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  • 1
    Electronic Resource
    Electronic Resource
    The benzoyl cation: The participation of isolated electronic excited states in the dissociation of molecular ions of the form [C6H5COX]+· (1973)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 7 (1973), S. 1407-1413 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The heat of formation of the benzoyl cation generated from [C6H5COX]+· is found to depend on X, while the heat of formation of the phenyl ion produced therefrom is, with one exception, independent of X. The excess energy of the benzoyl cation can be accounted for by an electronic excited state of the ion in the mass spectra of benzoic acid, benzaldehyde, benzamide, methyl benzoate and possibly benzophenone; the benzoyl cation is not excited in the mass spectra of acetophenone and benzoyl chloride.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210071215
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