 640-644 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 23
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 652-655 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 24
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 387-389 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 25
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 26
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gas-liquid chromatography is used to measure polymer-solvent interactions in polymer solutions where the solvent is at infinite dilution. Experimental data are presented for 24 binary polymer-solvent systems in the temperature range 50° to 150°C. A simple relation exists between the experimental retention volume data and the infinite dilution volatility; this volatility can be used to calculate the solvent vapor pressure over the polymer solution up to about 0.1 weight fraction solvent. Using concepts from the Prigogine-Flory theory of polymer solutions, Flory-Huggins X parameters for some polymer-hydrocarbon systems were correlated with the hydrocarbon's normal boiling temperature.
    Additional Material: 7 Ill.
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  • 27
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 736-741 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Cyclic Polyethers acting as mobile carriers in facilitated transport can cause changes of as much as three orders of magnitude in the fluxes of various cations across liquid membranes. The cyclic polyether dibenzo-18-crown-6 (2,3,11,12-dibenzo-1,4,7,10,13,16-hexaoxacyclooctadeca-2,11-diene) was used in this work to achieve such a large selectivity. The results show that a primary factor leading to the selectivity is the ratio of unsolvated cation radius to polyether central ring radius. The implication is that by selecting a polyether with a desired central ring radius, any two cations of slightly different radius can be separated efficiently.
    Additional Material: 7 Ill.
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  • 28
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 673-683 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 29
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 445-452 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Atactic polystyrene was molded at pressures up to 3000 atmospheres, and the effects of this pressure history were studied by permeability measurements using helium, neon, and argon as probe molecules. The permeabilities were significantly reduced by molding at higher pressures. The diffusion coefficients decreased monotonically with molding pressure, reflecting more extensive interchain cohesion. In contrast, the solubility coefficients showed a broad minimum around a molding pressure of 1000 atm, indicating that changes in local order were induced by higher pressures. These changes were shown to affect permeation, mechanical characteristics, and other properties. An optimum molding pressure somewhat below 1000 atm is indicated for polystyrene.
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  • 30
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 486-497 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Marker-and-Cell numerical technique has been adapted to develop a method of solution for three-dimensional, unconfined, isothermal flow of a highly viscous, Newtonian fluid in a region bounded by two, nonparallel traveling surfaces. Results are reported only for plane and elliptical surfaces, but the analysis is general enough to handle any shape of interest.A computer program was developed which can be used to generate and plot the flow and pressure fields. Numerical results were obtained for the special case of symmetrically opposed convergent surfaces for a wide range of conditions.
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  • 31
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 517-521 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Filter equations for linear delay systems with continuous-time dynamics and discrete-time measurements are derived by separating the estimation problem into prediction between measurements and updating at a measurement. The result is the analog of the well-known Kalman filter for the nondelay case. A computational technique for implementing the filter is indicated and illustrated by an example of a scalar system with a delay in the dynamics as well as measurement.
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  • 32
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 533-540 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Molar volumes were measured and partial molar volumes were calculated in the supercritical region, including the vicinity of the critical locus, lor compositions of 1.8 to 20 mole % n-heptane. Molar volumes can he represented, to a reasonable approximation, by the Flory-OrwollVrij (FOV) reduced equation of state. A better fit of the data is possible if the three exponents in the FOV equation are adjusted The irodified FOV equation or the Redlich-Kwong equation, with parameters idjusted to fit the critical locus, can in general represent the partial molar rolumcs adequately along the critical locus only. The prediction of the imposition-dependence of the partial molar volumes is only qualitatively successful at best.
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  • 33
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 934-942 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An algorithm that combines structural equation analysis with algebraic rearrangement and substitution has been developed to precedence-order algebraic chemical process equations. The SWS (Structural Analysis with Substitutions) algorithm selects an output variable for each equation, rearranges the equation to solve for that variable, and reduces the number of equations by substitution. The algorithm has been used for computer generation of Fortran programs to perform meterial and energy balances in the design of chemical processes.
