ISSN:
0009-2940
Schlagwort(e):
Alkyne complexes
;
Clusters
;
Iron complexes
;
Chemistry
;
Inorganic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Reaction of undecacarbonyl(acetonitrile)triiron (1) with 1,4-dimethoxy-2-butyne (2) yields the alkyne complexes decacarbonyl(μ3;-η2-Verbar-1,4-dimethoxy-2-butyne)triiron (3) and nonacarbonyl(μ3;-η2;-⊥-1,4-dimethoxy-3-butyne)triiron (4). The crystal structure determination of 2 shows that the alkyne ligand is coordinated strictly parallel to one iron-iron edge.
Zusätzliches Material:
1 Tab.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/cber.19911240417