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Digitale Medien

Melting behavior of cis-polybutadiene crystallized under stress (1989)

De Candia, F. ; Romano, G.

New York, NY [u.a.] : Wiley-Blackwell

Journal of Applied Polymer Science 38 (1989), S. 249-256

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Details

ISSN: 0021-8995

Schlagwort(e): Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Maschinenbau , Physik

Notizen: Samples of crosslinked cis-polybutadiene were crystallized at different temperature and drawing degree. The melting behavior of the crystallized samples was analyzed detecting the retractive stress as a function of temperature. The experimental melting data were extrapolated to the equilibrium conditions to obtain the thermodynamic melting temperature as a function of the drawing degree. The extrapolated data were analyzed with different theoretical approaches. Results agree with a model in which chain-folding and extended-chain crystallization can coexist, depending on crystallization temperature and drawing degree.

Zusätzliches Material: 6 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/app.1989.070380205

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