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Digitale Medien

Stereoisomeric effects on mass spectra - II: The isomeric methyldecalins (1969)

Meyerson, Seymour ; Weitkamp, A. W.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 2 (1969), S. 603-609

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Details

ISSN: 0030-493X

Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Mass spectra of the four stereoisomeric 1-methyldecalins and the four 2-methyldecalins have been measured. For each set of stereoisomers, the order of relative intensity of the parent-less-CH3 ion, but not of the parent ion, parallels the order of relative stability of the molecules. The correlation suggests that loss of the methyl group from the members of each set of stereoisomers leads to a common product, with the differing conformational energies converting into differences in vibrational energy, which in turn lead to differing extents of further decomposition.

Zusätzliches Material: 3 Tab.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/oms.1210020606

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