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  • 34
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 658-659 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 35
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 666-667 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 36
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 671-671 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 37
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 698-703 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The diffusion coefficients D of n-hexane and of naphthalene in a series of hydrocarbon liquids with viscosities μ from 5 · 10-4 to 5 kg m-1 sec-1 (0.5 to 5000 centipoise) have been measured at 25°C with a one Savart plate wavefront-shearing interferometer. This apparatus allows direct determinations at effectively infinite dilution. The values obtained suggest that for a small solute diffusing in a large solvent \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{*{20}c} {D\mu ^{2/3} } & = & {{\rm constant}} \\ \end{array} $$\end{document} a result consistent with earlier studies. The exponent of 2/3 may be rationalized on the basis of the Eyring rate theory.
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  • 38
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 729-735 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid molar volumes and excess volumes have been experimentally determined for some methane-rich binary and ternary mixtures containing ethane, propane, isobutane, and nitrogen between 91 and 115 K. A gas expansion type system calibrated against pure methane densities was used to make the necessary pure fluid and mixture measurements.The best of the available density correlations predicts the experimental methane-ethane molar volumes within ±0.2%, while larger systematic deviations are found for the methane-propane and methane-isobutane systems. Molar volumes for methane-nitrogen and ternary mixtures containing nitrogen diverge strongly from the correlation predictions at 108 K and higher temperatures. An empirical scheme is proposed for predicting molar volumes of methane-rich liquefied natural gases using reported methane-ethane and methane-nitrogen excess volumes. This method predicts all binary and ternary molar volumes from this investigation within ±0.1%.
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  • 39
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    AIChE Journal 19 (1973), S. 753-759 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Multicomponent vapor condensation in the presence of noncondensing gas has been analyzed using numerical solutions to a set of linearized rate equations that describe the simultaneous heat and mass transfer to the condensate film. For specific examples of methanol and water and ethanol and toluene condensing from turbulent air streams in vertical tube and on horizontal tube condensers, it is shown that the alcohol concentrations in both the liquid and gas phases increase as condensation from initially superheated, alcohol-rich gas phases progresses; the liquid phases also become richer in alcohol. The mass fluxes of the vapors vary with their respective mass transfer coefficients and local concentration driving forces. In the vertical tube condensers, the flux of the alcohols go through maximums. Gas phase saturation is approached as the mixtures cool and the final traces of vapor become more difficult to condense. Interface properties are computed from limited VL equilibrium data, heat of solution data, and a predictive equation. The techniques of solution and analysis have general application to the design of cooler-condensers in either vertical or horizontal configurations.
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  • 40
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    AIChE Journal 19 (1973), S. 1284-1285 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 41
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    AIChE Journal 19 (1973), S. 1247-1249 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 42
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    AIChE Journal 19 (1973), S. 1258-1259 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 43
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    AIChE Journal 19 (1973), S. 1254-1257 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 44
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    AIChE Journal 19 (1973), S. 1263-1265 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 45
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    AIChE Journal 19 (1973), S. 1283-1283 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 46
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    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 47
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    AIChE Journal 19 (1973), S. 1060-1061 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 48
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    AIChE Journal 19 (1973), S. 1070-1072 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 49
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    AIChE Journal 19 (1973), S. 1196-1204 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Quasi-elastic light scattering techniques have been employed to measure the mutual diffusion coefficient DAB as a function of concentration in eight binary mixtures and the thermal diffusivity x in nine pure liquids and two binary mixtures. The mass diffusivities obtained are typically accurate to 3% while thermal diffusivities are known to be accurate to 5%; both types of values are in substantial agreement with the available bulk values. Under most circumstances light scattering is found to offer distinct advantages over the standard techniques for determining mass and thermal diffusivities.
