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Digitale Medien

The collisional energy transfer between the D 1Π and d 3Π states of the NaK dimer induced by argon buffer gas H. Zhiwei et al.: Appl. Phys. B 66, 471 (1998) (1999)

Hansson, T.

Springer

Applied physics 69 (1999), S. 249-251

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Details

ISSN: 1432-0649

Schlagwort(e): PACS: 33.00; 34.00; 35.00

Quelle: Springer Online Journal Archives 1860-2000

Thema: Physik

Notizen: Abstract. It is shown in this Comment that the method proposed by Zhiwei et al. to extract cross sections for collisional energy transfer between molecular states mediated by argon atoms, is neither correct nor suitable, as it fails to reproduce the molecular behaviour they observe. An alternative model based on a consecutive scheme is put forward, and it is shown that a minimal assumption of one intermediate collisionally activated step is enough to satisfactorily reproduce the observations by Zhiwei et al. However, the extracted parameters are functions of the involved rate constants that are too complex to leave any hope of attaining information on the desired cross sections from them by just varying the argon buffer gas pressure, as done by Zhiwei et al.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/s003400050802

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