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Digitale Medien

Kinetic investigation of the alkylation of salts of 2,5-dimercapto-1,3,4-thiadiazole (2000)

Kuodis, Z. ; Rutavichyus, A. ; Valiulene, S.

Springer

Chemistry of heterocyclic compounds 36 (2000), S. 857-861

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Details

ISSN: 1573-8353

Schlagwort(e): salts of 2,5-dimercapto-1,3,4-thiadiazole ; alkylation ; kinetics ; electronic absorption spectra

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract A kinetic investigation has been carried out, using electronic absorption spectra, of the alkylation with benzyl chloride of the dihydrazine, monohydrazine, and the disodium salts of 2,5-dimercapto-1,3,4-thiadiazole, and also of the hydrazine and sodium salts of 5-benzylthio-2-mercapto-1,3,4-thiadiazole. The rates orders and constants were established for the benzylation reaction and it was noted that the reaction rate depends on the cation of these salts and the degree of substitution of the 2,5-dimercapto-1,3,4-thiadiazole.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF02256923

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