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  • 50
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    AIChE Journal 19 (1973), S. 1244-1246 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 51
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    AIChE Journal 19 (1973), S. 1252-1254 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 52
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    AIChE Journal 19 (1973), S. 1262-1263 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 53
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    AIChE Journal 19 (1973) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 54
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    AIChE Journal 19 (1973), S. 15-21 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Theoretical models for computing velocity profiles and friction factors for sinusoidally pulsing laminar flow in linearly elastic tubes were derived from the Navier-Stokes equations, a modified Fanning equation, and the pressure-tube wall movement relationship. The theoretical results were checked experimentally for NRe and λ = ωR2/v values up to 2000 and 57, respectively. It was found that the theoretical friction factors predicted the experimental values to within less than 13%. Also the results showed that the energy losses in elastic tubes were greater than in rigid tubes.
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  • 55
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    Notes: The thermoelectrogravitational electrophoresis column without reservoirs has been conceived following the principle of the Clusius-Dickel thermal diffusion column. The transport equation approach in thermal diffusion developed by Jones and Furry to explain the behavior of a conventional thermogravitational thermal diffusion column has been applied to describe the electrophoretic separation in the thermoelectrogravitational electrophoresis column. Equations have been established for a system in which one single or one hypothetically single component is mobile and the other species are at their isoelectric points.Theoretical calculations for the velocity profiles, temperature distribution, and the steady state batch separation factors have been made with field strength, temperature difference, membrane spacing, and electric mobility as variables, and expected trends of the results are discussed using the steady state solution of the transport equation for batch operation.
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  • 56
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    AIChE Journal 19 (1973), S. 76-84 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Theoretical equations and graphs are presented for filter cake reslurrying and washing with linear solute sorption.In the case of washing, the filter cake was represented by a model consisting of a number of mixing cells in series. Due to the complexity of the model, explicit algebraic solutions could not be obtained for countercurrent washing, but numerical data were generated using a computer.Practical application of the above is outlined.
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  • 57
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    AIChE Journal 19 (1973), S. 102-111 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The physical and mathematical characteristics of carrier-facilitated transport in a liquid film are examined for a reaction scheme of the form A + B ⇄ AB, in which A is the permeating species and B and AB are diffusable species which are constrained not to leave the film. For thin films, a solution is developed as a perturbation from purely physical diffusion and is expressed as a second-order power series. For thick films, a solution is developed as a perturbation from a state in which the species concentrations at any one point within the film are related by an equilibrium constraint. This development utilizes the techniques of matched asymptotic analysis. Taken together, these solutions provide an excellent estimate of the facilitation for a film of any thickness, as shown by comparison with numerical results.
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  • 58
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    AIChE Journal 19 (1973), S. 129-137 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The suboptimal control algorithms developed in Part I are tested on four example problems to obtain some indication of their performance. Results are presented and compared with results obtained from the application of classical open-loop optimal control synthesis algorithms to the same test problems.The suboptimal feedback control algorithms are found to give acceptable performance on both linear and nonlinear systems at the expense of very little computational effort.
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  • 59
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    AIChE Journal 19 (1973), S. 159-166 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Adsorption from liquid mixtures can be predicted from the adsorption isotherm of the pure unsaturated vapor, measured for each component of the liquid mixture. The theory gives analytical expressions for adsorption from liquids corresponding to Type I (finite capacity) and Type II (multilayer adsorption) vapor isotherms. The free energy of immersion of the adsorbent in the pure liquid adsorbate is the essential parameter for either type of adsorption. Predictions based upon the assumption of an ideal adsorbed solution are compared with experimental data on adsorption from liquid mixtures.
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    AIChE Journal 19 (1973), S. 177-178 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 19 (1973), S. 188-191 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 19 (1973), S. 195-196 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 19 (1973), S. 202-204 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 19 (1973), S. 206-206 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    AIChE Journal 19 (1973), S. 207-207 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 66
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    AIChE Journal 19 (1973), S. 230-237 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The hydrodynamics of countercurrent flow of liquids with a high density difference cannot be predicted reliably from correlations developed with data on fluids having low densities (usually water and organic solvents). Dispersed-phase holdup, flooding rates, and pressure drop during countercurrent flow of mercury and water were studied with several packing materials. Results show that, for a given packing, flooding rates and holdup can be correlated in terms of a single parameter, the superficial slip velocity. For the mercury-water system, this parameter is shown to be proportional to the packing diameter and packing void fraction for Raschig rings and solid cylindrical packing.
