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Evidence for one bromine participation in the expulsion of the other from 1,2-dibrominated compounds (1971)

Pechine, J. M.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 5 (1971), S. 705-711

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Analysing the stereoisomeric effect on mass spectra for three pairs of geometric isomers (meso and racemic 2,3 dibromobutanes, cis and trans 1,2 dibromocyclohexanes and cis and trans dibromocyclopentanes) it is suggested that the [M - Br] ion formation is facilitated by participation of the other bromine, this participation being maximum when the two halogens are trans or diaxial. The particular bromine character and the analogy with solution chemistry are emphasized.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210050609

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