ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
A study has been made of the cation exchange equilibria between Dowex 50W-X8 resin and aqueous solutions of copper nitrate, nitric acid, and sodium nitrate in binary and ternary mixtures. Experiments were carried out at room temperature with solutions having total cation concentrations of approximately 0.1N, 0.05N, and 0.01N. It was found that the equilibria for any two ions were essentially the same in binary and ternary mixtures. Moreover single valued selectivity coefficients were determined which characterize these data quite well for all three concentration levels. This makes possible the complete description, for engineering purposes, of ternary equilibria in terms of the simpler and more accessible binary exchange reactions, as previously suggested (1).
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690090109