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  • 67
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    AIChE Journal 19 (1973), S. 251-258 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Structured design systems are systems in which the equations representing the equality and inequality constraints are sparse and highly precedenc orderable. An algorithm has been developed for such systems which is guaranteed, under certain assumptions, to arrive in a finite number of steps at a feasible point (that is, one which satisfies all the constraints) or to identify a subset of the constraints for which no feasible point can be found. The algorithm can be applied to a system with only inequality constraints or to a system with both equality and inequality constraints.The algorithm uses an indirect approach. It hypothesizes that a subset of constraints has no feasible region and then attempts to verify this conjecture. If successful, the subset is identified as infeasible and obviously no feasible point exists. If unsuccessful, either a new hypothesis can be generated or the algorithm has indirectly found a feasible point.Limited computational experience with the algorithm indicates that the number of steps required to find a feasible point for a system of constraints has been of the same order of magnitude as the total number of constraints in the system. For linear constraints, the efficiency of the algorithm has been comparable to phase one of the Simplex algorithm of Linear Programming.
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  • 68
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    Notes: Two forms of a generalized Benedict-Webb-Rubin Equation, BWR24 and BWR44, are proposed for dense gases which represent an improvement by a factor of about three in calculated pressures compared to reduced forms of this relationship in the literature. The method is also tested for accuracy in predicting enthalpy departures for pure components and mixtures. The proposed methods are marginally better than the best of other methods tested. Major advantages for the proposed equations are their relative simplicity, low computer storage requirements, and generality. No mixture interaction constants are required other than those already available in the literature.
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    AIChE Journal 19 (1973), S. 313-320 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A generalized analytic correlation is presented for activity coefficient. osmotic coefficient, enthalpy, and heat capacity of single and multicomponent strong aqueous solutions. A good correlation for each salt to an ionic strength of six is obtained by assigning a single parameter “B” value to each salt. These B values are well approximated by assigning two parameters for each ion. Values presented for the common ions at 25°C allow the estimation of activity and osmotic coefficients of many unmeasured salt solutions.
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    AIChE Journal 19 (1973), S. 343-348 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Diffusion coefficients of binary solutions can be measured accurately by observation at long times of isothermal diffusion in a vertical cell closed at the ends (restricted diffusion). The present analysis, which accounts for the effects of solvent flux and variable solution properties, demonstrates that the experiment yields a well-defined, differential diffusion coefficient, even in concentrated solutions.Observation is effected by Rayleigh interference optics, and results for aqueous potassium chloride solutions confirm the accuracy of the method.
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    AIChE Journal 19 (1973), S. 368-369 
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    AIChE Journal 19 (1973), S. 375-376 
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    AIChE Journal 19 (1973), S. 384-386 
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    AIChE Journal 19 (1973), S. 398-400 
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    AIChE Journal 19 (1973), S. 401-403 
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    AIChE Journal 19 (1973), S. 408-409 
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    AIChE Journal 19 (1973), S. 412-412 
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    AIChE Journal 19 (1973), S. 414-416 
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    AIChE Journal 19 (1973) 
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    AIChE Journal 19 (1973), S. 453-459 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The theory of adsorption from binary liquid mixtures on solids is extended to an arbitrary number of components. An equation for the surface excess is derived in terms of the free energy of immersion of the adsorbent, the capacity of the adsorbent at saturation, and activity coefficients in the bulk and adsorbed phases.Experimental data are reported for adsorption from binary and ternary liquid mixtures of benzene, ethyl acetate, and cyclohexane on activated carbon at 30°C. These systems exhibit nonidealities in the adsorbed phase. The theory provides accurate estimates of adsorption from the ternary mixture using data for adsorption from binaries.
