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Digitale Medien

Effect of the internal field on the birefringence of polymer crystals (1969)

Stein, Richard S.

New York : Wiley-Blackwell

Journal of Polymer Science Part A-2: Polymer Physics 7 (1969), S. 1021-1031

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Details

ISSN: 0449-2978

Schlagwort(e): Physics ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: The discrepancy between the values of the anisotropy of methylene groups determined from crystal refractive indices, stress-optical data, and gas and liquid light-scattering depolarization is explained on the basis of the effect of the internal field on the polarizability of the isolated molecule. The internal field may arise from intermolecular or intramolecular interactions which depend upon molecular conformation and state of aggregation. A simple continuum calculation based upon an extension of the calculation of the Lorenz-Lorentz field is shown capable of accounting for the discrepancy.

Zusätzliches Material: 5 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1969.160070605

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