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  • 1985-1989  (3,542)
  • Chemical Engineering  (3,542)
  • 101
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 325-328 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 102
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 353-353 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 103
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 876-876 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 104
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 105
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 876-876 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 106
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 881-890 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An on-line procedure is developed that uses estimates of the dominant eigenvalues of a reactor-exchanger system to detect impending unstable operating behavior. In the event reactor stability is threatened, changes are made in the reactor's nominal operating state through a procedure that ensures the attainment of an accessment is made through estimation of closed-loop eigenvalues derived from a physically-based dynamic model. The guiding of the reactor to safe and stable conditions is carried out through a multiloop control system that receives optimal process setpoints found from an interative search. Experiments were made on a laboratory autothermal reactor system to assess the correspondence of the predicted and observed degrees of reactor stability.
    Additional Material: 9 Ill.
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  • 107
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 931-942 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dynamic gas disengagement technique is discussed comprehensively in this paper. Also outlined is the procedure for estimating holdup structures and bubble rise velocities in a bubble column, which is extended to include the methodology for estimating the Sauter mean bubble diameter and therefore the specific gas-liquid interfacial area. The error limits for the estimated quantities are established using two extreme cases to describe the disengagement process: constant rate disengagement and interactive disengagement of bubbles. The analysis is done assuming a bimodal bubble size distribution; however, generalized equations for a multimodal bubble size distribution are also presented. Sensitivity of results to the two cases is illustrated using results obtained from experiments conducted with the air-tap water system in two bubble columns (0.05 and 0.23 m in diameter, 3 m tall). Sauter mean bubble diameters and specific interfacial areas estimated using the two approaches provide lower and upper limits for values reported in the literature.
    Additional Material: 8 Ill.
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  • 108
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 500-506 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A calcium hydroxide [Ca(OH)2] sorbent modified by the addition of calcium lignosulfonate has recently been developed for use in the Environmental Protection Agency's limestone injection multistage burner process. The increased reactivity with sulfur dioxide (SO2) displayed by this modified sorbent has been shown to be caused, in part, by its decreased particle (agglomerate) size compared to conventional Ca(OH)2. Subsequent work has shown that surfactant-modified Ca(OH)2 also undergoes significantly different structural changes during furnace injection. For a given reactor temperature and residence time, the modified sorbent calcines to a greater extent than unmodified sorbent. It also loses surface area more slowly, and retains more of its porosity, suggesting that it sinters more slowly than conventional sorbent. Therfore, in addition to reducing the particle size of Ca(OH)2 in some applications, calcium lignosulfonate also to inhibit one or more of the diffusion mechanisms responsible for the process of sintering.
    Additional Material: 10 Ill.
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  • 109
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 519-522 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 110
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1039-1043 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 111
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 112
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1157-1169 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The proposed on-line adaptive optimization technique incorporates a priori knowledge in the form of approximate steady-state models. The steady-state geometric characteristics of the model are periodically recalculated using a Hammerstein system and recursive least squares. The algorithm is self-tuning in the sense that it converges to the optimal performance provided that a matching condition is satisfied and that the data are persistently exited. Simulation and experimental studies performed on a continuous fermentation system have been conducted to illustrate the performance of the optimization algorithm and demonstrate the viability of adaptive extremum control.
    Additional Material: 11 Ill.
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  • 113
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1195-1198 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 114
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 115
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1224-1226 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 116
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 673-675 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 117
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 686-689 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 118
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 700-701 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 119
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1211-1214 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 120
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1328-1336 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The solid circulation in the annular region of a 0.146 and a 0.292 m ID semicylindrical and cylindrical air spouted beds was investigated for different spouting conditions. Stroboscopic photography, stopwatch and fiber optic methods were used to measure the vertical particle velocities in the annular region. The optical fiber probe enabled the measurement of particle velocities inside the dense annular phase and was validated at the walls. Velocity profiles in half beds were very different from those found in full beds. The work was then limited to full beds. Experimental results show that the solids flow is characterized by a point sink at the nozzle entrance with the solids moving almost in plug flow higher in the bed. There is negligible entrainment of solids along the spout wall and slow, thin wall layers are observed near the walls and spout. The velocity profiles are independent of the total height of the bed. A kinematic model successfully describes the observed velocity field.
    Additional Material: 12 Ill.
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  • 121
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1365-1369 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 122
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1385-1390 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 123
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1215-1218 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 124
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 845-848 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 125
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 831-844 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The novel combination of a pressure swing adsorber (PSA) with a periodic flow-forced packed-bed reactor is explored. The device provides integral component separation and reaction. Feed sequences studied for the periodic separating reactor (PSR) were those of rapid, single-bed pressure swing adsorption (RPSA). The experimental investigation employed CO oxidation over a packed bed of supported platinum catalyst and molecular sieve adsorbent. A reaction rate limited model is formulated and solved for a variety of irreversible and reversible reactions.The presence of irreversible chemical reaction is shown to greatly enhance the separation achievable by RPSA alone. For a wide range of inlet CO/O2 ratios, CO2 production could be increased up to two times over steady-state plug-flow reactor operation, while providing a recycle stream without phase change or extractive procedures. Selectivity and conversion improvements were predicted for multiple reaction systems. Other unusual features of operation, such as separation reversals, were also predicted and observed.