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    AIChE Journal 19 (1973), S. 474-481 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of specific gravity differences as a primary factor of nonideal mixing was investigated and demonstrated by means of a combined M-T (mixed-tubular) reactor in a simple cylindrical flow tank. Specific gravity differences were provided by a temperature gradient created by a strongly exothermic, second-order adiabatic chemical reaction. The results also allow investigation of the effects of the inlet feed rate, agitator diameter, and speed on the agitator fraction of the combined reactor.
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    AIChE Journal 19 (1973), S. 504-510 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dynamic responses of five electrodes were measured by pulse testing. The electrodes were three pH electrodes a calcium-ion electrode, and a chloride-ion electrode. Measurements were made at temperatures from 1° to 50°C. The responses of their electrodes were analyzed to give the transfer function containing first- and second-order time constants and a dead time.
    Additional Material: 9 Ill.
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  • 83
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 527-532 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An improved procedure is presented for the calculation of detailed steady-state temperature distributions throughout the human body. The efficacy of the proposed computation procedure is demonstrated by comparison of calculated and experimental results for seven studies conducted on four subjects. Core temperatures were predicted within ±0.2°C and deviations for individual skin temperatures generally were within ±0.5°C.
    Additional Material: 7 Tab.
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  • 84
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 552-558 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental investigation of the penetration distance required for complete condensation of a submerged turbulent vapor jet injected into a quiescent liquid bath of the same material was made. The bath was maintained in a subcooled condition at a temperature below the boiling temperature of the liquid at the bath pressure. The experiments were limited to choked injector Hows with the penetration regime such that buoyancy effects are negligible. Tests were run for water, ethylene glycol, and iso-octane over a range of flow rates and bath pressures. A theoretical expression for the vapor penetration distance was developed utilizing a variable density single fluid model for the two-phase flow, with the turbulent mixing process treated by an entrainment law. Corrections for the external expansion of the choked flow beyond the injector exit were also determined. This model was found to correlate the results of both the present experiments and those of earlier investigators over a wide range of operating conditions and injector geometries.
    Additional Material: 3 Ill.
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  • 85
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 579-589 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The problem of determining real-time (episode) air pollution control strategies for an urban airshed is posed as selecting those control measures from among all possible such that air quality is maintained at a certain level over a given time period and the total control imposed is minimum. The real-time control is based on meteorological predictions made over a several-hour to several-day period. A computational algorithm is developed for solving the class of control problems that result. The theory is applied to a hypothetical study of the effect of implementation of the optimal control on September 29, 1969, in the Los Angeles basin.
    Additional Material: 7 Ill.
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  • 86
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 608-617 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: At the forward stagnation point of a bluff body the laminar flow is influenced by externally generated free-stream turbulence, such as from grids, in such a way that heat and mass transport are significantly enhanced above their normal values. The basis of this enhancement is an unsteady, threedimensional flow pattern formed at the forward stagnation point and triggered or altered by the free-stream turbulence. Such complex flows can be interpreted as roll cells oriented with their axes parallel to streamwise coordinates. Such roll cells have been observed by other investigators using special experimental visualization techniques. This complex flow was introduced into the momentum and transport equations, which were then solved numerically to produce the relationships between Nusselt, Reynolds, and Prandtl numbers and free-stream turbulence. Not only were these relationships nearly identical with earlier established empirical correlations, but they revealed in addition a strong augmentation for high Prandtl number flows. Predictions in slurry flows around bluff bodies were also found to be reasonable.
    Additional Material: 14 Ill.
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  • 87
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 636-637 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 88
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 645-646 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Tab.
