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  • 1
    Electronic Resource
    Electronic Resource
    Ortho effect: The fragmentation of isopropyl 2-hydroxychlorocarbanilates (1971)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 977-982 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of isopropyl 2-hydroxychlorocarbanilate indicate a preferential ortho intramolecular rearrangement which yields a chloro 2-benzoxazolinone intermediate ion. A com-parison of the fragmentation of ortho, meta and para hydroxy analogs of isopropyl 3-chlorohydroxy-carbanilate indicates the existence of an ‘ortho effect’ during the fragmentation of isopropyl-chloro 2-hydroxycarbanilates.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210050810
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