ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
With t-BuO-/t-BuOH at 185°C bicyclo-[2.2.2] and -[3.2.1]octanones are interconvertible. In saturated systems equilibrium is attained very slowly, but in unsaturated cases an equilibrium mixture heavily favoring the [3.2.1] skeleton is obtained relatively rapidly, thereby providing a convenient route to homo and bis-homo conjugated ketones. Experiments in t-BuOD using 13C NMR to monitor deuterium incorporation revealed five major sites of exchange in the unsaturated ketones.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270061114