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  • 1
    Electronic Resource
    Electronic Resource
    Isotope effects and H/D scrambling in the fragmentation of labelled propenes (1974)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 9 (1974), S. 555-557 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The fragmentation reaction [C3(H,D)6]+· → [C3(H,D)5]+ + (H, D) has been examined in the metastable decomposition region for two pairs of labelled propenes: CH3CD=CH2,CD3CH=CD2 and CD3CH=CH2, CH3CD=CD2. The results indicate that complete hydrogen scrambling occurs in the propene molecular ion prior to fragmentation. The isotope effect kH/kD is in the range 2·1 to 3·3.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210090602
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