ISSN:
0749-1581
Keywords:
1H NMR
;
13C NMR
;
1-Substituted pyridinium salts
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
1H and 13C NMR chemical shifts of a series of 1-substituted pyridinium salts were measured in dimethyl sulfoxide. The effect of the quaternary pyridinium ring on the resonance of the methylene group of the substituent is reported. Increments of δ1H = 3.89 ± 0.16 ppm and δ13C = 47.5 ± 3.7 ppm and are estimated for replacing YCH2H with YCH2Py+. The effects of 1-substituents on the pyridinium ring chemical shifts are discussed.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260271113