    Additional Material: 13 Ill.
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  • 126
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1395-1398 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 127
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1497-1508 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: For particle deposition from log-normal polydispersed aerosol streams by one or more of several mechanisms described by piecewise-power-law mass transfer coefficients, we derive useful relations between actual total mass deposition rates and the ‘reference’ rate one would calculate by imagining that all particles in the mainstream population had the average particle volume v(=φp/Np). Included here are diffusion or inertial mechanisms for laminar- or turbulent-boundary layers, free-molecular or continuum diffusion at high Peclet numbers of dense spherical particles, or fractal agglomerates. The mainstream particle volume distribution is considered to be log-normal with arbitrary ‘spread’ parameter, thereby generalizing earlier results for “coagulation-aged” (self-preserving) distributions. Further generalizations include transitions between important particle transport mechanisms, opening the way to efficient, finite-analytic methods for predicting mass deposition rates for arbitrary, size-dependent particle capture efficiencies.
    Additional Material: 11 Ill.
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  • 128
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1535-1542 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Many industrially important processes feature both nonlinear system dynamics and a process deadtime. Powerful deadtime compensation methods, such as the Smith predictor structure in state space for linear systems is presented first and then directly extended to nonlinear systems. When combined with input/output linearizing state feedback, this Smith-like predictor makes a nonlinear system with deadtime behave like a linear system with deadtime. The control structure is completed by adding an external linear controller, which provides integral action and compensates for the deadtime in the input/output linear system, and an open-loop state observer. Conditions for robust stability with respect to errors in the deadtime and more general linear unstructured multiplicative uncertainties are given. Computer simulations for an example system demonstrate the high controller performance that can be obtained using the proposed method.
    Additional Material: 13 Ill.
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  • 129
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 877-877 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 130
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 877-877 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 131
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 132
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 943-950 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It has been recognized that a diagnostic expert system's ability to learn from past experience will improve its diagnostic efficiency as well as make it acquire new heuristics. In this paper, we propose a failure-driven learning scheme by which the expert system automatically updates its compiled knowledge by acquiring new heuristics or refining existing heuristics. A heuristic is refined if it hypothesizes the wrong causal origin during a diagnosis. Using its deep-level knowledge of the process, the expert system draws inductive inferences from causal models to determine why the hypothesis proposed by the heuristic is inconsistent with the current state of the process. The refinement limits the applicability of the heuristic and prevents it from firing if a similar situation were to subsequently arise.
    Additional Material: 3 Ill.
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  • 133
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1402-1403 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 134
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1428-1436 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A magnetic thermometric method is used to determine cross-sectional average axial catalyst temperature profiles for superparamagnetic neckel catalyst beds during ethane hydrogenolysis, an exothermic reaction. Each solid temperature profile is determined from an axial profile of cross-sectional average magnetization and is represented by a polynomial. In turn, each magnetization profile is determined from voltage data obtained as the bed is moved through an AC permeameter. A Fredholm equation of the first kind, “regularized” using a minimum variance constraint, is inverted to determine the magnetization profile.The determination of the axial temperature profile for a reactor operating at 11.0% conversion is detailed. It provides a good test of the method used. Some limitations of the method are highlighted by attempts to analyze data from a reactor operating at complete conversion. The potential for model parameter estimation is discussed.
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  • 135
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    AIChE Journal 35 (1989), S. 1465-1472 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper presents a simple linear model based self-tuning controller (STC) for MIMO systems. The controller, namely the cautious selftuning controller (CSTC), features enhanced robustness characteristics in the case of unmodeled nonlinearities and / or dynamics. The controller structure is that of a linear quadratic, minimizing a single-step cost function, and with time varying input penalization. The CSTC can be applied to open-loop stable and minimum-phase systems. Application to a simulated distillation column demonstrates its effectiveness.
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  • 136
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1735-1738 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 137
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    AIChE Journal 35 (1989), S. 1739-1741 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 138
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 139
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1543-1546 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 140
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1559-1563 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 141
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    AIChE Journal 35 (1989), S. 1582-1582 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 142
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    AIChE Journal 35 (1989), S. 1829-1834 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A low residence time flow method for the measurement of the critical temperatures and pressures of thermally-unstable fluids was developed in this work. The low residence time at elevated temperatures minimizes decomposition and other reactions, making it possible to measure the critical properties of many unstable fluids. An extrapolation procedure was developed to obtain the critical properties of rapidly reacting substances, based on the linear behavior of the apparent critical property with residence time. The measured critical properties of 14 n-alkanes (pentane through octadecane) using this method are reported in this paper. The results extend the available data on the critical properties of the higher alkanes and reveal a possible error in the literature value for the critical pressure of tetradecane.
