ISSN:
0749-1581
Keywords:
Solid-state NMR
;
Carbon-13
;
Magic-angle spinning
;
Residual dipolar splittings
;
Second-order quadrupolar effects
;
Carbon-chlorine interactions
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Residual dipolar splittings in 13C cross-polarization magic-angle spinning spectra arising from coupling to chlorine nuclei are reported for the three chloroacetanilide isomers, using several spectrometers. At medium to high magnetic field doublets are seen for C—Cl carbon resonances. Perturbation theory explains the appearance of the spectra qualitatively but is inadequate quantitatively.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260311016