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Digitale Medien

Theoretical reaction kinetics of reversible polymerization (1972)

Huang, Ching-Rong ; Wang, Huei-Hsiung

New York : Wiley-Blackwell

Journal of Polymer Science Part A-1: Polymer Chemistry 10 (1972), S. 791-795

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Details

ISSN: 0449-296X

Schlagwort(e): Physics ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The kinetics of reversible polymerization of a polymer system without transfer and termination reactions is investigated theoretically. An analytic solution is obtained that enables one to predict the variation of monomer concentration with respect to time in a closed system. When the polymer system reaches equilibrium, three different relationships are derived between the equilibrium monomer concentration and the ceiling temperature under different conditions. The classical relationship by Dainton and Ivin is a special case of the three derived cases.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1972.150100314

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