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  • 143
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    AIChE Journal 35 (1989), S. 1779-1790 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of protein aggregation in salt-induced precipitation processes were studied as a function of salt type, salt concentration, temperature and protein concentration. α-chymotrypsin (αCT) was used as a model protein. Stopped-flow turbidimetry was used to monitor the progress of precipitations. Analysis of the linear portions of the turbidity trajectories indicates that temperature and salt concentration effects are related to protein solubility; the protein concentration dependence is well described by the Smoluchowski collision equation. The aggregation kinetics of partially-inhibited αCT exhibit poisoning behavior, underscoring the importance of dimerization and monomer addition in the precipitation of αCT. Solute particle radius distributions determined via dynamic laser light scattering for low salt and supernatant αCT solutions indicated that significant aggregation does not occur in the absence of supersaturation. A detailed population balance model was proposed that accounted for specific and nonspecific interactions and monomer addition. The model is expected to find general application to protein aggregation phenomena, in particular for proteins that have specific quaternary interactions.
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  • 144
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1895-1898 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 145
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    AIChE Journal 35 (1989), S. 1219-1223 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 7 Ill.
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  • 146
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    AIChE Journal 35 (1989), S. 1233-1244 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The purpose of this work is to introduce the notion of synthesizing mass-exchange networks (MEN's). A systematic, two-stage, procedure is proposed for the synthesis of cost-effective MEN's. In the first stage, a thermodynamically-oriented procedure is used to identify the thermodynamic bottlenecks (pinch points) that limit the extent of mass exchange between the rich and the lean process streams. Preliminary networks, that feature maximum mass exchange, are generated at this stage. The objective of the second stage is to improve the design of these preliminary networks so as to develop a final configuration of the MEN that satisfies the assigned exchange duty at minimum venture cost. This approach is applied to the synthesis of MEN's with single-component targets as well as multicomponent, compatible targets. An illustrative example on the sweetening of coke-oven gas is presented to demonstrate the applicability of the proposed synthesis procedure.
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  • 147
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    AIChE Journal 35 (1989), S. 1883-1893 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Partition coefficients are computed for hard spherical solutes in equilibrium with sponge-type matrices containing randomly-placed spherical cavities or pores using grand canonical Monte Carlo simulation. The random pore model is representative of a variety of disordered porous solids including porous glasses and some polymeric materials. The algorithm used brings additional realism to the problem by rigorously distinguishing between accessible and inaccessible pore space. The simulation results display significant concentration effects which are often observed experimentally and are compared to data obtained by Brannon and Anderson (1982) for the partitioning of bovine serum albumin into controlled-pore glass.
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  • 148
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    AIChE Journal 35 (1989), S. 1903-1906 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 149
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    AIChE Journal 35 (1989), S. 1942-1952 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A Monte Carlo (MC) technique involving explicit calculation of molecular trajectories in fibrous media is used to obtain effective transport coefficients in the Knudsen regime of gas diffusion. A fully penetrable cylinders (FPC) model is used to represent a fibrous substrate during the course of densification, as in composite fabrication processes such as chemical vapor infiltration (CVI). The calculated Knudsen permeabilities are in excellent agreement with available data. Accessible porosities are computed as a function of total porosity and are shown to depend on the fiber number density. The nonfiber phase is shown to percolate at φ ≈ 0.095, but the threshold is sensitive to the boundary conditions employed.
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  • 150
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    AIChE Journal 35 (1989), S. 1899-1902 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 151
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    AIChE Journal 35 (1989), S. 1915-1916 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 152
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    AIChE Journal 35 (1989), S. 1927-1932 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The model of uniform nonlinear kinetics recently developed for the continuous description of a multicomponent mixture reacting in a batch or plug flow reactor (Astarita, 1989) is applied to the analysis of a continuous stirred tank reactor (CSTR). It is shown that most of the equations can be solved in general, independently of the specific kinetic mechanism. Some specific mechanisms are discussed. The difference between the behavior in a plug flow reactor (PFR) and a CSTR turns out to be quite dissimilar from what one would expect by considering the single-component case.
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  • 153
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    AIChE Journal 35 (1989), S. 1962-1974 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A computer simulation of turbulent flow in a channel is used to detect flow patterns related to the production of Reynolds stress. It is found that quadrant 2 and quadrant 4 events possess a streaky structure in the viscous wall region and that these events can be best understood by examining the velocity field in the y-z plane. Large turbulence production in the viscous wall region is found to occur in updrafts and downdrafts associated with closed eddies. These eddies, on average, have a spanwise dimension of 50 wall units and a streamwise dimension of 400-450 wall units. They are often seen to originate from small attached eddies at the wall.