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  • 89
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 655-657 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 90
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 664-665 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 91
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 671-671 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 92
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 684-698 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Perturbation methods relate thermodynamic and transport properties of the system of interest (gas or liquid) to the known properties of some reference system; commonly used reference substances are hard sphere fluids and argon. Developments since 1967 are reviewed for both types of approach, with emphasis on applications to liquid mixtures of practical interest. Calculations for liquid mixtures of simple and complex molecules, gas solubility in liquids, fused salts, electrolytes, solvent extraction systems, and liquid metals are reviewed.
    Additional Material: 9 Ill.
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  • 93
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    AIChE Journal 19 (1973), S. 720-728 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements of the size and rate of shedding of wakes of drops, average drop holdup and velocity of the continuous phase as functions of drop size for kerosene, hexane, and benzene dispersed in water in a liquid-liquid fluidized bed are reported. The average drop size ranged between 3.3 and 4.8 mm. The water velocity was 5.0 to 12.05 cm/s. The average drop hold up was 0.065 to 0.560.The ratio of wake to drop volume was 0.2 to 2.4, and the rate of wake shedding, reported as time of wake transfer units, was 0.7 to 2.4. At low drop holdups, the effect of single drops and groups of drops is dominant. At high drop holdups, the effect of neighboring drops and wakes is dominant. The wake size is correlated with slip velocity and can be calculated from empirical holdup measurements.
    Additional Material: 17 Ill.
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  • 94
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The three-parameter tabular correlation of Pitzer et al. for calculating the compressibility factor of pure components has been extended to lower temperatures in the region where Tr is from 0.5 to 0.80 and Pr is from 0 to 9. The compressibility-factor is expressed linearly in the acentric factor Z = Z(0) + ωZ(1) with values of Z(0) and Z(1) tabulated in terms of Tr and Pr. The generalized correlation has been tested for 21 compounds with a total number of 463 data points. The average deviations in the calculated compressibility factors are 1.63% for the compressed liquids and 0.67% for the gases.
    Additional Material: 2 Ill.
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  • 95
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    AIChE Journal 19 (1973), S. 775-783 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The flow of air through packed beds of solid and hollow particles of a wide range of geometries was studied, with particular reference to the effect of the particle shape on the pressure drop in the turvbulent range. A method of analysis based on the concept of stagnant void fraction and the principle of drag additivity has been developed. Equations for estimating the stagnant voidages for various particle shapes arranged in a random pattern in a packed bed were derived. A new type of friction factor based on this approach was correlated satisfactorily with a shape factor. The momentum transfer data were also correlated with the sphericity of the particles.
    Additional Material: 5 Ill.
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  • 96
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    AIChE Journal 19 (1973), S. 802-806 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A six-parameter multiresponse model based on the catalyst aging theory of Wojciechowski (1968) is applied to experimental selectivity data in gas oil cracking. Within the range of conditions studied, the model gave an adequate fit to the data. It was found that the selectivity curves at various cat/oil ratios were contained within optimum and minimum performance envelopes but that the relationships between these envelopes and the selectivity curves were not quite as simple as had previously been reported for a theoretical example (Campbell and Wojciechowski, 1969). The optimum time-on-stream for each of the cat/oil ratios was about one minute. Maximum gasoline production was 59 weight % at 81 weight % total cumulative conversion, resulting in a gasoline efficiency of 72.8%.
    Additional Material: 3 Ill.
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  • 97
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 832-839 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Asymptotic analytic expressions for the concentration and temperature profiles as well as effectiveness factor inside porous, thin-disk shaped catalyst particles have been developed for zeroth-order exothermic reaction with reactant-to-product volume change. The individual and combinative effects of volume-change, Thiele and thermal Thiele moduli, and of the dimensionless activation energy are discussed. As expected, the expressions revert to those for the corresponding isothermal and constant-volume cases. Errors arising from the approximation were calculated and found to be quite acceptable.
    Additional Material: 11 Ill.
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  • 98
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    AIChE Journal 19 (1973), S. 851-852 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 99
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 858-859 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 100
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 19 (1973), S. 862-863 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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