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Raman spectroscopy study of powdered [Ni(NH3)6] X2 compounds (1975)

Janik, J. M. ; Janik, J. A. ; Pytasz, G. ; [et al.]

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 4 (1975), S. 13-24

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ISSN: 0377-0486

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Ten out of eleven Raman active modes were detected in [Ni(NH3)6] X2 powders, apart from internal modes of the X- ions. The Raman active lattice mode happens to agree fairly well with the predictions of a model based on the electrostatic potential field of point charges. The X = Cl compound showed evidence of losing ammonia during irradiation with the laser beam. Two modes (the N—Ni—N angle deformation and the lattice vibration) are especially sensitive to the NH3- vacancies thus created.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jrs.1250040103

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