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  • 154
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    AIChE Journal 35 (1989), S. 2003-2012 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ceramic particle formation processes have been studied using SiO2 as a model compound. Silica particles have been synthesized in a counterpropagating diffusion flame reactor, in which in-situ measurements of particle size and number density have been made. In addition, the time-temperature history of the particle field has been calculated from a flame simulation. Numerical simulations using moment and sectional methods for particle formation have been applied and compared to the experimental measurements. The simulations for the particle formation assume a kinetically-constrained approach, allowing a simple representation of nucleation, surface growth and coagulation. The results suggest that, if the source rates are known well enough, particle formation of low vapor pressure species can be predicted. Both models do well in predicting the gross features of particle formation (number density and mean particle size), although the moment solution does a poor job of predicting the polydispersity effects during periods of high monomer generation rates.
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  • 155
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    AIChE Journal 35 (1989), S. 1753-1756 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 156
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    AIChE Journal 35 (1989), S. 1770-1778 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Previous work has shown that in a standard stirred tank, the three-dimensional velocity field in the discharge flow of the stirrer is characterized by a strong deviation from homogeneous isotropic turbulence. By means of a two-component laser Doppler velocimeter (2D-LDV), the \documentclass{article}\pagestyle{empty}\begin{document}$ \overline {v'_r v'_\theta} $\end{document} Reynolds stresses are measured in a 6.3-dm3 standard tank stirred by a six-flat-blade Rushton turbine. Obviously, these stresses must be known to better understand the turbulent mixing in such a configuration. Moreover, the 2D-LDV appears to be an efficient tool for characterizing, from an energy viewpoint, the type of agitator used and, in principle, is confirmed to be useful to accurately obtain the length scales of turbulence which are fundamental parameters for the study of the micromixing processes.
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  • 157
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    AIChE Journal 35 (1989), S. 1813-1820 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new generalized algorithm has been developed for solving simultaneous chemical and phase equilibrium equations of two-phase systems. By rearranging convergence loops of the algorithm of Sanderson and Chien (1973), this new approach shows improved robustness and speed. Solutions to the material balance and chemical equilibrium equations are obtained with an improved Marquardt method (Zhan, 1976). An esterification reaction and dissociation reactions of electrolytes in phase equilibrium are presented as examples.
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  • 158
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    AIChE Journal 35 (1989), S. 1845-1855 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Continuous-phase backmixing coefficients have been determined by continuous tracer injection for pulsed-plate extraction columns of 72-, 152- and 300-mm-diameter. Both single-phase water and two-phase kerosene-water were studied in all three columns, together with four other solvent-water systems in the smallest column; in all cases, water was the continuous phase. Evidence of maldistribution of the phases was obtained in the largest column. The backmixing coefficient was found to increase with column diameter in single-phase operation, but was diameter-independent in the two-phase case. Alternative correlations of the data were based on dimensional analysis and on a physical model, respectively. The influence of different systems was accounted for in the latter in terms of droplet size and terminal velocity, dispersed phase holdup, and density difference. Qualitative color tracer tests on the dispersed phase gave no evidence of backmixing of this phase, although strong forward dispersion was observed in the emulsion regime.
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    AIChE Journal 35 (1989), S. 1894-1894 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 160
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    AIChE Journal 35 (1989) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 161
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    AIChE Journal 35 (1989), S. 1916-1916 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 162
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    AIChE Journal 35 (1989), S. 1953-1961 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A previously developed method (Sotirchos and Burganos, 1988) for studying isobaric multicomponent diffusion in a class of capillary networks is extended for application to the problem of convection and diffusion of gaseous mixtures in porous media. The method is used to develop flux models for nonisobaric transport in capillary structures, which are then compared with corresponding “three-parameter” dustygas models. Results for discrete and continuous pore size distributions show that the predictions of the developed flux models depend strongly, both qualitatively, and quantitatively, on the procedure used to average the dusty-gas model equations for a single pore over the pore-size distribution.
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  • 163
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    AIChE Journal 35 (1989), S. 1993-2002 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The ability of knowledge-based expert systems to facilitate the automation of difficult problems in process engineering that require symbolic reasoning and an efficient manipulation of diverse knowledge has generated considerable interest recently. Rapid deployment of these systems, however, has been difficult because of the tedious nature of knowledge acquisition, the inability of the system to learn or dynamically improve its performance, and the unpredictability of the system outside its domain of expertise.This paper proposes a neural-network-based methodology for providing a potential solution to the preceding problems in the area of process fault diagnosis. The potential of this approach is demonstrated with the aid of an oil refinery case study of the fluidized catalytic cracking process. The neural-network-based system successfully diagnoses the faults it is trained upon. It is able to generalize its knowledge to successfully diagnose novel fault combinations it is not explicitly trained upon. Furthermore, the network can also handle incomplete and uncertain data. In addition, this approach is compared with the knowledge-based approach.
