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Digitale Medien

Solvent and concentration dependence of hydrodynamic volumes and GPC elution volumes (1976)

Rudin, Alfred ; Wagner, R. A.

New York, NY [u.a.] : Wiley-Blackwell

Journal of Applied Polymer Science 20 (1976), S. 1483-1490

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Details

ISSN: 0021-8995

Schlagwort(e): Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Maschinenbau , Physik

Notizen: The sizes of dissolved polymers can be estimated a priori at infinite dilution and under theta conditions from existing theories. The effects of concentration can be calculated by assuming that the hydrodynamic volume decreases from a maximum value at infinite dilution toward the theta condition volume, which is reached when the volume fraction of solvated polymer in solution is unity. The predicted hydrodynamic volumes coincide with results of small-angle x-ray scattering and effects of solvent and concentration on gel permeation chromatography elution volumes.

Zusätzliches Material: 2 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/app.1976.070200607

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