Digitale Medien
New York, NY
:
Wiley-Blackwell
International Journal of Quantum Chemistry
6 (1972), S. 289-296
ISSN:
0020-7608
Schlagwort(e):
Computational Chemistry and Molecular Modeling
;
Atomic, Molecular and Optical Physics
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The matrices of the irreducible representations of the 3-dimensional rotation group are shown to be related to Krawtchouk's orthogonal polynomials of a discrete variable x = j - m', whose degrees are given by n = j + m. The relation follows directly from the recurrence formulas satisfied by the matrix elements and permits a concise development of the formal properties of the rotation matrices. In particular, an asymptotic relation for large j is developed that generalizes a formula first discussed for a special case by Wigner.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/qua.560060208
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