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  • 164
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    AIChE Journal 35 (1989), S. 37-41 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental data on sulfation rates of CaO particles derived from CaCO3 are compared to those derived from Ca(OH)2 using a product layer diffusion control model differing only in the shape of the CaO grain. Both the model and the experimental data indicate slightly higher reactivity for the Ca(OH)2-derived oxide due to the observed difference in grain shape. This effect is considered as a contributor to the greater performance of Ca(OH)2 in pilot-scale SO2 removal studies.
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  • 165
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    AIChE Journal 35 (1989), S. 129-138 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A study of the flow of viscous liquids contained in an open cavity driven by a moving wall has been undertaken as a first step toward understanding interphase heat and mass transport in polymer processing equipment where rolling pools of liquid are generated. Solutions to the equations of motion for creeping flow in cavities of different aspect ratios were obtained using a finite-differences technique for circumstances when the wall moves in the same direction as the gravitational field.Experimental studies of the flow patterns in cavities of various aspect ratios were found to be in good agreement with the creeping flow predictions for cavity Reynolds numbers Re 〈 50 and aspect ratios a 〈 1. The structure of the flow in this geometry was found to be similar to that in closed cavities of the same shape. The position and strength of the principal vortex were observed to be nearly independent of the existence of a free surface, and the gas-liquid interface was found to significantly stabilize the rotational motion in shallow cavities.
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  • 166
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    AIChE Journal 35 (1989), S. 164-167 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 167
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    AIChE Journal 35 (1989), S. 120-128 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The homogeneous vapor phase cracking of newly formed wood pyrolysis tar was studied at low molar concentrations as a function of temperature (773-1,073 K), at residence times of 0.9-2.2 s. Tar conversions ranged from about 5 to 88%. The tars were generated by low heating rate (0.2 K/s) pyrolysis of ∼2 cm deep beds of sweet gum hardwood, and then rapidly conveyed to an adjacent reactor for controlled thermal treatment. Quantitative yields and kinetics were obtained for tar cracking and resulting products formation. The major tar conversion product was carbon monoxide, which accounted for over two-thirds of the tar lost at high severities. Corresponding ethylene and methane yields were each about 10% of the converted tar. Coke formation was negligible and weight-average tar molecular weight declined with increasing tar conversion. A first-order distributed activation energy model more closely correlated tar conversion kinetics over a wider range of reaction conditions than did a single-reaction model.
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  • 168
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    AIChE Journal 35 (1989), S. 148-158 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A computer-generated slim tube randomly packed with spheres of almost uniform size is used to model single-phase flow in a packed tube with a small tube diameter to particle diameter ratio, R. To obtan a detailed description of its morphology, the slim packed tube is first tessellated into tetrahedra in the interior, and pentahedra near the walls of the tube. Then, the pore space is represented by a network of interconnected circular and triangular sinusoidal flow channels. The size and length of each channel, as well as their interconnectivity, are exactly known. In addition, porosity and solid surface area per unit volume of the porous medium are determined as a function of distance away from a wall. These data suggest that the presence of the walls has two counteracting effects on fluid flow. A higher porosity promotes flow along the walls but a higher surface area per unit volume hinders it. To confirm this prediction, experimental permeability data are obtained for tubes with R between 2.5 and 40. For R 〉 25, the permeability is the same as that of a large diameter tube, k∞. Between 8 and 25, the permeability can be larger or less than k∞. The way the tube is packed determines whether the higher porosity or surface area dominates in the wall region, and thus higher or lower permeability. Below R = 8, the confining walls cause a marked increase in overall bed porosity and the permeability is always larger than k∞. Theoretical predictions of the permeability of such very slim tubes are in good agreement with experimental data.
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  • 169
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    AIChE Journal 35 (1989), S. 177-186 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A long-wave equation for film thickness as a function of position is derived for a general case incorporating viscous, surface tension, and interfacial shear effects. The derivation considers both the parabolic and the power-law velocity profiles. The analysis is aimed at revealing the wave velocity that induces infinitely long (homoclinic) periods as well as substrate thickness and wave peak amplitude. Phase plane analysis shows that at Re ≫ 1, due to time-scale separation, the homoclinic velocity is near that at the Hopf bifurcation. That enables analytical derivation of the wave characteristics.Comparison with experimental results in the range of Re-310-3, 100 with countercurrent gas flow, shows encouraging agreement. At very high Re the wave velocity suggests the onset of turbulence, in agreement with theory. Phase plane analysis predicts also that the wave shape consists of a simple peak with a steep front, with short waves riding on the main wave at low Re.
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  • 170
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    AIChE Journal 35 (1989), S. 223-229 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A robust and efficient algorithm is developed to calculate dynamic inputs for optimal experimental designs. Different objective functions are presented to allow designs for both model discrimination and the improvement of parameter precision. Time-varying inputs are calculated by reformulating the optimal design problem as an optimal control problem. This approach can provide large improvements in the ability to discriminate among a series of models, and then increase the accuracy of the resulting parameters.
