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Carbon-13 NMR studies of a series of benzylphenols (1978)

Nakai, Yoshimi ; Yamada, Fukiko

Chichester : Wiley-Blackwell

Organic Magnetic Resonance 11 (1978), S. 607-611

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ISSN: 0030-4921

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Carbon-13 NMR spectra of a series of benzylphenols and their O-alkylated derivatives were recorded to find the substituent effects of the benzyl, hydroxybenzyl and alkoxybenzyl groups on the 13C chemical shifts. It was found that the methylene bridge carbons show signal shifts mainly due to the mesomeric effects of the OH and OCH3 substituents, and that in the case of ortho-substituted benzyl compounds, the methylene carbon signals exhibit upfield shifts due to both mesomeric and steric effects.

Additional Material: 8 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mrc.1270111206

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