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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 6463-6468 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The coupled electron–phonon dynamics of a one-dimensional system, which is described by a Su–Schrieffer–Heeger(SSH)-type Hamiltonian, is investigated by means of a time-dependent projection operator technique. The equations of motion for the vibrational and electronic expectation values are derived without using the adiabatic and continuum approximation. When solving these transport equations numerically a quantum correction to the usual soliton solutions which we calculate from the Heisenberg equations for the SSH Hamiltonian is obtained. It turns out that the soliton solutions become unstable when the extension of the soliton is of the order of a lattice constant.
    Type of Medium: Electronic Resource
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