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    AIChE Journal 35 (1989), S. 259-266 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A dynamic model is derived for simultaneous, homogeneous and heterogeneous, first-order reactions in a slurry reactor. The theory is applied to experimental data for the oxidation (with gaseous oxygen) of aqueous sulfite solutions which is first order in oxygen and zero order in sulfite. The homogeneous reaction is very slow at low pH (2-3) where the sulfur exists as dissolved SO2 or HSO3-, even when cobalt is added as a homogeneous catalyst. At higher pH (7-8.5), considerable homogeneous reaction occurs with and without cobalt ions. Here the predominant species are SO3= and HSO3-. Activated carbon is not a heterogeneous catalyst at pH 7 or 8.5, but is responsible for nearly all the reaction at the low pH values. Analysis of the heterogeneous data indicates that the surface reaction between adsorbed oxygen and SO2 controls the rate rather than adsorption of oxygen.
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    AIChE Journal 35 (1989), S. 603-613 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A block relative gain measure for nonsquare systems has been derived. Evaluated at steady state, this measure serves as a performance-related tool for evaluating control structures prior to controller design. Both the nonsquare dynamic block relative gain and the relative sensitivities have been presented as dynamic interaction measures that depend on the controller tuning and are consequently applicable to design of nonsquare decentralized controllers. Rigorous relationships between the dynamic block relative gain and the performance and stability of a closed-loop system have been established.
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    AIChE Journal 35 (1989), S. 635-644 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This work provides a new method for calculating phase equilibria for systems where conventional activity-coefficient models are not suitable. A procedure is presented for superimposing ionic effects on a conventional equation of state for nonelectrolytes. A modification of Born's equation is used to describe charging the ions; ion-ion interactions are described with the Mean Spherical Approximation, coupled with an adjustable salt/solvent parameter that is obtained from osmotic-coefficient data at room temperature. The equation of state is used to predict gas solubilities in aqueous salt solutions at high pressures. While this method produces qualitative agreement with the experimental solubility data, quantitative agreement requires a salt/ gas parameter obtained from Setchenow-constant data. When Setchenow constants are used, agreement with experiment is good except at high salt concentrations, where salting-out is usually underpredicted. Good results are obtained for phase equilibria in a natural-gas/brine system at high pressures.
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    AIChE Journal 35 (1989), S. 658-661 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 35 (1989), S. 662-665 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 35 (1989), S. 676-678 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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    AIChE Journal 35 (1989), S. 690-693 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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    AIChE Journal 35 (1989), S. 701-701 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 179
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    AIChE Journal 35 (1989), S. 481-489 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A semitheoretical group contribution method for predicting pure-compound second virial coefficients is proposed. An expression for the second virial coefficient, expressed as the product of a nonpolar and a polar contribution, is derived using statistical thermodynamic concepts and an approximate form for the radial distribution function. For polar compounds the nonpolar contribution is assumed to be given by the Tsonopoulos correlation with the nonpolar acentric factor defined by Thompson and Braun. The polar contribution is represented by an energetic term expressed in terms of group contributions. Second virial coefficient predictions for strong polar and associating systems are comparable with those obtained with the correlations of Tsonopoulos and Hayden and O'Connell. Cross-second virial coefficients for mixtures obtained using well-defined molecular mixing rules compare well with literature values.
    Additional Material: 4 Ill.
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  • 180
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    AIChE Journal 35 (1989), S. 755-763 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The loading of organic molecules adsorbed on high surface area carbon materials can be influenced by the potential of the surface. This phenomenon can form the basis for carbon regeneration and for separation processes. A theoretical treatment demonstrates that adsorption loading becomes more sensitive to potential change when the double layer capacitance of the interface and the size of the organic species are increased. An experimental method was developed to estimate isotherm parameters. The technique was demonstrated on model adsorbates, pentanol and heptanol. The values of the measured isotherm parameters (B = 3.4-9.1 V-2: Emax = 0.36-0.5 V vs. Hg/Hg2 SO4) are in the range of expected values based on literature values for similar systems. Although only 5% of activated carbon surface area was shown to be electrochemically accessible, it still has ten times the area available for electrosorption as compared to the graphite, thus making it attractive for industrial application.
    Additional Material: 8 Ill.
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  • 181
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 182
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    AIChE Journal 35 (1989), S. 533-538 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A lumping procedure proposed previously is applied to two types of continuous reaction mixtures: one in which the constituents undergo reactions of a Langmuir-Hinshelwood (LH) type, the other in which the constituents undergo reactions of a bimolecular type. It is shown that both mixtures initially can behave qualitatively like lumped first-order reactions. At large times, the behavior of the lumps can be described by power law kinetics, with the bimolecular lump displaying a higher overall reaction order. In particular, if the feed contains a nonzero amount of unconvertible species, the LH lump at large times decays at a second-order rate, whereas the bimolecular lump decays at a third-order rate. To complement the asymptotic results, expressions describing the behavior of the lumps at any time are derived.
