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Deuterium isotope effects on oxygen-17 chemical shifts (1986)

Aime, Silvio ; Santucci, Enrica ; Fruttero, Roberta

Chichester : Wiley-Blackwell

Organic Magnetic Resonance 24 (1986), S. 919-920

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ISSN: 0749-1581

Keywords: 17O NMR Chemical Shifts ; deuterium isotope effects ; Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Large deuterium isotope effects on 17O resonances were observed for six common NMR solvents. Only in the case of acetone did the substitution of deuterium for hydrogen result in a downfield shift. The H/D isotope effect was also detected in a study of the reversible hydration of CH3CHO.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mrc.1260241015

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