ISSN:
0935-6304
Keywords:
Atomic emission detection
;
High temperature GC
;
GC-AED
;
Microwave-induced plasma
;
Metalloporphyrins
;
Selective detection of metals
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
High temperature gas chromatography-atomic emission spectroscopy is used for the detection of vanadyl, nickel, and iron porphyrins in crude oils. The operational variables are investigated with regard to the effects on performance in high temperature GC-AED. Under optimal conditions, the method provides charactersitic metal distributions for oils from different sources. The method is also advantageous in the study of decomposition of petroleum metal species. Several crude oils were analyzed for the content of the distillable metals in comparison with total metals as determined by a direct spectroscopic method.
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240170407