    Additional Material: 1 Ill.
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  • 183
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    AIChE Journal 35 (1989), S. 139-147 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Knp ≫ 1 gas-kinetic approach of Waldmann (1959, 1961) is extended to predict the thermophoretic properties of nonspherical aerosol particles, and massive nonspherical gas molecules. Calculations are presented for sphero-cylindrical particles (molecules) of arbitrary aspect ratio, L/R, predicting that in a local temperature gradient grad T they will thermophoretically drift: (i) more rapidly when their major axis is aligned with -grad T; (ii) at a velocity different from that of a sphere of radius R equal to the cylinder radius; (iii) at an angle with respect to -grad T when their major axis is not parallel to, nor perpendicular to, -grad T; and (iv) without a net torque tending to orient the particle with respect to -grad T. Important corollaries are that nonspherical particles in a temperature gradient should also experience new thermophoretically-induced coagulation mechanisms. We predict that the orientation-averaged thermal diffusion factor αT should increase approximately linearly with particle (molecule) length.
    Additional Material: 7 Ill.
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  • 184
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    AIChE Journal 35 (1989), S. 168-172 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
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  • 185
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    AIChE Journal 35 (1989), S. 187-195 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Three isolated waves of differing amplitude and shape were selected from experimental measurements of a falling liquid film at Re = 880 for study using an algorithm developed for solution of the Navier-Stokes equations. The method computes the velocity and pressure fields as well as the velocity of the wave. The results show that large streamwise accelerations exist along with regions of recirculating flow in a moving coordinate system. These features can explain the enhanced rates of heat and mass transfer observed in wavy film flow. Computed wave velocities and wall shear stress were in reasonably good agreement with measurements. Wave velocity is shown to be sensitive to small variations in the wave shape and explains the apparent random variation of wave velocity with amplitude that has been observed experimentally. This numerical experiment points to the shortcomings of the many methods used to model large waves on falling films that have been based on parabolic velocity profiles.
    Additional Material: 17 Ill.
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  • 186
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    AIChE Journal 35 (1989), S. 679-682 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 187
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    AIChE Journal 35 (1989), S. 695-699 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 188
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    AIChE Journal 35 (1989), S. 702-702 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 189
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 190
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 737-745 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An investigation of the continuous chromatographic separation of an equimolar mixture of 1,3,5-trimethylcyclohexane and 1,3,5-trimethylbenzene with a 2.4 m × 1.37 cm ID vertical countercurrent moving bed is reported. The solid adsorbent was 30 mesh Al2O3, and the separation was carried out at 200°C. Steady-state axial concentration profiles of each species were determined by withdrawing vapor samples for analysis by gas chromatography. The binary mixture was continuously fed through a port located at approximately the midpoint of the column. The relative solids and carrier gas flow rates could be adjusted so that the more strongly adsorbed trimethylbenzene was transported downward, and less strongly adsorbed trimethylcyclohexane moved upward. For low feed rates, high-purity product streams of each were obtained at the bottom and top of the separator. For sufficiently high feed rates, trimethylbenzene was transported upward as well as downward, and top product purity deteriorated. This behavior is in qualitative accord with the predictions of a dispersionless, one-dimensional flow, adsorption equilibrium model incorporating a Langmuir isotherm.
    Additional Material: 16 Ill.
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  • 191
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    AIChE Journal 35 (1989), S. 775-792 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A quantitative model of softening coal pryolysis is developed and tested against observed behavior. The model treats intraparticle transport of gases and metaplast throughout the softening stage of pyrolysis via growth of bubbles uniformly dispersed in the molten coal. The model quantitatively describes the transient softening behavior including the initiation, duration, and magnitude of plasticity and swelling of the particle. The model kinetic parameters are derived from experiments, in which a highly softening Pittsburgh No. 8 bituminous coal was pyrolyzed, and total weight loss, and yields and molecular weight distributions of tars and pyridine extractables of cooled chars were measured. Model predictions of effects of pressure, particle diameter and temperature on tar yields and weight losses, of effects of pressure on swelling ratio, and of effects of heating rate on plasticity are presented. The model provides good fits to the laboratory data and predicts trends in pyrolysis behavior in good qualitative accord with expectations based on published data.
    Additional Material: 17 Ill.
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  • 192
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    AIChE Journal 35 (1989), S. 873-874 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 193
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    AIChE Journal 35 (1989), S. 875-875 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 194
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 195
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    AIChE Journal 35 (1989), S. 891-907 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A control system is designed for a copolymerization reactor using a combination of feedforward, ratio, and feedback control to regulate polymer production rate, copolymer composition, molecular weight, and reactor temperature. The solution copolymerization of methyl methacrylate and vinyl acetate in a continuous stirred tank reactor is used as an illustrative example with the kinetic parameters and reactor operating conditions obtained from the literature. The process includes equipment to recycle unreacted monomers and solvent. The recycle stream introduces disturbances to the reactor feed, which perturb the polymer properties. A feedforward control strategy is proposed to counter these disturbances, and its effectiveness is demonstrated using the model. The mathematical model is used to investigate input/output control pairings in order to identify the fundamental nature of the solution copolymerization control problem and to determine the best control system structure. The combined feedforward/feedback strategy is tested on a nonlinear model of the process for set point changes and compensation of unmeasured reactor disturbances. The performance of the control system design was quite good, and such designs have been found successful in plant operations.
    Additional Material: 13 Ill.
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  • 196
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    AIChE Journal 35 (1989), S. 449-458 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analytical model has been constructed to predict the birefringence level in an injuection-molded disk with direct application to optical disk substrates. The model incorporates simplified analyses for the flow in a center-gated cavity during the filling stage, the heat transfer during the cooling stage, and the stress relaxation following the cessation of flow at the end of the filling stage of the injection-molding cycle. The stress relaxation process is analyzed with the integral constitutive equation of Wagner and the residual stresses are converted to retardation via the stress-optical law. Predictions of normal retardation profiles are in line with experimental data and the general effects of melt temperature, mold temperature, and injection speed are closely captured by the model. By contrast, the observed transverse retardation is not in accord with the predicted response. This discrepancy is attributed to the fact that the transverse retardation is induced by cooling stresses and thus cannot be explained in terms of a flow stress mechanism employed in the present analysis.
    Additional Material: 14 Ill.
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  • 197
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    AIChE Journal 35 (1989), S. 459-465 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: During inflammation, leukocytes cross the blood vessel wall and migrate to the inflammatory site in response to gradients of diffusible chemical attractants produced there. This directed migration response to a chemical gradient, termed chemotaxis, can be studied experimentally in the Millipore filter assay. We have applied a mathematical model to analyze cell population migration in the assay in terms of two parameters analogous to molecular transport coefficients. The random motility coefficient, μ, reflects the cell response to uniform concentrations of chemical attractant, while the chemotaxis coefficient, χ, reflects the response to a concentration gradient. We have measured μ and χ by comparing theoretical cell density profiles to those measured in the assay. Both parameters vary as a function of the attractant concentration; μ ranges from 10-10-10-9 cm2/s and χ ranges from 10-100 cm2/s.M for the attractant tested. These values agree with ones predicted from a priori theoretical relationships for μ and χ. Quantitation of the Millipore filter assay provides a framework for the quantitation of analogous cell transport systems such as a composite assay simulating cell migration across the vessel wall.
    Additional Material: 10 Ill.
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  • 198
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    AIChE Journal 35 (1989), S. 967-980 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The important connection between particulate deposit properties and deposition mechanism remains poorly understood and only scarcely studied. Accordingly, in this research, we develop a discrete stochastic model to simulate particulate deposition processes resulting from realistic combinations of deposition mechanisms. Particle motion is assumed to be determined by the superposition of a deterministic force that acts toward the collecting surface and a random force, which produces Brownian diffusion. We characterize the resulting deposit microstructure via porosity and pore size/area distribution, surface area; and we examine the evolution of these descriptors with time (number of particles deposited) for different deposition mechanisms. We also examine the effect of particle polydispersity, spatial orientation (for nonspherical particles), and mean-free-path on the resulting deposit structure.
    Additional Material: 13 Ill.
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  • 199
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    AIChE Journal 35 (1989), S. 1003-1016 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An extended transportation array representation is developed for the design of process heat recovery networks incorporating heat engines and heat pumps. The formulation automatically accounts for the relocation of pinches in the integrated system. The optimal heat flow pattern is determined based on simple economic criteria. Simplified models of heat engine and heat pump systems are developed that permit integration options to be identified on the basis of heat flows without requiring specific cycle designs. The solution array identifies design alternatives and provides a decision framework to guide in selecting the final design topology.
    Additional Material: 13 Ill.
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  • 200
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    AIChE Journal 35 (1989), S. 1097-1106 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The sorption of toluene, dilute in CO2, and likewise the distribution coefficient of toluene between silicone rubber and CO2 have been explored from gaseous to supercritical fluid conditions. Sorption and desorption isotherms were determined by frontal analysis using a new inverse supercritical fluid chromatography technique at 35 and 70°C up to 250 bar. Complementary swelling data are presented for pure CO2 in silicone rubber up to 315 bar. A new result is that the sorption of toluene goes through a maximum and is highly adjustable over a continuum in the highly compressible region of carbon dioxide. This behavior is explained physically and predicted quantitatively with the Flory equation and the Peng-Robinson equation of state using only information from binary systems. These results are useful for a wide variety of applications including impregnation of polymers with pharmaceuticals, fragrances and other additives, and polymer purification.
    Additional Material: 12 Ill.
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